Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Probing Polaritons in 2D Materials with Synchrotron Infrared Nanospectroscopy

Journal Article · · Advanced Optical Materials
 [1];  [2];  [3];  [3];  [4];  [1];  [1]
  1. Brazilian Center for Research in Energy and Materials (CNPEM), Campinas, SP (Brazil). Brazilian Synchrotron Light Laboratory (LNLS)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  3. Mackenzie Presbyterian Univ., São Paulo (Brazil). MackGraphe – Graphene and Nanomaterials Research Center
  4. Physikalisch‐Technische Bundesanstalt (PTB), Berlin (Germany)
Polaritons, which are quasiparticles composed of a photon coupled to an electric or magnetic dipole, are a major focus in nanophotonic research of van der Waals (vdW) crystals and their derived 2D materials. For the variety of existing vdW materials, polaritons can be active in a broad range of the electromagnetic spectrum (meVs to eVs) and exhibit momenta much higher than the corresponding free-space radiation. Hence, the use of high momentum broadband sources or probes is imperative to excite those quasiparticles and measure the frequency-momentum dispersion relations, which provide insights into polariton dynamics. Synchrotron infrared nanospectroscopy (SINS) is a technique that combines the nanoscale spatial resolution of scattering-type scanning near-field optical microscopy with ultrabroadband synchrotron infrared radiation, making it highly suitable to probe and characterize a variety of vdW polaritons. In this work, the advances enabled by SINS on the study of key photonic attributes of far- and mid-infrared plasmon- and phonon-polaritons in vdW and 2D crystals are reviewed. In that context the SINS technique is comprehensively described and it is demonstrated how fundamental polaritonic properties are retrieved for a range of atomically thin systems including hBN, MoS2, graphene and 2D heterostructures. 2
Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
CNPq; São Paulo Research Foundation; USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1775370
Alternate ID(s):
OSTI ID: 1577874
Journal Information:
Advanced Optical Materials, Journal Name: Advanced Optical Materials Journal Issue: 5 Vol. 8; ISSN 2195-1071
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English

References (131)

Fourier Transform Infrared Spectrometry book June 2007
Launching Phonon Polaritons by Natural Boron Nitride Wrinkles with Modifiable Dispersion by Dielectric Environments journal August 2017
Density functional investigation of the thermophysical and thermochemical properties of talc [Mg3Si4O10(OH)2] journal August 2014
Graphene-plasmon polaritons: From fundamental properties to potential applications journal February 2016
Scanning probe optical microscopy using a metallic probe tip journal February 1995
Enhancing the response of NH3 graphene-sensors by using devices with different graphene-substrate distances journal August 2018
Strain engineering in graphene journal August 2012
Enhanced Light Emission from Large-Area Monolayer MoS 2 Using Plasmonic Nanodisc Arrays journal March 2015
Infrared Vibrational Nanospectroscopy by Self-Referenced Interferometry journal December 2015
Ultraconfined Plasmonic Hotspots Inside Graphene Nanobubbles journal November 2016
Photoinduced Force Mapping of Plasmonic Nanostructures journal November 2016
Visualizing Strain-Induced Pseudomagnetic Fields in Graphene through an hBN Magnifying Glass journal April 2017
Efficiency of Launching Highly Confined Polaritons by Infrared Light Incident on a Hyperbolic Material journal August 2017
Nanoscale Mapping and Spectroscopy of Nonradiative Hyperbolic Modes in Hexagonal Boron Nitride Nanostructures journal February 2018
Anisotropic Flow Control and Gate Modulation of Hybrid Phonon-Polaritons journal January 2019
Phonon Polariton-assisted Infrared Nanoimaging of Local Strain in Hexagonal Boron Nitride journal February 2019
Phonon Polaritonics in Two-Dimensional Materials journal March 2019
van der Waals Layered Materials: Opportunities and Challenges journal October 2016
Infrared Nanospectroscopy of Phospholipid and Surfactin Monolayer Domains journal April 2018
Amplitude- and Phase-Resolved Nanospectral Imaging of Phonon Polaritons in Hexagonal Boron Nitride journal June 2015
Infrared Fingerprints of Natural 2D Talc and Plasmon–Phonon Coupling in Graphene–Talc Heterostructures journal April 2018
Multifrequency Superscattering from Subwavelength Hyperbolic Structures journal January 2018
Far Infrared Synchrotron Near-Field Nanoimaging and Nanospectroscopy journal December 2017
Expanding the Spectral Tunability of Plasmonic Resonances in Doped Metal-Oxide Nanocrystals through Cooperative Cation–Anion Codoping journal August 2014
Indium Tin Oxide Nanoparticles with Compositionally Tunable Surface Plasmon Resonance Frequencies in the Near-IR Region journal December 2009
Defect Chemistry and Plasmon Physics of Colloidal Metal Oxide Nanocrystals journal April 2014
Infrared Nanoscopy of Dirac Plasmons at the Graphene–SiO 2 Interface journal October 2011
Tunable Infrared Absorption and Visible Transparency of Colloidal Aluminum-Doped Zinc Oxide Nanocrystals journal November 2011
Nano-FTIR Absorption Spectroscopy of Molecular Fingerprints at 20 nm Spatial Resolution journal July 2012
Local Strain Engineering in Atomically Thin MoS 2 journal October 2013
Dielectric Screening of Excitons and Trions in Single-Layer MoS 2 journal September 2014
Emerging Photoluminescence in Monolayer MoS2 journal April 2010
Graphene Photonics, Plasmonics, and Broadband Optoelectronic Devices journal May 2012
Graphene Plasmonics for Terahertz to Mid-Infrared Applications journal January 2014
Near-field probing of vibrational absorption for chemical microscopy journal May 1999
Ultimate upgrade for US synchrotron journal September 2013
X-ray science: The big guns journal January 2014
Next-generation X-ray source fires up journal August 2015
Phonon-enhanced light–matter interaction at the nanometre scale journal July 2002
Gate-tuning of graphene plasmons revealed by infrared nano-imaging journal June 2012
Optical nano-imaging of gate-tunable graphene plasmons journal June 2012
Van der Waals heterostructures journal July 2013
Direct observation of narrow mid-infrared plasmon linewidths of single metal oxide nanocrystals journal May 2016
Nanoimaging of resonating hyperbolic polaritons in linear boron nitride antennas journal June 2017
Mechanical properties of atomically thin boron nitride and the role of interlayer interactions journal June 2017
Subdiffractional focusing and guiding of polaritonic rays in a natural hyperbolic material journal April 2015
Hyperbolic phonon-polaritons in boron nitride for near-field optical imaging and focusing journal June 2015
Infrared-spectroscopic nanoimaging with a thermal source journal April 2011
Highly confined low-loss plasmons in graphene–boron nitride heterostructures journal December 2014
Reversible optical switching of highly confined phonon–polaritons with an ultrathin phase-change material journal May 2016
Mixed-dimensional van der Waals heterostructures journal August 2016
Polaritons in layered two-dimensional materials journal November 2016
Infrared nanoscopy of strained semiconductors journal January 2009
Graphene plasmonics for tunable terahertz metamaterials journal September 2011
Control of valley polarization in monolayer MoS2 by optical helicity journal June 2012
Electronic and plasmonic phenomena at graphene grain boundaries journal October 2013
Graphene on hexagonal boron nitride as a tunable hyperbolic metamaterial journal June 2015
Acoustic terahertz graphene plasmons revealed by photocurrent nanoscopy journal October 2016
Graphene plasmonics journal November 2012
Two-dimensional material nanophotonics journal November 2014
Direct observation of ultraslow hyperbolic polariton propagation with negative phase velocity journal September 2015
Naturally hyperbolic journal March 2015
Real-space mapping of tailored sheet and edge plasmons in graphene nanoresonators journal March 2016
Ultrafast optical switching of infrared plasmon polaritons in high-mobility graphene journal March 2016
Imaging exciton–polariton transport in MoSe2 waveguides journal May 2017
Energy gaps and a zero-field quantum Hall effect in graphene by strain engineering journal September 2009
Selective excitation and imaging of ultraslow phonon polaritons in thin hexagonal boron nitride crystals journal June 2018
Superlight inverse Doppler effect journal July 2018
Photonics with hexagonal boron nitride journal July 2019
Fundamental limits to graphene plasmonics journal May 2018
In-plane anisotropic and ultra-low-loss polaritons in a natural van der Waals crystal journal October 2018
Plasmon modes in graphene: status and prospect journal January 2014
Graphene/h-BN plasmon–phonon coupling and plasmon delocalization observed by infrared nano-spectroscopy journal January 2015
Graphene, hexagonal boron nitride, and their heterostructures: properties and applications journal January 2017
Single metal nanoparticle absorption spectroscopy and optical characterization journal February 2006
Ultrabroadband infrared nanospectroscopic imaging journal May 2014
The transition metal dichalcogenides discussion and interpretation of the observed optical, electrical and structural properties journal May 1969
Two-dimensional crystals-based heterostructures: materials with tailored properties journal January 2012
Polaritons: the electromagnetic modes of media journal July 1974
Plasmonics in Dirac systems: from graphene to topological insulators journal March 2014
Simulation study of near-field enhancement on a laser-irradiated AFM metal probe journal May 2013
Electronic and optical properties of strained graphene and other strained 2D materials: a review journal August 2017
Experimental and theoretical investigations of monolayer and few-layer talc journal February 2015
Spontaneous doping on high quality talc-graphene-hBN van der Waals heterostructures journal July 2017
Near-field microscopy by elastic light scattering from a tip
  • Keilmann, Fritz; Hillenbrand, Rainer
  • Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 362, Issue 1817 https://doi.org/10.1098/rsta.2003.1347
journal April 2004
Broadband-infrared assessment of phonon resonance in scattering-type near-field microscopy journal January 2011
Near-field spectroscopy of silicon dioxide thin films journal February 2012
Plasmons and screening in a monolayer of MoS 2 journal July 2013
Strained hexagonal boron nitride: Phonon shift and Grüneisen parameter journal June 2018
Strain Engineering of Graphene’s Electronic Structure journal July 2009
Phase-Resolved Surface Plasmon Interferometry of Graphene journal July 2014
Near-Field Spectral Effects due to Electromagnetic Surface Excitations journal August 2000
Complex Optical Constants on a Subwavelength Scale journal October 2000
Drastic Reduction of Plasmon Damping in Gold Nanorods journal January 2002
Detection and Spectroscopy of Gold Nanoparticles Using Supercontinuum White Light Confocal Microscopy journal July 2004
Electron mobility enhancement in strained-Si n-type metal-oxide-semiconductor field-effect transistors journal March 1994
NMOS and PMOS transistors fabricated in strained silicon/relaxed silicon-germanium structures conference January 1992
The Effect of General Strain on the Band Structure and Electron Mobility of Silicon journal September 2007
Ultra-confined mid-infrared resonant phonon polaritons in van der Waals nanostructures journal June 2018
Transient exciton-polariton dynamics in WSe 2 by ultrafast near-field imaging journal February 2019
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene journal July 2008
Strain-Induced Pseudo-Magnetic Fields Greater Than 300 Tesla in Graphene Nanobubbles journal July 2010
Tunable Phonon Polaritons in Atomically Thin van der Waals Crystals of Boron Nitride journal March 2014
Controlling graphene plasmons with resonant metal antennas and spatial conductivity patterns journal May 2014
Scanning Interferometric Apertureless Microscopy: Optical Imaging at 10 Angstrom Resolution journal August 1995
2D materials and van der Waals heterostructures journal July 2016
Large optical nonlinearity of indium tin oxide in its epsilon-near-zero region journal April 2016
Polaritons in van der Waals materials journal October 2016
Infrared hyperbolic metasurface based on nanostructured van der Waals materials journal February 2018
Two-Dimensional Material Nanophotonics text January 2014
Two-Dimensional Material Nanophotonics text January 2018
Infrared synchrotron radiation from electron storage rings journal January 1983
Near-field imaging and nano-Fourier-transform infrared spectroscopy using broadband synchrotron radiation journal January 2013
Characterization of semiconductor materials using synchrotron radiation-based near-field infrared microscopy and nano-FTIR spectroscopy journal January 2014
Nanoscale plasmonic phenomena in CVD-grown MoS_2 monolayer revealed by ultra-broadband synchrotron radiation based nano-FTIR spectroscopy and near-field microscopy journal January 2016
Nanoscale plasmonic phenomena in CVD-grown MoS_2 monolayer revealed by ultra-broadband synchrotron radiation based nano-FTIR spectroscopy and near-field microscopy: publisher’s note journal January 2016
Low-aberration beamline optics for synchrotron infrared nanospectroscopy journal January 2018
Integrated nanophotonics based on nanowire plasmons and atomically thin material journal January 2014
Role of epsilon-near-zero substrates in the optical response of plasmonic antennas journal January 2016
Hyperbolic phonon-polaritons in boron nitride for near-field optical imaging and focusing text January 2015
Near-field spectroscopy of silicon dioxide thin films text January 2011
Infrared nanoscopy of Dirac plasmons at the graphene-SiO2 interface text January 2011
Plasmons and screening in a monolayer of MoS$_2$ text January 2013
Subdiffractional focusing and guiding of polaritonic rays in a natural hyperbolic material text January 2015
Mixed-Dimensional van der Waals Heterostructures text January 2016
2D materials and van der Waals heterostructures text January 2016
Visualizing Strain-induced Pseudo magnetic Fields in Graphene through an hBN Magnifying Glass text January 2017
Selective excitation and imaging of ultraslow phonon polaritons in thin hexagonal boron nitride crystals preprint January 2017
Enhancing the response of NH3 graphene-sensors by using devices with different graphene-substrate distances text January 2018
Phonon polaritonics in two-dimensional materials text January 2019
Mechanical Properties of Atomically Thin Boron Nitride and the Role of Interlayer Interactions text January 2020