Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m-Cresol

Hong, Yongchun; Zhang, He; Sun, Junming; Ayman, Karim M.; Hensley, Alyssa R.; Gu, Meng; Engelhard, Mark H.; McEwen, Jean-Sabin; Wang, Yong

doi:10.1021/cs500578g

Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m-Cresol

Journal Article · Tue Jul 29 00:00:00 EDT 2014 · ACS Catalysis

DOI:https://doi.org/10.1021/cs500578g· OSTI ID:1773667

Hong, Yongchun ^[1]; Zhang, He ^[2]; Sun, Junming ^[2]; Ayman, Karim M. ^[3]; Hensley, Alyssa R. ^[2]; Gu, Meng ^[3]; Engelhard, Mark H. ^[3]; McEwen, Jean-Sabin ^[2]; Wang, Yong ^[4]

Washington State Univ., Pullman, WA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Washington State University
Washington State Univ., Pullman, WA (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Washington State Univ., Pullman, WA (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Here, a series of Pd/Fe₂O₃ catalysts were synthesized, characterized, and evaluated for the hydrodeoxygenation (HDO) of m-cresol. It was found that the addition of Pd remarkably promotes the catalytic activity of Fe while the product distributions resemble that of monometallic Fe catalyst, showing high selectivity toward the production of toluene (C–O cleavage without saturation of aromatic ring and C–C cleavage). Reduced catalysts featured with Pd patches on the top of reduced Fe nanoparticle surface, and the interaction between Pd and Fe, was further confirmed using X-ray photoelectron spectroscopy (XPS), scanning transmission electron microscopy (STEM), and X-ray absorption near edge fine structure (XANES). A possible mechanism, including Pd assisted H₂ dissociation and Pd facilitated stabilization of the metallic Fe surface as well as Pd enhanced product desorption, is proposed to be responsible for the high activity and HDO selectivity in Pd–Fe catalysts. The synergic catalysis derived from Pd–Fe interaction found in this work was proved to be applicable to other precious metal promoted Fe catalysts, providing a promising strategy for future design of highly active and selective HDO catalysts.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Delaware, Newark, DE (United States). Synchrotron Catalysis Consortium (SCC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: FG02-05ER15688

OSTI ID:: 1773667

Alternate ID(s):: OSTI ID: 1229432
OSTI ID: 1170077

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 10 Vol. 4; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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