Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m-Cresol

Hong, Yongchun; Zhang, He; Sun, Junming; Karim, Ayman M.; Hensley, Alyssa; Gu, Meng; Engelhard, Mark H.; McEwen, Jean-Sabin; Wang, Yong

doi:10.1021/cs500578g

Synergistic Catalysis between Pd and Fe in Gas Phase Hydrodeoxygenation of m-Cresol

Journal Article · Fri Oct 31 04:00:00 EDT 2014 · ACS Catalysis, 4(10):3335-3345

DOI:https://doi.org/10.1021/cs500578g· OSTI ID:1170077

Hong, Yongchun; Zhang, He; Sun, Junming; Karim, Ayman M.; Hensley, Alyssa; Gu, Meng; Engelhard, Mark H.; McEwen, Jean-Sabin; Wang, Yong

In this work, a series of Pd/Fe2O3 catalysts were synthesized, characterized, and evaluated for the hydrodeoxygenation (HDO) of m-cresol. It was found that the addition of Pd remarkably promotes the catalytic activity of Fe while the product distributions resemble that of monometallic Fe catalyst, showing high selectivity towards the production of toluene (C-O cleavage without saturation of aromatic ring and C-C cleavage). Reduced catalysts featured with Pd patches on the top of reduced Fe nanoparticle surface, and the interaction between Pd and Fe was further confirmed using X-ray photoelectron spectroscopy (XPS), scanning transmission electron microscopy (STEM) and X-ray absorption near edge fine structure (XANES). A possible mechanism, including Pd assisted H2 dissociation and Pd facilitated stabilization of metallic Fe surface as well as Pd enhanced product desorption, is proposed to be responsible for the high activity and HDO selectivity in Pd-Fe catalysts. The synergic catalysis derived from Pd-Fe interaction found in this work was proved to be applicable to other precious metal promoted Fe catalysts, providing a promising strategy for future design of highly active and selective HDO catalysts.

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1170077

Report Number(s):: PNNL-SA--102420; 47660; KC0302010

Journal Information:: ACS Catalysis, 4(10):3335-3345, Journal Name: ACS Catalysis, 4(10):3335-3345

Country of Publication:: United States

Language:: English

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