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Sodium-halogen secondary cell

Patent ·
OSTI ID:1771696

An intermediate temperature sodium-halogen secondary cell that includes a negative electrode compartment housing a negative, molten sodium-based electrode and a positive electrode compartment housing a current collector disposed in a highly conductive molten positive electrolyte. A sodium halide (NaX) positive electrode is disposed in a molten positive electrolyte comprising one or more AlX3 salts, wherein X may be the same or different halogen selected from Cl, Br, and I, wherein the ratio of NaX to AlX3 is greater than or equal to one. A sodium ion conductive solid electrolyte membrane separates the molten sodium negative electrode from the molten positive electrolyte. The secondary cell operates at a temperature in the range from about 80° C. to 210° C.

Research Organization:
Field Upgrading USA, Inc., Broomfield, CO (United States)
Sponsoring Organization:
USDOE
Assignee:
Field Upgrading USA, Inc. (Broomfield, CO)
Patent Number(s):
10,854,929
Application Number:
14/956,078
OSTI ID:
1771696
Country of Publication:
United States
Language:
English

References (10)

A low temperature NaS battery incorporating A soluble S cathode journal June 1978
A review of the electrochemical performance of alloy anodes for lithium-ion batteries journal January 2011
Cation Electrochemical Stability in Chloroaluminate Ionic Liquids journal October 2005
Ionic-liquid materials for the electrochemical challenges of the future journal July 2009
XAFS analysis of triiodide ion in solutions journal March 2001
A Solid Sulfur Cathode for Aqueous Batteries journal August 1993
Electrochemical Investigation of Quaternary Ammonium/Aluminum Chloride Ionic Liquids journal January 2004
The Role of Additives in the Electroreduction of Sodium Ions in Chloroaluminate-Based Ionic Liquids journal January 2005
Dentrite-Free Electrochemical Deposition of Li–Na Alloys from an Ionic Liquid Electrolyte journal January 2006
Erratum journal April 2010

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