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Metal phosphide nanomaterials prepared from single source metal amides

Patent ·
OSTI ID:1771629
; ; ;
The present invention provides a novel solution or route for metal phosphide (MPx) nanomaterials from the thermal decomposition of metal bis[bis(diisopropylphosphino)amide], M[N(PPri2)2]2, and/or single-source precursors. Synthetic routes to MPx nanomaterials may be used in energy applications including batteries, semiconductors, magnets, catalyst, lasers, inks, electrocatalysts and photodiodes.
Research Organization:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC04-94AL85000
Assignee:
UNM Rainforest Innovations (Albuquerque, NM)
Patent Number(s):
10,836,638
Application Number:
15/565,670
OSTI ID:
1771629
Country of Publication:
United States
Language:
English

References (6)

Germanium phosphide coatings from the atmospheric pressure chemical vapour deposition of GeX4 (X=Cl or Br) and PCychexH2 journal July 2003
Synthesis and Characterization of Supported Co 2 P Nanoparticles by Grafting of Molecular Clusters into Mesoporous Silica Matrixes journal November 2002
Stoichiometric molecular single source precursors to cobalt phosphides journal January 2014
Hexanuclear Gold(I) Phosphide Complexes as Platforms for Multiple Redox-Active Ferrocenyl Units journal December 2013
Au 19 Nanocluster Featuring a V-Shaped Alkynyl–Gold Motif journal January 2015
A Novel Solvothermal Route to Nanocrystalline Sn4P3 with Red Phosphorous as Raw Material journal June 2013

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