Bifunctional metal phosphide FeMnP films from single source metal organic chemical vapor deposition for efficient overall water splitting

Zhao, Zhenhuan; Schipper, Desmond E.; Leitner, Andrew P.; Thirumalai, Hari; Chen, Jing-Han; Xie, Lixin; Qin, Fan; Alam, Md Kamrul; Grabow, Lars C.; Chen, Shuo; Wang, Dezhi; Ren, Zhifeng; Wang, Zhiming; Whitmire, Kenton H.; Bao, Jiming

doi:10.1016/j.nanoen.2017.07.027

Bifunctional metal phosphide FeMnP films from single source metal organic chemical vapor deposition for efficient overall water splitting

Journal Article · Thu Jul 20 00:00:00 EDT 2017 · Nano Energy

DOI:https://doi.org/10.1016/j.nanoen.2017.07.027· OSTI ID:1478401

Zhao, Zhenhuan ^[1]; Schipper, Desmond E. ^[2]; Leitner, Andrew P. ^[2]; Thirumalai, Hari ^[3]; Chen, Jing-Han ^[2]; Xie, Lixin ^[4]; Qin, Fan ^[5]; Alam, Md Kamrul ^[6]; Grabow, Lars C. ^[3]; Chen, Shuo ^[4]; Wang, Dezhi ^[4]; Ren, Zhifeng ^[4]; Wang, Zhiming ^[7]; Whitmire, Kenton H. ^[2]; Bao, Jiming ^[1]

Univ. of Electronic Science and Technology of China, Chengdu (China). Inst. of Fundamental and Frontier Sciences; Univ. of Houston, Houston, TX (United States). Dept. of Electrical and Computer Engineering
Rice Univ., Houston, TX (United States). Dept. of Chemistry
Univ. of Houston, Houston, TX (United States). Dept. of Chemical and Biomolecular Engineering
Univ. of Houston, Houston, TX (United States). Dept. of Physics and Texas Center for Superconductivity
Univ. of Houston, Houston, TX (United States). Dept. of Electrical and Computer Engineering
Univ. of Houston, TX (United States). Dept. of Electrical and Computer Engineering
Univ. of Electronic Science and Technology of China, Chengdu (China). Inst. of Fundamental and Frontier Sciences

Developing stable and efficient bifunctional catalysts for overall water splitting into hydrogen and oxygen is a critical step in the realization of several clean-energy technologies. Here we report a robust and highly active electrocatalyst that is constructed by deposition of the ternary metal phosphide FeMnP onto graphene-protected nickel foam by metal-organic chemical vapor deposition from a single source precursor. FeMnP exhibits high electrocatalytic activity toward both the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). Utilizing FeMnP/GNF as both the anode and the cathode for overall water splitting, a current density of 10 mA cm^-2 is achieved at a cell voltage of as low as 1.55 V with excellent stability. Complementary density functional theory (DFT) calculations suggest that facets exposing both Fe and Mn sites are necessary to achieve high HER activity. The present work provides a facile strategy for fabricating highly efficient electrocatalysts from earth-abundant materials for overall water splitting.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)

Sponsoring Organization:: National Science Foundation (NSF); Robert A. Welch Foundation; USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1478401

Alternate ID(s):: OSTI ID: 1550024
OSTI ID: 22903328

Journal Information:: Nano Energy, Journal Name: Nano Energy Journal Issue: C Vol. 39; ISSN 2211-2855

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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