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The formation and evolution of the Moon’s crust inferred from the Sm-Nd isotopic systematics of highlands rocks

Journal Article · · Geochimica et Cosmochimica Acta
 [1];  [1];  [1];  [1];  [2]
  1. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
  2. Univ. of New Mexico, Albuquerque, NM (United States)

Ages determined for magnesian and ferroan anorthosite crustal rock suites overlap, suggesting they formed contemporaneously about 4.3–4.5 Ga. A notable exception is the Sm-Nd age previously determined on Mg-suite gabbronorite 67667 which is at least 100 Ma younger than the youngest ferroan anorthosite. New chronologic measurements of 67667 presented here yield concordant Sm-Nd and Rb-Sr mineral isochron ages of 4349 ± 31 Ma and 4368 ± 67 Ma, suggesting the sample is older than previous estimates. Furthermore, a whole rock Sm-Nd isochron of Mg-suite rocks from the Apollo 14, 15, 16, and 17 landing sites yields an age of 4348 ± 25 Ma, indicating that Mg-suite magmatism was widespread and roughly contemporaneous on the lunar nearside. Here, analysis of Sm-Nd internal isochron ages confirms that Mg-suite magmatism was restricted to a period between about 4.33 and 4.35 Ga at the Apollo 14, 15, 16, and 17 landing sites and was synchronous with magmatism at the Apollo 16 site associated with the ferroan anorthosite suite between 4.35 and 4.37 Ga. Magnesian- and ferroan anorthosite suite rocks with ages younger than ~4.33 Ga appear to have experienced slow cooling in the deep lunar interior, so that the ages record when the samples cooled below the closure temperature of the Sm-Nd isotopic system and not the time they crystallized.

Research Organization:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA); NASA Emerging Worlds Program
Grant/Contract Number:
AC52-07NA27344
OSTI ID:
1771024
Alternate ID(s):
OSTI ID: 1810920
OSTI ID: 1771028
Report Number(s):
LLNL-JRNL--810106; 1016585
Journal Information:
Geochimica et Cosmochimica Acta, Journal Name: Geochimica et Cosmochimica Acta Journal Issue: na Vol. 290; ISSN 0016-7037
Publisher:
Elsevier; The Geochemical Society; The Meteoritical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (80)

Rb-Sr ages of clasts from within Boulder 1, Station 2, Apollo 17 journal January 1975
40Ar-39Ar ages and cosmic ray exposure ages of Apollo 14 samples journal September 1971
Subcommission on geochronology: Convention on the use of decay constants in geo- and cosmochronology journal October 1977
SmNd constraints on early lunar differentiation and the evolution of KREEP journal October 1979
Sm-Nd age of lherzolite 67667: implications for the processes involved in lunar crustal formation journal December 1981
Time and duration of lunar highlands crust formation journal February 1981
A model for the thermal and chemical evolution of the Moon's interior: implications for the onset of mare volcanism journal September 1995
K-Ar-Altersbestimmungen an Eisenmeteoriten—II spallogenes Ar40 und Ar40-Ar38-Bestrahlungsalter journal October 1966
Precise determination of initial ϵNd from Sm-Nd isochron data journal October 1982
Abundances of the elements: Meteoritic and solar journal January 1989
Phase transformations and their bearing on the constitution and dynamics of the mantle journal August 1991
A chemical model for generating the sources of mare basalts: Combined equilibrium and fractional crystallization of the lunar magmasphere journal October 1992
The isotopic record of lunar volcanism journal June 1992
Common asteroid break-up events of eucrites, diogenites, and howardites and cosmic-ray production rates for noble gases in achondrites journal January 1995
An ancient Sm-Nd age for a ferroan noritic anorthosite clast from lunar breccia 67016 journal July 1994
Chronology and petrogenesis of the lunar highlands alkali suite: Cumulates from KREEP basalt crystallization journal March 1995
146Sm-142Nd formation interval for the lunar mantle journal July 1995
Ion microprobe investigation of plagioclase and orthopyroxene from lunar Mg-suite norites: Implications for calculating parental melt REE concentrations and for assessing postcrystallization REE redistribution journal October 1996
Re-examination of the lunar magma ocean cumulate overturn hypothesis: melting or mixing is required journal March 2002
Evolution of the lunar crust: SIMS study of plagioclase from ferroan anorthosites journal June 1997
Isotopic studies of ferroan anorthosite 62236: a young lunar crustal rock from a light rare-earth-element-depleted source journal October 1999
A highly depleted moon or a non-magma ocean origin for the lunar crust? journal October 2007
The Lu–Hf and Sm–Nd isotopic composition of CHUR: Constraints from unequilibrated chondrites and implications for the bulk composition of terrestrial planets journal August 2008
Age of the Dakhleh impact event and implications for Middle Stone Age archeology in the Western Desert of Egypt journal March 2010
The lunar magma ocean: Reconciling the solidification process with lunar petrology and geochronology journal April 2011
Isotopic evidence for chondritic Lu/Hf and Sm/Nd of the Moon journal October 2013
Lunar feldspathic meteorites: Constraints on the geology of the lunar highlands, and the origin of the lunar crust journal February 2014
Constraints on the formation age and evolution of the Moon from 142Nd–143Nd systematics of Apollo 12 basalts journal June 2014
Lead isotope evidence for a young formation age of the Earth–Moon system journal October 2016
Timing of mantle overturn during magma ocean solidification journal June 2018
The participation of ilmenite-bearing cumulates in lunar mantle overturn journal April 2019
Timescale of overturn in a magma ocean cumulate journal June 2019
Isotopic evidence for a young lunar magma ocean journal October 2019
The timing of lunar solidification and mantle overturn recorded in ferroan anorthosite 62237 journal May 2020
Early crustal building processes on the moon: Models for the petrogenesis of the magnesian suite journal July 2005
Oxygen isotopic signature of 4.4–3.9Ga zircons as a monitor of differentiation processes on the Moon journal April 2006
Feldspathic clasts in Yamato-86032: Remnants of the lunar crust with implications for its formation and impact history journal December 2006
Cooling history of lunar Mg-suite gabbronorite 76255, troctolite 76535 and Stillwater pyroxenite SC-936: The record in exsolution and ordering in pyroxenes journal December 2006
Complex history of a zircon aggregate from lunar breccia 73235 journal March 2007
Solar and cosmogenic argon in dated lunar impact spherules journal March 2007
SIMS U–Pb study of zircon from Apollo 14 and 17 breccias: Implications for the evolution of lunar KREEP journal January 2008
A combined Sm–Nd, Rb–Sr, and U–Pb isotopic study of Mg-suite norite 78238: Further evidence for early differentiation of the Moon journal January 2009
Thermal history recorded by the Apollo 17 impact melt breccia 73217 journal May 2009
Mechanisms for incompatible-element enrichment on the Moon deduced from the lunar basaltic meteorite Northwest Africa 032 journal July 2009
Re-evaluating 142Nd/144Nd in lunar mare basalts with implications for the early evolution and bulk Sm/Nd of the Moon journal October 2009
The pattern of Ni and Co abundances in lunar olivines journal January 2010
Complex magmatic and impact history prior to 4.1Ga recorded in zircon from Apollo 17 South Massif aphanitic breccia 73235 journal April 2011
Response to the comment by W.H. Schwarz et al. on “Joint determination of 40K decay constants and 40Ar∗/40K for the Fish Canyon sanidine standard, and improved accuracy for 40Ar/39Ar geochronology” by P.R. Renne et al. (2010) journal September 2011
Origin of sulfide replacement textures in lunar breccias. Implications for vapor element transport in the lunar crust journal April 2012
Chromite symplectites in Mg-suite troctolite 76535 as evidence for infiltration metasomatism of a lunar layered intrusion journal June 2012
A young solidification age for the lunar magma ocean journal September 2014
Sm–Nd systematics of lunar ferroan anorthositic suite rocks: Constraints on lunar crust formation journal January 2015
Paleotemperatures at the lunar surfaces from open system behavior of cosmogenic 38Ar and radiogenic 40Ar journal April 2015
Chronologic implications for slow cooling of troctolite 76535 and temporal relationships between the Mg-suite and the ferroan anorthosite suite journal March 2017
Geochronology of an Apollo 16 Clast Provides Evidence for a Basin‐Forming Impact 4.3 Billion Years Ago journal October 2019
Geochemistry and Petrogenesis of Northwest Africa 10401: A New Type of the Mg‐Suite Rocks journal May 2020
Lunar ferroan anorthosites and mare basalt sources: The mixed connection journal November 1991
Petrogenesis of lunar troctolites journal January 1994
Chemical composition of the mantle journal January 1983
Subdivision of the Mg-suite noritic rocks into Mg-gabbronorites and Mg-norites journal January 1983
Anorthosite assimilation and the origin of the Mg/Fe-related bimodality of pristine moon rocks: Support for the magmasphere hypothesis journal March 1986
Chronological evidence that the Moon is either young or did not have a global magma ocean journal August 2011
Timing of crystallization of the lunar magma ocean constrained by the oldest zircon journal January 2009
Evidence of extensive lunar crust formation in impact melt sheets 4,330 Myr ago journal May 2020
Early Moon formation inferred from hafnium–tungsten systematics journal July 2019
Early crust building enhanced on the Moon’s nearside by mantle melting-point depression journal March 2020
Rb-Sr, Sm-Nd and Lu-Hf isotope systematics of the lunar Mg-suite: the age of the lunar crust and its relation to the time of Moon formation
  • Carlson, Richard W.; Borg, Lars E.; Gaffney, Amy M.
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 372, Issue 2024 https://doi.org/10.1098/rsta.2013.0246
journal September 2014
Uranium-lead ages for lunar zircons: Evidence for a prolonged period of granophyre formation from 4.32 to 3.88 Ga journal May 1996
The comparative behavior of apatite-zircon U-Pb systems in Apollo 14 breccias: Implications for the thermal history of the Fra Mauro Formation journal November 2009
A review of lunar chronology revealing a preponderance of 4.34-4.37 Ga ages journal November 2014
Early formation of the Moon 4.51 billion years ago journal January 2017
Chronology of martian breccia NWA 7034 and the formation of the martian crustal dichotomy journal May 2018
A long-lived magma ocean on a young Moon journal July 2020
Neodymium Isotope Evidence for a Chondritic Composition of the Moon journal June 2006
Time Scales of Critical Events Around the Cretaceous-Paleogene Boundary journal February 2013
KREEP cumulates in the western lunar highlands; ion and electron microprobe study of alkali-suite anorthosites and norites from Apollo 12 and 14 journal June 1999
The distribution of Mg-spinel across the Moon and constraints on crustal origin journal October 2014
Origin of the lunar highlands Mg-suite: An integrated petrology, geochemistry, chronology, and remote sensing perspective journal December 2014
Formation of the lunar highlands Mg-suite as told by spinel journal July 2016
Cosmic-Ray-Produced Noble Gases in Meteorites journal January 2002

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