An Americium-Containing Metal-Organic Framework: A Platform for Studying Transplutonium Elements

Ridenour, James A.; Surbella, Robert G.; Gelis, Artem V.; Koury, Daniel; Poineau, Frederic; Czerwinski, Kenneth R.; Cahill, Christopher L.

doi:10.1002/anie.201909988

Title: An Americium-Containing Metal-Organic Framework: A Platform for Studying Transplutonium Elements

Journal Article · Mon Nov 11 00:00:00 EST 2019 · Angewandte Chemie International Edition

DOI:https://doi.org/10.1002/anie.201909988· OSTI ID:1768594

Ridenour, James A. ^[1];

^[2]; Gelis, Artem V. ^[3]; Koury, Daniel ^[3]; Poineau, Frederic ^[3]; Czerwinski, Kenneth R. ^[3]; Cahill, Christopher L. ^[4]

VISITORS
BATTELLE (PACIFIC NW LAB)
University of Nevada, Las Vegas
GEORGE WASHINGTON UNIV

The synthesis, structural and spectroscopic characterization of the first transplutonium metal-organic framework (MOF) is described. The preparation and structure of Am GWMOF-6, [Am2(C6H8O4)3(H2O)2][(C10H8N2)], is analogous to that of the isostructural trivalent lanthanide-only containing material GWMOF-6. The presented MOF architecture is used as a plat-form to probe Am3+ coordination chemistry and guest-enhanced luminescent emission, whereas the framework itself provided a means to monitor the effects of self-irradiation upon crystallinity over time. Presented here is a discussion of these properties and the opportunities that metal-organic frameworks provide in the structural and spectroscopic study of actinides.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1768594

Report Number(s):: PNNL-SA-145892

Journal Information:: Angewandte Chemie International Edition, Vol. 58, Issue 46

Country of Publication:: United States

Language:: English

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