An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements

Ridenour, J. August; Surbella, III, Robert G.; Gelis, Artem V.; Koury, Daniel; Poineau, Frederic; Czerwinski, Kenneth R.; Cahill, Christopher L.

doi:10.1002/ange.201909988

Title: An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements

Journal Article · Mon Sep 30 00:00:00 EDT 2019 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201909988· OSTI ID:1567888

Ridenour, J. August ^[1]; Surbella, III, Robert G. ^[2]; Gelis, Artem V. ^[3]; Koury, Daniel ^[3]; Poineau, Frederic ^[3]; Czerwinski, Kenneth R. ^[3];

^[1]

Department of Chemistry The George Washington University 800 22^nd St NW Washington D.C. 20052 USA
Pacific Northwest National Laboratory 902 Battelle Boulevard Richland WA 99354 USA
Radiochemistry Department of Chemistry and Biochemistry University of Nevada Las Vegas 4505 S. Maryland Pkwy Las Vegas NV 89154 USA

Abstract The synthesis, structure, and spectroscopic characterization of the first transplutonium metal–organic framework (MOF) is described. The preparation and structure of Am‐GWMOF‐6, [Am ₂ (C ₆ H ₈ O ₄ ) ₃ (H ₂ O) ₂ ][(C ₁₀ H ₈ N ₂ )], is analogous to that of the isostructural trivalent lanthanide‐only containing material GWMOF‐6. The presented MOF architecture is used as a platform to probe Am ³⁺ coordination chemistry and guest‐enhanced luminescent emission, whereas the framework itself provides a means to monitor the effects of self‐irradiation upon crystallinity over time. Presented here is a discussion of these properties and the opportunities that MOFs provide in the structural and spectroscopic study of actinides.

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Sponsoring Organization:: USDOE

OSTI ID:: 1567888

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 131 Journal Issue: 46; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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