Solvation Rule for Solid-Electrolyte Interphase Enabler in Lithium-Metal Batteries

Su, Chi‐Cheung; He, Meinan; Shi, Jiayan; Amine, Rachid; Zhang, Jian; Amine, Khalil

doi:10.1002/anie.202008081

Solvation Rule for Solid-Electrolyte Interphase Enabler in Lithium-Metal Batteries

Journal Article · Tue Jul 07 00:00:00 UTC 2020 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.202008081· OSTI ID:1756578

Su, Chi‐Cheung ^[1]; He, Meinan ^[1]; Shi, Jiayan ^[2]; Amine, Rachid ^[1]; Zhang, Jian ^[3]; ^[4]

Argonne National Lab. (ANL), Argonne, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of California, Riverside, CA (United States)
Univ. of California, Riverside, CA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States); Stanford Univ., CA (United States); Imam Abdulrahman Bin Faisal Univ. (IAU), Dammam (Saudi Arabia)

Despite the exceptionally high energy density of lithium metal anodes, the practical application of lithium-metal batteries (LMBs) is still impeded by the instability of the interphase between the lithium metal and the electrolyte. To formulate a functional electrolyte system that can stabilize the lithium-metal anode, the solvation behavior of the solvent molecules must be understood because the electrochemical properties of a solvent can be heavily influenced by its solvation status. Here, we unambiguously demonstrated the solvation rule for the solid-electrolyte interphase (SEI) enabler in an electrolyte system. In this study, fluoroethylene carbonate was used as the SEI enabler due to its ability to form a robust SEI on the lithium metal surface, allowing relatively stable LMB cycling. The results revealed that the solvation number of fluoroethylene carbonate must be ≥ 1 to ensure the formation of a stable SEI in which the sacrificial reduction of the SEI enabler subsequently leads to the stable cycling of LMBs.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1756578

Alternate ID(s):: OSTI ID: 1647420
OSTI ID: 22956155

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 41 Vol. 59; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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