Effect of Laser Beam Profile on Rotating Lattice Single Crystal Growth in Sb2S3 Model Glass

Au-Yeung, Courtney; Savytskii, Dmytro; Veenhuizen, Keith; Dierolf, Volkmar; Jain, Himanshu

doi:10.3390/cryst11010036

Title: Effect of Laser Beam Profile on Rotating Lattice Single Crystal Growth in Sb2S3 Model Glass

Journal Article · Thu Dec 31 00:00:00 EST 2020 · Crystals

DOI:https://doi.org/10.3390/cryst11010036· OSTI ID:1755262

; Savytskii, Dmytro;

; Dierolf, Volkmar;

Laser heating of chalcogenide glasses has successfully produced rotating lattice single crystals through a solid-solid transformation. To better understand the nature of complex, orientation-dependent lattice rotation, we designed heat profiles of the continuous wave laser by beam shaping, fabricated larger Sb₂S₃ crystal dots in Sb₂S₃ glass, and investigated the lattice rotation where the crystal could grow in all radial directions under a circular thermal gradient. The results show that the rate of lattice rotation is highly anisotropic and depends on crystallographic direction. The nature of this rotation is the same in crystals of different orientation relative to the surface. The growth directions that align with the slip planes show the highest rate of rotation and the rotation rate gradually decreases away from this direction. Additionally, the presence of multiple growth directions results in a complicated rotation system. We suggest that the growth front influences the density of dislocations introduced during growth under confinement and thus affects the lattice rotation rate in these crystals.

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Research Organization:: Lehigh Univ., Bethlehem, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: DE SC0005010; SC0005010; DGE-1452783

OSTI ID:: 1755262

Alternate ID(s):: OSTI ID: 1850891

Journal Information:: Crystals, Journal Name: Crystals Vol. 11 Journal Issue: 1; ISSN 2073-4352

Publisher:: MDPI AGCopyright Statement

Country of Publication:: Germany

Language:: English

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36 MATERIALS SCIENCE
Crystallography
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single crystal growth
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Title: Effect of Laser Beam Profile on Rotating Lattice Single Crystal Growth in Sb2S3 Model Glass

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