A stable and highly selective metalloporphyrin based framework for the catalytic oxidation of cyclohexene

Xia, Zhinan; Li, Fengyan; Xu, Lin; Feng, Pingyun

doi:10.1039/d0dt01420f

A stable and highly selective metalloporphyrin based framework for the catalytic oxidation of cyclohexene

Journal Article · Fri Jul 17 00:00:00 EDT 2020 · Dalton Transactions

DOI:https://doi.org/10.1039/d0dt01420f· OSTI ID:1755097

Xia, Zhinan ^[1]; ^[2]; ^[3]; ^[4]

Northeast Normal Univ., Changchun, Jilin (China); UC Riverside
Northeast Normal Univ., Changchun, Jilin (China); Univ. of California, Riverside, CA (United States)
Northeast Normal Univ., Changchun, Jilin (China)
Univ. of California, Riverside, CA (United States)

A new metalloporphyrin framework of molybdenum Mo₂O₄(C₄₈H₂₈N₄O₈)·(CH₃)₂NH·5H₂O·2DMF (Mo₂TCPP) was synthesized from tetrakis(4-carboxyphenyl)porphyrin (H₄TCPP) and sodium molybdate dihydrate by a hydrothermal method. Mo₂TCPP is a 3D network with two sub-units, in which both TCPP ligands and each Mo₂ dimer act as four connection nodes. The crystal structure was determined by single crystal analysis and further characterized by FTIR, SEM, EDX, PXRD, XPS and TGA. Here cumene hydrogen peroxide and hydrogen peroxide were used as oxidants to study the catalytic activity of new metalloporphyrins in the oxidation of cyclohexene at different temperatures. The conversion rate of cyclohexene and the selectivity of epoxycyclohexane were both higher than 99%, which was better than the previously published research results. The stability of the catalyst before and after the reaction was further tested for 10 runs without obvious degradation. The catalyst was stable in different solutions such as acidic, water and alkaline. These results shed light on the future development of new catalytic materials based on metalloporphyrin.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Riverside, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: SC0010596

OSTI ID:: 1755097

Alternate ID(s):: OSTI ID: 1644355

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 32 Vol. 49; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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