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The early-stage growth and reversibility of Li electrodeposition in Br-rich electrolytes

Journal Article · · Proceedings of the National Academy of Sciences of the United States of America
 [1];  [1];  [1];  [2];  [3];  [1];  [1];  [1];  [4];  [5]
  1. Robert Frederick Smith School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853,
  2. Department of Materials Science and Engineering, Cornell University, Ithaca, NY 14853,
  3. School of Applied and Engineering Physics, Cornell University, Ithaca, NY 14853,
  4. School of Applied and Engineering Physics, Cornell University, Ithaca, NY 14853,, Kavli Institute at Cornell for Nanoscale Science, Cornell University, Ithaca, NY 14853
  5. Robert Frederick Smith School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853,, Department of Materials Science and Engineering, Cornell University, Ithaca, NY 14853,
Significance

Spatial variations in chemical composition and transport properties of the material phases (interphases) formed on reactive metals in liquid electrolytes are thought to be responsible for the propensity of metal battery electrodes to electrodeposit in irregular, nonplanar morphologies. Equilibrium theoretical calculations using joint density functional analysis in vacuum and generic liquid media indicate that in-plane transport at such interphases is enhanced substantially if LiX (X = Br > Cl > F) species predominate. This study employs optical visualization experiments and nucleation theory to experimentally investigate nucleation and early-stage growth dynamics of metallic lithium in electrolytes enriched with LiBr. It is shown that the Li-Br–rich interphases formed profoundly alter the morphology of Li electrodeposits by enhancing Li-ion surface diffusion.

Research Organization:
State Univ. of New York (SUNY), Albany, NY (United States)
Sponsoring Organization:
USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0012673
OSTI ID:
1749974
Alternate ID(s):
OSTI ID: 1851754
Journal Information:
Proceedings of the National Academy of Sciences of the United States of America, Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Issue: 2 Vol. 118; ISSN 0027-8424
Publisher:
Proceedings of the National Academy of SciencesCopyright Statement
Country of Publication:
United States
Language:
English

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