Synthesis and characterization of carboxyethylene-bridged bimetallic compounds

Journal Article · Tue Oct 31 23:00:00 EST 1995 · Organometallics

DOI:https://doi.org/10.1021/om00011a029· OSTI ID:174270

Gibson, D H; Franco, J O; Mehta, J M; Harris, M T; Ding, Y; Mashuta, M S; Richardson, J F ^[1]

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1. Univ. of Louisville, KY (United States)

The synthesis and characterization of carboxyethylene-bridged bimetallic complexes Cp{sup *}Re(CO)(NO)CO{sub 2}CH{sub 2}CH{sub 2}M (4, M = Mo(CO){sub 3}Cp; 7, M = W(CO){sub 3}Cp; 9, M = Fe(CO){sub 2}Cp) and CpFe(CO)(PPh{sub 3})CO{sub 2}CH{sub 2}CH{sub 2}W(CO){sub 3}Cp (11) are described. Thermolysis of 4, in solution or in the solid state, yields the CO{sub 2}-bridged compound Cp{sup *}Re(CO)(NO)(CO{sub 2} )Mo(CO){sub 2}Cp (3) as the major product. Compound 11 has been structurally characterized. Crystal data for 11 are reported. 16 refs., 1 fig., 3 tabs.

• Sponsoring Organization: USDOE
• OSTI ID: 174270
• Journal Information: Organometallics, Journal Name: Organometallics Journal Issue: 11 Vol. 14; ISSN 0276-7333; ISSN ORGND7
• Country of Publication: United States
• Language: English

Related Subjects

40 CHEMISTRY
CHEMICAL BONDS
CRYSTAL STRUCTURE
ETHYLENE
EXPERIMENTAL DATA
NMR SPECTRA
ORGANOMETALLIC COMPOUNDS
RHENIUM COMPLEXES
STRUCTURAL CHEMICAL ANALYSIS
SYNTHESIS
THERMOCHEMICAL PROCESSES
X-RAY DIFFRACTION