All-Solid-State Sodium Batteries with a Polyethylene Glycol Diacrylate–Na3Zr2Si2PO12 Composite Electrolyte

Yu, Xingwen; Xue, Leigang; Goodenough, John B.; Manthiram, Arumugam

doi:10.1002/aesr.202000061

Title: All-Solid-State Sodium Batteries with a Polyethylene Glycol Diacrylate–Na₃Zr₂Si₂PO₁₂ Composite Electrolyte

Journal Article · Thu Dec 10 00:00:00 EST 2020 · Advanced Energy and Sustainability Research

DOI:https://doi.org/10.1002/aesr.202000061· OSTI ID:1735387

Yu, Xingwen ^[1]; Xue, Leigang ^[1]; Goodenough, John B. ^[1];

^[1]

Materials Science &, Engineering Program and Texas Materials Institute The University of Texas at Austin Austin TX 78712 USA

A novel sodium‐ion conducting polymer–ceramic solid‐state composite electrolyte is developed for ambient‐temperature sodium batteries. Polyethylene glycol diacrylate (PEGDA) is used as a polymeric matrix into which ceramic nanoparticles of NASICON‐type Na ₃ Zr ₂ Si ₂ PO ₁₂ are integrated. The PEGDA polymeric phase of the composite can maintain an amiable ionic interface between the solid‐state electrolyte and electrodes. The Na ₃ Zr ₂ Si ₂ PO ₁₂ ceramic phase not only enhances the sodium‐ion conductivity of the composite but also can suppress the Na dendrites from penetrating through the electrolyte membrane. To optimize the Na ⁺ ‐ion conductivity, a succinonitrile (SCN) plasticizer is also incorporated. The composite solid electrolyte membranes are fabricated with an ultraviolet (UV) curing process. Through proper management of the composition, the PEGDA‐SCN‐Na ₃ Zr ₂ Si ₂ PO ₁₂ ‐NaClO ₄ composite solid electrolyte delivers an ionic conductivity of 4.5 × 10 ⁻⁴ S cm ⁻¹ at room temperature. All‐solid‐state Na cells with the PEGDA‐SCN‐NaClO ₄ ‐Na ₃ Zr ₂ Si ₂ PO ₁₂ composite electrolyte are fabricated by coupling a Na ₂ MnFe(CN) ₆ positive electrode to a Na‐metal negative electrode. The resulting Na ‖ PEGDA‐SCN‐NaClO ₄ ‐Na ₃ Zr ₂ Si ₂ PO ₁₂ ‖ Na ₂ MnFe(CN) ₆ cells show remarkable cycling stability.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0005397

OSTI ID:: 1735387

Alternate ID(s):: OSTI ID: 1786081

Journal Information:: Advanced Energy and Sustainability Research, Journal Name: Advanced Energy and Sustainability Research Vol. 2 Journal Issue: 1; ISSN 2699-9412

Publisher:: WileyCopyright Statement

Country of Publication:: Germany

Language:: English

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Title: All-Solid-State Sodium Batteries with a Polyethylene Glycol Diacrylate–Na₃Zr₂Si₂PO₁₂ Composite Electrolyte