Ambient‐Temperature All‐Solid‐State Sodium Batteries with a Laminated Composite Electrolyte

Yu, Xingwen; Xue, Leigang; Goodenough, John B.; Manthiram, Arumugam

doi:10.1002/adfm.202002144

Ambient‐Temperature All‐Solid‐State Sodium Batteries with a Laminated Composite Electrolyte

Journal Article · Wed May 13 00:00:00 EDT 2020 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.202002144· OSTI ID:1618505

Yu, Xingwen ^[1]; Xue, Leigang ^[1]; Goodenough, John B. ^[1]; ^[1]

Materials Science and Engineering Program and Texas Materials Institute The University of Texas at Austin Austin TX 78712 USA

Abstract

This study presents a sodium‐ion conductive laminated polymer/ceramic‐polymer solid‐state electrolyte for the development of room‐temperature all‐solid‐state sodium batteries. At the negative electrode side, a negative‐electrode‐benign poly(ethylene oxide) (PEO) is used as a polymer matrix into which succinonitrile (SN) is integrated to improve the room‐temperature Na ⁺ ‐ion conductivity. At the positive electrode side, a cathode‐friendly poly(acrylonitrile) (PAN) serves as a polymer matrix into which a NASICON‐type ceramic solid‐electrolyte (Na ₃ Zr ₂ Si ₂ PO ₁₂ ) powder is incorporated toward both the enhancement of Na ⁺ ‐ion conductivity and the prevention of Na dendrite from penetrating through the electrolyte membrane. Through a strategical management of composition, the PAN‐Na ₃ Zr ₂ Si ₂ PO ₁₂ ‐NaClO ₄ composite and the PEO‐SN‐NaClO ₄ polymer deliver a balanced Na ⁺ ‐ion conductivity. Combining the two electrolyte layers, the laminated PEO‐SN‐NaClO ₄ /PAN‐Na ₃ Zr ₂ Si ₂ PO ₁₂ ‐NaClO ₄ solid electrolyte provides a Na ⁺ ‐ion conductivity of 1.36 × 10 ⁻⁴ S cm ⁻¹ at room temperature. With respect to the anodic friendly feature of the PEO‐SN‐NaClO ₄ layer and the cathodic friendly feature of the PAN‐Na ₃ Zr ₂ Si ₂ PO ₁₂ ‐NaClO ₄ layer, the laminated solid electrolyte presents a stable electrochemical window of 0–4.8 V. Room‐temperature all‐solid‐state sodium batteries fabricated with the laminated solid electrolyte, a Na‐metal negative electrode, and a Na ₂ MnFe(CN) ₆ positive electrode exhibit remarkably stable cyclability.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0005397

OSTI ID:: 1618505

Alternate ID(s):: OSTI ID: 1850916

Journal Information:: Advanced Functional Materials, Journal Name: Advanced Functional Materials Journal Issue: 2 Vol. 31; ISSN 1616-301X

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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