High-rate electroreduction of carbon monoxide to multi-carbon products

Jouny, Matthew; Luc, Wesley; Jiao, Feng

doi:10.1038/s41929-018-0133-2

High-rate electroreduction of carbon monoxide to multi-carbon products

Journal Article · Mon Aug 20 04:00:00 EDT 2018 · Nature Catalysis

DOI:https://doi.org/10.1038/s41929-018-0133-2· OSTI ID:1712666

^[1]; ^[2]; ^[2]

Univ. of Delaware, Newark, DE (United States); University of Delaware
Univ. of Delaware, Newark, DE (United States)

Carbon monoxide electrolysis has previously been reported to yield enhanced multi-carbon (C₂₊) Faradaic efficiencies of up to ~55%, but only at low reaction rates. This is due to the low solubility of CO in aqueous electrolytes and operation in batch-type reactors. Here, we present a high-performance CO flow electrolyser with a well controlled electrode–electrolyte interface that can reach total current densities of up to 1 A cm^–2, together with improved C₂₊ selectivities. Computational transport modelling and isotopic C¹⁸O reduction experiments suggest that the enhanced activity is due to a higher surface pH under CO reduction conditions, which facilitates the production of acetate. Here, at optimal operating conditions, we achieve a C₂₊ Faradaic efficiency of ~91% with a C₂₊ partial current density over 630 mA cm^–2. Further investigations show that maintaining an efficient triple-phase boundary at the electrode–electrolyte interface is the most critical challenge in achieving a stable CO/CO₂ electrolysis process at high rates.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: FE0029868; AC02-06CH11357

OSTI ID:: 1712666

Alternate ID(s):: OSTI ID: 1614347

Journal Information:: Nature Catalysis, Journal Name: Nature Catalysis Journal Issue: 10 Vol. 1; ISSN 2520-1158

Publisher:: Springer NatureCopyright Statement

Country of Publication:: United States

Language:: English

References (63)

Acetaldehyde as an Intermediate in the Electroreduction of Carbon Monoxide to Ethanol on Oxide-Derived Copper Bertheussen, Erlend; Verdaguer-Casadevall, Arnau; Ravasio, Davide Angewandte Chemie, Vol. 128, Issue 4 https://doi.org/10.1002/ange.201508851	journal	December 2015
Tailoring Copper Nanocrystals towards C ₂ Products in Electrochemical CO ₂ Reduction Loiudice, Anna; Lobaccaro, Peter; Kamali, Esmail A. Angewandte Chemie, Vol. 128, Issue 19 https://doi.org/10.1002/ange.201601582	journal	April 2016
Acetaldehyde as an Intermediate in the Electroreduction of Carbon Monoxide to Ethanol on Oxide-Derived Copper Bertheussen, Erlend; Verdaguer-Casadevall, Arnau; Ravasio, Davide Angewandte Chemie International Edition, Vol. 55, Issue 4 https://doi.org/10.1002/anie.201508851	journal	December 2015
Tailoring Copper Nanocrystals towards C ₂ Products in Electrochemical CO ₂ Reduction Loiudice, Anna; Lobaccaro, Peter; Kamali, Esmail A. Angewandte Chemie International Edition, Vol. 55, Issue 19 https://doi.org/10.1002/anie.201601582	journal	April 2016
High-Selectivity Electrochemical Conversion of CO ₂ to Ethanol using a Copper Nanoparticle/N-Doped Graphene Electrode Song, Yang; Peng, Rui; Hensley, Dale K. ChemistrySelect, Vol. 1, Issue 19 https://doi.org/10.1002/slct.201601169	journal	September 2016
Calculation for the cathode surface concentrations in the electrochemical reduction of CO2 in KHCO3 solutions Gupta, N.; Gattrell, M.; MacDougall, B. Journal of Applied Electrochemistry, Vol. 36, Issue 2 https://doi.org/10.1007/s10800-005-9058-y	journal	October 2005
Regulating the Product Distribution of CO Reduction by the Atomic-Level Structural Modification of the Cu Electrode Surface Kim, Youn-Geun; Javier, Alnald; Baricuatro, Jack H. Electrocatalysis, Vol. 7, Issue 5 https://doi.org/10.1007/s12678-016-0314-1	journal	June 2016
Electrochemical reduction of carbon dioxide at various series of copper single crystal electrodes Hori, Y.; Takahashi, I.; Koga, O. Journal of Molecular Catalysis A: Chemical, Vol. 199, Issue 1-2, p. 39-47 https://doi.org/10.1016/S1381-1169(03)00016-5	journal	May 2003
Electrochemical conversion of CO2 to useful chemicals: current status, remaining challenges, and future opportunities Jhong, Huei-Ru “Molly”; Ma, Sichao; Kenis, Paul JA Current Opinion in Chemical Engineering, Vol. 2, Issue 2 https://doi.org/10.1016/j.coche.2013.03.005	journal	May 2013
One-dimensional nanoclustering of the Cu(100) surface under CO gas in the mbar pressure range Eren, Baran; Zherebetskyy, Danylo; Hao, Yibo Surface Science, Vol. 651 https://doi.org/10.1016/j.susc.2016.04.016	journal	September 2016
General Techno-Economic Analysis of CO ₂ Electrolysis Systems Jouny, Matthew; Luc, Wesley; Jiao, Feng Industrial & Engineering Chemistry Research, Vol. 57, Issue 6 https://doi.org/10.1021/acs.iecr.7b03514	journal	February 2018
Mechanistic Insights into the Selective Electroreduction of Carbon Dioxide to Ethylene on Cu ₂ O-Derived Copper Catalysts Handoko, Albertus D.; Ong, Cheng Wai; Huang, Yun The Journal of Physical Chemistry C, Vol. 120, Issue 36 https://doi.org/10.1021/acs.jpcc.6b07128	journal	September 2016
Spectroscopic Observation of Reversible Surface Reconstruction of Copper Electrodes under CO ₂ Reduction Gunathunge, Charuni M.; Li, Xiang; Li, Jingyi The Journal of Physical Chemistry C, Vol. 121, Issue 22 https://doi.org/10.1021/acs.jpcc.7b03910	journal	May 2017
Theoretical Insights into a CO Dimerization Mechanism in CO ₂ Electroreduction Montoya, Joseph H.; Shi, Chuan; Chan, Karen The Journal of Physical Chemistry Letters, Vol. 6, Issue 11 https://doi.org/10.1021/acs.jpclett.5b00722	journal	May 2015
Cu–Sn Bimetallic Catalyst for Selective Aqueous Electroreduction of CO ₂ to CO Sarfraz, Saad; Garcia-Esparza, Angel T.; Jedidi, Abdesslem ACS Catalysis, Vol. 6, Issue 5 https://doi.org/10.1021/acscatal.6b00269	journal	April 2016
Morphology Matters: Tuning the Product Distribution of CO ₂ Electroreduction on Oxide-Derived Cu Foam Catalysts Dutta, Abhijit; Rahaman, Motiar; Luedi, Nicola C. ACS Catalysis, Vol. 6, Issue 6 https://doi.org/10.1021/acscatal.6b00770	journal	May 2016
Tuning the Selectivity of Carbon Dioxide Electroreduction toward Ethanol on Oxide-Derived Cu _x Zn Catalysts Ren, Dan; Ang, Bridget Su-Hui; Yeo, Boon Siang ACS Catalysis, Vol. 6, Issue 12 https://doi.org/10.1021/acscatal.6b02162	journal	November 2016
Electrochemical Reduction of CO ₂ Using Copper Single-Crystal Surfaces: Effects of CO* Coverage on the Selective Formation of Ethylene Huang, Yun; Handoko, Albertus D.; Hirunsit, Pussana ACS Catalysis, Vol. 7, Issue 3 https://doi.org/10.1021/acscatal.6b03147	journal	February 2017
Nanoporous Copper Films by Additive-Controlled Electrodeposition: CO ₂ Reduction Catalysis Hoang, Thao T. H.; Ma, Sichao; Gold, Jake I. ACS Catalysis, Vol. 7, Issue 5 https://doi.org/10.1021/acscatal.6b03613	journal	April 2017
Low-Overpotential Electroreduction of Carbon Monoxide Using Copper Nanowires Raciti, David; Cao, Liang; Livi, Kenneth J. T. ACS Catalysis, Vol. 7, Issue 7 https://doi.org/10.1021/acscatal.7b01124	journal	June 2017
Electrochemical Reduction of CO ₂ into Multicarbon Alcohols on Activated Cu Mesh Catalysts: An Identical Location (IL) Study Rahaman, Motiar; Dutta, Abhijit; Zanetti, Alberto ACS Catalysis, Vol. 7, Issue 11 https://doi.org/10.1021/acscatal.7b02234	journal	October 2017
Importance of Ag–Cu Biphasic Boundaries for Selective Electrochemical Reduction of CO ₂ to Ethanol Lee, Seunghwa; Park, Gibeom; Lee, Jaeyoung ACS Catalysis, Vol. 7, Issue 12 https://doi.org/10.1021/acscatal.7b02822	journal	November 2017
Mechanism of CO ₂ Reduction at Copper Surfaces: Pathways to C ₂ Products Garza, Alejandro J.; Bell, Alexis T.; Head-Gordon, Martin ACS Catalysis, Vol. 8, Issue 2 https://doi.org/10.1021/acscatal.7b03477	journal	January 2018
A Direct Grain-Boundary-Activity Correlation for CO Electroreduction on Cu Nanoparticles Feng, Xiaofeng; Jiang, Kaili; Fan, Shoushan ACS Central Science, Vol. 2, Issue 3 https://doi.org/10.1021/acscentsci.6b00022	journal	March 2016
Insights into the Low Overpotential Electroreduction of CO ₂ to CO on a Supported Gold Catalyst in an Alkaline Flow Electrolyzer Verma, Sumit; Hamasaki, Yuki; Kim, Chaerin ACS Energy Letters, Vol. 3, Issue 1 https://doi.org/10.1021/acsenergylett.7b01096	journal	November 2017
Recent Advances in CO ₂ Reduction Electrocatalysis on Copper Raciti, David; Wang, Chao ACS Energy Letters, Vol. 3, Issue 7 https://doi.org/10.1021/acsenergylett.8b00553	journal	June 2018
Plasma-Activated Copper Nanocube Catalysts for Efficient Carbon Dioxide Electroreduction to Hydrocarbons and Alcohols Gao, Dunfeng; Zegkinoglou, Ioannis; Divins, Nuria J. ACS Nano, Vol. 11, Issue 5 https://doi.org/10.1021/acsnano.7b01257	journal	April 2017
Electrochemical Reduction of CO ₂ at Copper Nanofoams Sen, Sujat; Liu, Dan; Palmore, G. Tayhas R. ACS Catalysis, Vol. 4, Issue 9 https://doi.org/10.1021/cs500522g	journal	August 2014
CO ₂ Electroreduction to Hydrocarbons on Carbon-Supported Cu Nanoparticles Baturina, Olga A.; Lu, Qin; Padilla, Monica A. ACS Catalysis, Vol. 4, Issue 10 https://doi.org/10.1021/cs500537y	journal	September 2014
Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts Ren, Dan; Deng, Yilin; Handoko, Albertus Denny ACS Catalysis, Vol. 5, Issue 5 https://doi.org/10.1021/cs502128q	journal	March 2015
A Nuclear Magnetic Resonance Study of the Reversible Hydration of Aliphatic Aldehydes and Ketones. II. The Acid-Catalyzed Oxygen Exchange of Acetaldehyde Greenzaid, P.; Luz, Z.; Samuel, David. Journal of the American Chemical Society, Vol. 89, Issue 4 https://doi.org/10.1021/ja00980a005	journal	February 1967
Particle Size Effects in the Catalytic Electroreduction of CO ₂ on Cu Nanoparticles Reske, Rulle; Mistry, Hemma; Behafarid, Farzad Journal of the American Chemical Society, Vol. 136, Issue 19 https://doi.org/10.1021/ja500328k	journal	May 2014
Probing the Active Surface Sites for CO Reduction on Oxide-Derived Copper Electrocatalysts Verdaguer-Casadevall, Arnau; Li, Christina W.; Johansson, Tobias P. Journal of the American Chemical Society, Vol. 137, Issue 31 https://doi.org/10.1021/jacs.5b06227	journal	July 2015
Mechanistic Explanation of the pH Dependence and Onset Potentials for Hydrocarbon Products from Electrochemical Reduction of CO on Cu (111) Xiao, Hai; Cheng, Tao; Goddard, William A. Journal of the American Chemical Society, Vol. 138, Issue 2 https://doi.org/10.1021/jacs.5b11390	journal	January 2016
Electrochemical CO ₂ Reduction to Hydrocarbons on a Heterogeneous Molecular Cu Catalyst in Aqueous Solution Weng, Zhe; Jiang, Jianbing; Wu, Yueshen Journal of the American Chemical Society, Vol. 138, Issue 26 https://doi.org/10.1021/jacs.6b04746	journal	June 2016
The Importance of Cannizzaro-Type Reactions during Electrocatalytic Reduction of Carbon Dioxide Birdja, Yuvraj Y.; Koper, Marc T. M. Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b12008	journal	January 2017
Electrochemical CO ₂ Reduction over Compressively Strained CuAg Surface Alloys with Enhanced Multi-Carbon Oxygenate Selectivity Clark, Ezra L.; Hahn, Christopher; Jaramillo, Thomas F. Journal of the American Chemical Society, Vol. 139, Issue 44 https://doi.org/10.1021/jacs.7b08607	journal	October 2017
Nanoporous Copper–Silver Alloys by Additive-Controlled Electrodeposition for the Selective Electroreduction of CO ₂ to Ethylene and Ethanol Hoang, Thao T. H.; Verma, Sumit; Ma, Sichao Journal of the American Chemical Society, Vol. 140, Issue 17 https://doi.org/10.1021/jacs.8b01868	journal	April 2018
Direct Observation of the Local Reaction Environment during the Electrochemical Reduction of CO ₂ Clark, Ezra L.; Bell, Alexis T. Journal of the American Chemical Society, Vol. 140, Issue 22 https://doi.org/10.1021/jacs.8b04058	journal	April 2018
Prospects of CO₂ Utilization via Direct Heterogeneous Electrochemical Reduction Whipple, Devin T.; Kenis, Paul J. A. The Journal of Physical Chemistry Letters, Vol. 1, Issue 24, p. 3451-3458 https://doi.org/10.1021/jz1012627	journal	December 2010
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper Li, Christina W.; Ciston, Jim; Kanan, Matthew W. Nature, Vol. 508, Issue 7497 https://doi.org/10.1038/nature13249	journal	April 2014
Three-dimensional porous hollow fibre copper electrodes for efficient and high-rate electrochemical carbon dioxide reduction Kas, Recep; Hummadi, Khalid Khazzal; Kortlever, Ruud Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10748	journal	February 2016
Highly selective plasma-activated copper catalysts for carbon dioxide reduction to ethylene Mistry, Hemma; Varela, Ana Sofia; Bonifacio, Cecile S. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12123	journal	June 2016
Understanding trends in electrochemical carbon dioxide reduction rates Liu, Xinyan; Xiao, Jianping; Peng, Hongjie Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15438	journal	May 2017
Metal ion cycling of Cu foil for selective C–C coupling in electrochemical CO2 reduction Jiang, Kun; Sandberg, Robert B.; Akey, Austin J. Nature Catalysis, Vol. 1, Issue 2 https://doi.org/10.1038/s41929-017-0009-x	journal	January 2018
Catalyst electro-redeposition controls morphology and oxidation state for selective carbon dioxide reduction De Luna, Phil; Quintero-Bermudez, Rafael; Dinh, Cao-Thang Nature Catalysis, Vol. 1, Issue 2 https://doi.org/10.1038/s41929-017-0018-9	journal	January 2018
The importance of surface morphology in controlling the selectivity of polycrystalline copper for CO2 electroreduction Tang, Wei; Peterson, Andrew A.; Varela, Ana Sofia Phys. Chem. Chem. Phys., Vol. 14, Issue 1 https://doi.org/10.1039/C1CP22700A	journal	January 2012
A general framework for the assessment of solar fuel technologies Herron, Jeffrey A.; Kim, Jiyong; Upadhye, Aniruddha A. Energy & Environmental Science, Vol. 8, Issue 1 https://doi.org/10.1039/C4EE01958J	journal	January 2015
The effect of electrolyte composition on the electroreduction of CO ₂ to CO on Ag based gas diffusion electrodes Verma, Sumit; Lu, Xun; Ma, Sichao Physical Chemistry Chemical Physics, Vol. 18, Issue 10 https://doi.org/10.1039/C5CP05665A	journal	January 2016
Towards sustainable fuels and chemicals through the electrochemical reduction of CO ₂ : lessons from water electrolysis Martín, Antonio J.; Larrazábal, Gastón O.; Pérez-Ramírez, Javier Green Chemistry, Vol. 17, Issue 12 https://doi.org/10.1039/C5GC01893E	journal	January 2015
Carbon nanotube containing Ag catalyst layers for efficient and selective reduction of carbon dioxide Ma, Sichao; Luo, Raymond; Gold, Jake I. Journal of Materials Chemistry A, Vol. 4, Issue 22 https://doi.org/10.1039/C6TA00427J	journal	January 2016
A comparative technoeconomic analysis of pathways for commercial electrochemical CO ₂ reduction to liquid products Spurgeon, Joshua M.; Kumar, Bijandra Energy & Environmental Science, Vol. 11, Issue 6 https://doi.org/10.1039/C8EE00097B	journal	January 2018
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N. Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21234j	journal	January 2012
Polymer-supported CuPd nanoalloy as a synergistic catalyst for electrocatalytic reduction of carbon dioxide to methane Zhang, Sheng; Kang, Peng; Bakir, Mohammed Proceedings of the National Academy of Sciences, Vol. 112, Issue 52 https://doi.org/10.1073/pnas.1522496112	journal	December 2015
Engineering Cu surfaces for the electrocatalytic conversion of CO ₂ : Controlling selectivity toward oxygenates and hydrocarbons Hahn, Christopher; Hatsukade, Toru; Kim, Youn-Geun Proceedings of the National Academy of Sciences, Vol. 114, Issue 23 https://doi.org/10.1073/pnas.1618935114	journal	May 2017
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Activation of Cu(111) surface by decomposition into nanoclusters driven by CO adsorption Eren, B.; Zherebetskyy, D.; Patera, L. L. Science, Vol. 351, Issue 6272 https://doi.org/10.1126/science.aad8868	journal	January 2016
Terawatt-scale photovoltaics: Trajectories and challenges Haegel, Nancy M.; Margolis, Robert; Buonassisi, Tonio Science, Vol. 356, Issue 6334 https://doi.org/10.1126/science.aal1288	journal	April 2017
Selective increase in CO ₂ electroreduction activity at grain-boundary surface terminations Mariano, Ruperto G.; McKelvey, Kim; White, Henry S. Science, Vol. 358, Issue 6367 https://doi.org/10.1126/science.aao3691	journal	November 2017
CO ₂ electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface Dinh, Cao-Thang; Burdyny, Thomas; Kibria, Md Golam Science, Vol. 360, Issue 6390 https://doi.org/10.1126/science.aas9100	journal	May 2018
Electrochemical Energy Engineering: A New Frontier of Chemical Engineering Innovation Gu, Shuang; Xu, Bingjun; Yan, Yushan Annual Review of Chemical and Biomolecular Engineering, Vol. 5, Issue 1 https://doi.org/10.1146/annurev-chembioeng-060713-040114	journal	June 2014
Acetaldehyde As an Intermediate in the Electroreduction of Carbon Monoxide to Ethanol on Oxide-Derived Copper Bertheussen, Erlend; Verdaguer-Casdevall, Arnau; Ravasio, Davide ECS Meeting Abstracts, Vol. MA2016-01, Issue 38 https://doi.org/10.1149/ma2016-01/38/1940	journal	April 2016
Polymer-supported CuPd nanoalloy as a synergistic catalyst for electrocatalytic reduction of carbon dioxide to methane Sheng, Zhang,; J., Dares, Christopher; Peng, Kang, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/t2sj-1z15	text	January 2015

Cited By (26)

Shape-Controlled CO ₂ Electrochemical Reduction on Nanosized Pd Hydride Cubes and Octahedra Zhu, Wenlei; Kattel, Shyam; Jiao, Feng Advanced Energy Materials, Vol. 9, Issue 9 https://doi.org/10.1002/aenm.201802840	journal	January 2019
Bipyridine‐Assisted Assembly of Au Nanoparticles on Cu Nanowires To Enhance the Electrochemical Reduction of CO ₂ Fu, Jiaju; Zhu, Wenlei; Chen, Ying Angewandte Chemie, Vol. 131, Issue 40 https://doi.org/10.1002/ange.201905318	journal	August 2019
Highly Selective Production of Ethylene by the Electroreduction of Carbon Monoxide Chen, Ruixue; Su, Hai‐Yan; Liu, Deyu Angewandte Chemie, Vol. 132, Issue 1 https://doi.org/10.1002/ange.201910662	journal	December 2019
Hydroxide Is Not a Promoter of C ₂₊ Product Formation in the Electrochemical Reduction of CO on Copper Li, Jing; Wu, Donghuan; Malkani, Arnav S. Angewandte Chemie, Vol. 132, Issue 11 https://doi.org/10.1002/ange.201912412	journal	March 2020
Titelbild: Hydroxide Is Not a Promoter of C ₂₊ Product Formation in the Electrochemical Reduction of CO on Copper (Angew. Chem. 11/2020) Li, Jing; Wu, Donghuan; Malkani, Arnav S. Angewandte Chemie, Vol. 132, Issue 11 https://doi.org/10.1002/ange.202000873	journal	March 2020
Bipyridine-Assisted Assembly of Au Nanoparticles on Cu Nanowires To Enhance the Electrochemical Reduction of CO ₂ Fu, Jiaju; Zhu, Wenlei; Chen, Ying Angewandte Chemie International Edition, Vol. 58, Issue 40 https://doi.org/10.1002/anie.201905318	journal	August 2019
Highly Selective Production of Ethylene by the Electroreduction of Carbon Monoxide Chen, Ruixue; Su, Hai‐Yan; Liu, Deyu Angewandte Chemie International Edition, Vol. 59, Issue 1 https://doi.org/10.1002/anie.201910662	journal	December 2019
Hydroxide Is Not a Promoter of C ₂₊ Product Formation in the Electrochemical Reduction of CO on Copper Li, Jing; Wu, Donghuan; Malkani, Arnav S. Angewandte Chemie International Edition, Vol. 59, Issue 11 https://doi.org/10.1002/anie.201912412	journal	January 2020
Cover Picture: Hydroxide Is Not a Promoter of C ₂₊ Product Formation in the Electrochemical Reduction of CO on Copper (Angew. Chem. Int. Ed. 11/2020) Li, Jing; Wu, Donghuan; Malkani, Arnav S. Angewandte Chemie International Edition, Vol. 59, Issue 11 https://doi.org/10.1002/anie.202000873	journal	January 2020
Structure‐Sensitivity and Electrolyte Effects in CO ₂ Electroreduction: From Model Studies to Applications Sebastián‐Pascual, Paula; Mezzavilla, Stefano; Stephens, Ifan E. L. ChemCatChem, Vol. 11, Issue 16 https://doi.org/10.1002/cctc.201900552	journal	June 2019
Electrochemical Carbon Dioxide Splitting Xie, Jiafang; Huang, Yiyin; Wu, Maoxiang ChemElectroChem, Vol. 6, Issue 6 https://doi.org/10.1002/celc.201801716	journal	February 2019
Efficient upgrading of CO to C3 fuel using asymmetric C-C coupling active sites Wang, Xue; Wang, Ziyun; Zhuang, Tao-Tao Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13190-6	journal	November 2019
Formation of carbon–nitrogen bonds in carbon monoxide electrolysis Jouny, Matthew; Lv, Jing-Jing; Cheng, Tao Nature Chemistry, Vol. 11, Issue 9 https://doi.org/10.1038/s41557-019-0312-z	journal	August 2019
Efficient electrocatalytic conversion of carbon monoxide to propanol using fragmented copper Pang, Yuanjie; Li, Jun; Wang, Ziyun Nature Catalysis, Vol. 2, Issue 3 https://doi.org/10.1038/s41929-019-0225-7	journal	February 2019
Rational catalyst and electrolyte design for CO2 electroreduction towards multicarbon products Gao, Dunfeng; Arán-Ais, Rosa M.; Jeon, Hyo Sang Nature Catalysis, Vol. 2, Issue 3 https://doi.org/10.1038/s41929-019-0235-5	journal	March 2019
Perfluorocarbon nanoemulsion promotes the delivery of reducing equivalents for electricity-driven microbial CO2 reduction Rodrigues, Roselyn M.; Guan, Xun; Iñiguez, Jesus A. Nature Catalysis, Vol. 2, Issue 5 https://doi.org/10.1038/s41929-019-0264-0	journal	April 2019
Two-dimensional copper nanosheets for electrochemical reduction of carbon monoxide to acetate Luc, Wesley; Fu, Xianbiao; Shi, Jianjian Nature Catalysis, Vol. 2, Issue 5 https://doi.org/10.1038/s41929-019-0269-8	journal	April 2019
Designing materials for electrochemical carbon dioxide recycling Ross, Michael B.; De Luna, Phil; Li, Yifan Nature Catalysis, Vol. 2, Issue 8 https://doi.org/10.1038/s41929-019-0306-7	journal	July 2019
Constraining CO coverage on copper promotes high-efficiency ethylene electroproduction Li, Jun; Wang, Ziyun; McCallum, Christopher Nature Catalysis, Vol. 2, Issue 12 https://doi.org/10.1038/s41929-019-0380-x	journal	November 2019
Carbon monoxide electroreduction as an emerging platform for carbon utilization Jouny, Matthew; Hutchings, Gregory S.; Jiao, Feng Nature Catalysis, Vol. 2, Issue 12 https://doi.org/10.1038/s41929-019-0388-2	journal	December 2019
Frustrated Lewis pairs photocatalyst for visible light-driven reduction of CO to multi-carbon chemicals Chen, Zhe; Zhao, Jia; Zhao, Jingxiang Nanoscale, Vol. 11, Issue 43 https://doi.org/10.1039/c9nr07559c	journal	January 2019
Improving selectivity of CO reduction via reducing the coordination of critical intermediates Li, Yifan; Qian, Yumin; Ji, Yujin Journal of Materials Chemistry A, Vol. 7, Issue 41 https://doi.org/10.1039/c9ta06529f	journal	January 2019
Advances and challenges in electrochemical CO ₂ reduction processes: an engineering and design perspective looking beyond new catalyst materials Garg, Sahil; Li, Mengran; Weber, Adam Z. Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/c9ta13298h	journal	January 2020
CO ₂ electrolysis to multicarbon products at activities greater than 1 A cm ⁻² García de Arquer, F. Pelayo; Dinh, Cao-Thang; Ozden, Adnan Science, Vol. 367, Issue 6478 https://doi.org/10.1126/science.aay4217	journal	February 2020
Sputtered Platinum Thin-films for Oxygen Reduction in Gas Diffusion Electrodes: A Model System for Studies under Realistic Reaction Conditions Sievers, Gustav W.; Jensen, Anders W.; Brüser, Volker Surfaces, Vol. 2, Issue 2 https://doi.org/10.3390/surfaces2020025	journal	April 2019
Sputtered Platinum Thin-films for Oxygen Reduction in Gas Diffusion Electrodes: A Model System for Studies under Realistic Reaction Conditions Sievers, Gustav W.; Jensen, Anders W.; Brüser, Volker MDPI https://doi.org/10.7892/boris.133630	text	January 2019

Similar Records

Isolated copper single sites for high-performance electroreduction of carbon monoxide to multicarbon products

Journal Article · Sun Jan 10 23:00:00 EST 2021 · Nature Communications · OSTI ID:1811911

Fe-N₄O-C Nanoplates Covalently Bonding on Graphene for Efficient CO ₂ Electroreduction and Zn-CO₂ Batteries

Journal Article · Fri Mar 24 00:00:00 EDT 2023 · Advanced Functional Materials · OSTI ID:1963587

Recovering carbon losses in CO₂ electrolysis using a solid electrolyte reactor

Journal Article · Mon Apr 18 00:00:00 EDT 2022 · Nature Catalysis · OSTI ID:1875342

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
carbon dioxide
carbon monoxide
chemical engineering
electrocatalysts
electrochemical reduction
energy
heterogeneous catalysis
solar fuels

High-rate electroreduction of carbon monoxide to multi-carbon products

Citation Formats

References (63)

Cited By (26)

Similar Records

Related Subjects