Investigation of Room Temperature Formation of the Ultra-Hard Nanocarbons Diamond and Lonsdaleite

McCulloch, Dougal G.; Wong, Sherman; Shiell, Thomas B.; Haberl, Bianca; Cook, Brenton A.; Huang, Xingshuo; Boehler, Reinhard; McKenzie, David R.; Bradby, Jodie E.

doi:10.1002/smll.202004695

Title: Investigation of Room Temperature Formation of the Ultra-Hard Nanocarbons Diamond and Lonsdaleite

Journal Article · Wed Nov 04 00:00:00 EST 2020 · Small

DOI:https://doi.org/10.1002/smll.202004695· OSTI ID:1709105

^[1]; Wong, Sherman ^[1]; Shiell, Thomas B. ^[2];

^[3]; Cook, Brenton A. ^[1]; Huang, Xingshuo ^[2]; Boehler, Reinhard ^[3]; McKenzie, David R. ^[4]; Bradby, Jodie E. ^[2]

RMIT Univ., Melbourne, VIC (Australia)
Australian National Univ., Canberra, ACT (Australia)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Sydney, NSW (Australia)

Abstract Diamond is an attractive material due to its extreme hardness, high thermal conductivity, quantum optical, and biomedical applications. There is still much that is not understood about how diamonds form, particularly at room temperature and without catalysts. In this work, a new route for the formation of nanocrystalline diamond and the diamond‐like phase lonsdaleite is presented. Both diamond phases are found to form together within bands with a core‐shell structure following the high pressure treatment of a glassy carbon precursor at room temperature. The crystallographic arrangements of the diamond phases revealed that shear is the driving force for their formation and growth. This study gives new understanding of how shear can lead to crystallization in materials and helps elucidate how diamonds can form on Earth, in meteorite impacts and on other planets. Finally, the new shear induced formation mechanism works at room temperature, a key finding that may enable diamond and other technically important nanomaterials to be synthesized more readily.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA); National Science Foundation (NSF); Australian Research Council (ARC)

Grant/Contract Number:: AC05-00OR22725; NA0001974; EAR-1634415; FG02-94ER14466; AC02-06CH11357; DP170102087; DE‐NA0001974; DE‐AC05‐00OR22725

OSTI ID:: 1709105

Alternate ID(s):: OSTI ID: 1786565

Journal Information:: Small, Vol. 16, Issue 50; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (38)

Shear-induced phase transition of nanocrystalline hexagonal boron nitride to wurtzitic structure at room temperature and lower pressure Ji, C.; Levitas, V. I.; Zhu, H. Proceedings of the National Academy of Sciences, Vol. 109, Issue 47 https://doi.org/10.1073/pnas.1214976109	journal	November 2012
Structure of Glassy Carbon Jenkins, G. M.; Kawamura, K. Nature, Vol. 231, Issue 5299 https://doi.org/10.1038/231175a0	journal	May 1971
Graphitization of Glassy Carbon after Compression at Room Temperature Shiell, T. B.; McCulloch, D. G.; McKenzie, D. R. Physical Review Letters, Vol. 120, Issue 21 https://doi.org/10.1103/PhysRevLett.120.215701	journal	May 2018
Pressure-Induced Transformation Path of Graphite to Diamond Scandolo, S.; Bernasconi, M.; Chiarotti, G. L. Physical Review Letters, Vol. 74, Issue 20 https://doi.org/10.1103/PhysRevLett.74.4015	journal	May 1995
Local microstructure evolution at shear bands in metallic glasses with nanoscale phase separation He, Jie; Kaban, Ivan; Mattern, Norbert Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep25832	journal	May 2016
The shear-driven transformation mechanism from glassy carbon to hexagonal diamond Wong, S.; Shiell, T. B.; Cook, B. A. Carbon, Vol. 142 https://doi.org/10.1016/j.carbon.2018.10.080	journal	February 2019
Observations of transient high temperature vortical microstructures in solids during adiabatic shear banding Guduru, P. R.; Ravichandran, G.; Rosakis, A. J. Physical Review E, Vol. 64, Issue 3 https://doi.org/10.1103/PhysRevE.64.036128	journal	August 2001
Research Update: Direct conversion of amorphous carbon into diamond at ambient pressures and temperatures in air Narayan, Jagdish; Bhaumik, Anagh APL Materials, Vol. 3, Issue 10 https://doi.org/10.1063/1.4932622	journal	October 2015
Superhard Monoclinic Polymorph of Carbon Li, Quan; Ma, Yanming; Oganov, Artem R. Physical Review Letters, Vol. 102, Issue 17 https://doi.org/10.1103/PhysRevLett.102.175506	journal	April 2009
Detailed Structures of Hexagonal Diamond (lonsdaleite) and Wurtzite-type BN Yoshiasa, Akira; Murai, Yu; Ohtaka, Osamu Japanese Journal of Applied Physics, Vol. 42, Issue Part 1, No. 4A https://doi.org/10.1143/JJAP.42.1694	journal	April 2003
Properties of diamond under hydrostatic pressures up to 140 GPa Occelli, Florent; Loubeyre, Paul; LeToullec, René Nature Materials, Vol. 2, Issue 3 https://doi.org/10.1038/nmat831	journal	February 2003
Pseudopotential total-energy study of the transition from rhombohedral graphite to diamond Fahy, S.; Louie, Steven G.; Cohen, Marvin L. Physical Review B, Vol. 34, Issue 2 https://doi.org/10.1103/PhysRevB.34.1191	journal	July 1986
Strain-induced phase transformation under compression in a diamond anvil cell: Simulations of a sample and gasket Feng, Biao; Levitas, Valery I.; Ma, Yanzhang Journal of Applied Physics, Vol. 115, Issue 16 https://doi.org/10.1063/1.4873460	journal	April 2014
Structure and defects of detonation synthesis nanodiamond Iakoubovskii, K.; Baidakova, M. V.; Wouters, B. H. Diamond and Related Materials, Vol. 9, Issue 3-6 https://doi.org/10.1016/S0925-9635(99)00354-4	journal	April 2000
Man-Made Diamonds Bundy, F. P.; Hall, H. T.; Strong, H. M. Nature, Vol. 176, Issue 4471 https://doi.org/10.1038/176051a0	journal	July 1955
The pressure-temperature phase and transformation diagram for carbon; updated through 1994 Bundy, F. P.; Bassett, W. A.; Weathers, M. S. Carbon, Vol. 34, Issue 2 https://doi.org/10.1016/0008-6223(96)00170-4	journal	January 1996
Nanosecond formation of diamond and lonsdaleite by shock compression of graphite Kraus, D.; Ravasio, A.; Gauthier, M. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10970	journal	March 2016
Anticrack-associated faulting at very high pressure in natural olivine Green, Harry W.; Young, Thomas E.; Walker, David Nature, Vol. 348, Issue 6303 https://doi.org/10.1038/348720a0	journal	December 1990
Hexagonal Diamond—A New Form of Carbon Bundy, F. P.; Kasper, J. S. The Journal of Chemical Physics, Vol. 46, Issue 9 https://doi.org/10.1063/1.1841236	journal	May 1967
Finite Elastic Strain of Cubic Crystals Birch, Francis Physical Review, Vol. 71, Issue 11 https://doi.org/10.1103/PhysRev.71.809	journal	June 1947
GSAS-II : the genesis of a modern open-source all purpose crystallography software package Toby, Brian H.; Von Dreele, Robert B. Journal of Applied Crystallography, Vol. 46, Issue 2 https://doi.org/10.1107/S0021889813003531	journal	March 2013
Shock-induced martensitic phase transformation of oriented graphite to diamond Erskine, D. J.; Nellis, W. J. Nature, Vol. 349, Issue 6307 https://doi.org/10.1038/349317a0	journal	January 1991
Hexagonal Diamonds in Meteorites: Implications Hanneman, R. E.; Strong, H. M.; Bundy, F. P. Science, Vol. 155, Issue 3765 https://doi.org/10.1126/science.155.3765.995	journal	February 1967
Decompression-Induced Diamond Formation from Graphite Sheared under Pressure Dong, Jiajun; Yao, Zhen; Yao, Mingguang Physical Review Letters, Vol. 124, Issue 6 https://doi.org/10.1103/PhysRevLett.124.065701	journal	February 2020
Compressive stress induced formation of preferred orientation in glassy carbon following high-dose C ⁺ implantation Mc Culloch, D. G.; Mc Kenzie, R.; Prawer, S. Philosophical Magazine A, Vol. 72, Issue 4 https://doi.org/10.1080/01418619508239951	journal	October 1995
Low-energy tetrahedral polymorphs of carbon, silicon, and germanium Mujica, Andrés; Pickard, Chris J.; Needs, Richard J. Physical Review B, Vol. 91, Issue 21 https://doi.org/10.1103/PhysRevB.91.214104	journal	June 2015
Shear driven formation of nano-diamonds at sub-gigapascals and 300 K Gao, Yang; Ma, Yanzhang; An, Qi Carbon, Vol. 146 https://doi.org/10.1016/j.carbon.2019.02.012	journal	May 2019
Crystal structure of graphite under room-temperature compression and decompression Wang, Yuejian; Panzik, Joseph E.; Kiefer, Boris Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00520	journal	July 2012
Dynamic shear bands: an investigation using high speed optical and infrared diagnostics Guduru, P. R.; Rosakis, A. J.; Ravichandran, G. Mechanics of Materials, Vol. 33, Issue 7 https://doi.org/10.1016/S0167-6636(01)00051-5	journal	July 2001
Advanced integrated optical spectroscopy system for diamond anvil cell studies at GSECARS Holtgrewe, Nicholas; Greenberg, Eran; Prescher, Clemens High Pressure Research, Vol. 39, Issue 3 https://doi.org/10.1080/08957959.2019.1647536	journal	July 2019
Nanocrystalline hexagonal diamond formed from glassy carbon Shiell, Thomas. B.; McCulloch, Dougal G.; Bradby, Jodie E. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep37232	journal	November 2016
High-pressure in situ x-ray-diffraction study of the phase transformation from graphite to hexagonal diamond at room temperature Yagi, Takehiko; Utsumi, Wataru; Yamakata, Masa-aki Physical Review B, Vol. 46, Issue 10 https://doi.org/10.1103/PhysRevB.46.6031	journal	September 1992
Geology and structure of diamond-bearing rocks of the Kokchetav massif (Kazakhstan) Dobrzhinetskaya, Larissa F.; Braun, Tatjana V.; Sheshkel, Georgy G. Tectonophysics, Vol. 233, Issue 3-4 https://doi.org/10.1016/0040-1951(94)90247-X	journal	May 1994
A microstructural investigation of adiabatic shear bands in an interstitial free steel Lins, J. F. C.; Sandim, H. R. Z.; Kestenbach, H. -J. Materials Science and Engineering: A, Vol. 457, Issue 1-2 https://doi.org/10.1016/j.msea.2006.12.019	journal	May 2007
The properties and applications of nanodiamonds Mochalin, Vadym N.; Shenderova, Olga; Ho, Dean Nature Nanotechnology, Vol. 7, Issue 1 https://doi.org/10.1038/nnano.2011.209	journal	December 2011
Lonsdaleite, a Hexagonal Polymorph of Diamond Frondel, Clifford; Marvin, Ursula B. Nature, Vol. 214, Issue 5088 https://doi.org/10.1038/214587a0	journal	May 1967
Diamond as a high pressure gauge up to 2.7 Mbar Dubrovinskaia, Natalia; Dubrovinsky, Leonid; Caracas, Razvan Applied Physics Letters, Vol. 97, Issue 25 https://doi.org/10.1063/1.3529454	journal	December 2010
Nucleation mechanism for the direct graphite-to-diamond phase transition Khaliullin, Rustam Z.; Eshet, Hagai; Kühne, Thomas D. Nature Materials, Vol. 10, Issue 9 https://doi.org/10.1038/nmat3078	journal	July 2011

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