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A historical perspective on porphyrin-based metal–organic frameworks and their applications

Journal Article · · Coordination Chemistry Reviews
 [1];  [2];  [3];  [3];  [4];  [4];  [5];  [5];  [4];  [4];  [2];  [2];  [4];  [5];  [4];  [3];  [6];  [2]
  1. Northwestern Univ., Evanston, IL (United States); University of Notre Dame
  2. Northwestern Univ., Evanston, IL (United States)
  3. Memorial Univ. of Newfoundland, St. John's, NL (Canada)
  4. Concordia Univ., Montreal, QC (Canada)
  5. California State Univ., Los Angeles, CA (United States)
  6. Univ. of Wisconsin-Stevens Point, WI (United States)
+ Show Author Affiliations
Porphyrins are important molecules widely found in nature in the form of enzyme active sites and visible light absorption units. Recent interest in using these functional molecules as building blocks for the construction of metal–organic frameworks (MOFs) have rapidly increased due to the ease in which the locations of, and the distances between, the porphyrin units can be controlled in these porous crystalline materials. Porphyrin-based MOFs with atomically precise structures provide an ideal platform for the investigation of their structure–function relationships in the solid state without compromising accessibility to the inherent properties of the porphyrin building blocks. Here, this review will provide a historical overview of the development and applications of porphyrin-based MOFs from early studies focused on design and structures, to recent efforts on their utilization in biomimetic catalysis, photocatalysis, electrocatalysis, sensing, and biomedical applications.
Research Organization:
Univ. of Notre Dame, IN (United States); Northwestern Univ., Evanston, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
SC0012702; NA0003763; FG02-03ER15457; FG02-08ER15967
OSTI ID:
1706637
Alternate ID(s):
OSTI ID: 1809396
OSTI ID: 1870855
Journal Information:
Coordination Chemistry Reviews, Journal Name: Coordination Chemistry Reviews Vol. 429; ISSN 0010-8545
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

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Functional metal–organic frameworks as effective sensors of gases and volatile compounds journal January 2020
A mixed-ligand strategy regulates thorium-based MOFs journal January 2020
Selective decontamination of the reactive air pollutant nitrous acid via node-linker cooperativity in a metal–organic framework journal January 2019
Well-distributed Pt-nanoparticles within confined coordination interspaces of self-sensitized porphyrin metal–organic frameworks: synergistic effect boosting highly efficient photocatalytic hydrogen evolution reaction journal January 2019
Size control over metal–organic framework porous nanocrystals journal January 2019
A simple strategy for engineering heterostructures of Au nanoparticle-loaded metal–organic framework nanosheets to achieve plasmon-enhanced photocatalytic CO 2 conversion under visible light journal January 2019
In situ self-assembly of zirconium metal–organic frameworks onto ultrathin carbon nitride for enhanced visible light-driven conversion of CO 2 to CO journal January 2020
Biomimetic nanoscale metal–organic framework harnesses hypoxia for effective cancer radiotherapy and immunotherapy journal January 2020
A series of highly stable porphyrinic metal–organic frameworks based on iron–oxo chain clusters: design, synthesis and biomimetic catalysis journal January 2020
The oxidation of organic compounds by “singlet” oxygen journal January 1966
From simple to supramolecular cytochrome P450 mimics journal January 2000
New effective synthons for supramolecular self-assembly of meso-carboxyphenylporphyrins journal January 2000
Design strategies for supramolecular porphyrin-based materials journal January 2002
Crystal engineering of porphyrin framework solids journal January 2005
Metal–organic framework materials as catalysts journal January 2009
Singlet oxygen: there is indeed something new under the sun journal January 2010
Controlled growth of narrowly dispersed nanosize hexagonal MOF rods from Mn(iii)–porphyrin and In(NO3)3 and their application in olefin oxidation journal January 2012
Artificial enzymes based on supramolecular scaffolds journal January 2012
Addressing the terawatt challenge: scalability in the supply of chemical elements for renewable energy journal January 2012
Vertex-directed self-assembly of a high symmetry supermolecular building block using a custom-designed porphyrin journal January 2012
Versatile functionalization of the NU-1000 platform by solvent-assisted ligand incorporation journal January 2014
Nanomaterials with enzyme-like characteristics (nanozymes): next-generation artificial enzymes journal January 2013
Core Concept: Holey synthetic materials open their pores to medical applications journal April 2019
Multielectron transportation of polyoxometalate-grafted metalloporphyrin coordination frameworks for selective CO2-to-CH4 photoconversion journal July 2019
Two's company, three's a crowd: can H 2 S be the third endogenous gaseous transmitter? journal November 2002
Three-periodic nets and tilings: edge-transitive binodal structures journal August 2006
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal January 2002
A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst journal October 2012
Insulin Resistance and a Diabetes Mellitus-Like Syndrome in Mice Lacking the Protein Kinase Akt2 (PKBbeta ) journal June 2001
Balancing volumetric and gravimetric uptake in highly porous materials for clean energy journal April 2020
H2S Signals Through Protein S-Sulfhydration journal November 2009
Signaling by Gasotransmitters journal April 2009
Recent developments in robust microporous porphyrin solids journal February 2004
Trends in the Exchange Current for Hydrogen Evolution journal January 2005
Enzymes: An integrated view of structure, dynamics and function journal January 2006
Porphyrin-based photocatalysts for hydrogen production journal January 2020
Emerging applications of porphyrins in photomedicine journal April 2015
Ultrathin Cu-TCPP MOF nanosheets: a new theragnostic nanoplatform with magnetic resonance/near-infrared thermal imaging for synergistic phototherapy of cancers journal January 2018

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
77 NANOSCIENCE AND NANOTECHNOLOGY
Biomedical applications
Catalysis
Metal–organic frameworks
Porphyrin
Sensing