Phase mediated dynamics of self-propagating Co/Al nanolaminate reactions

Abere, Michael J.; Egan, Garth C.; Kittell, David E.; Campbell, Geoffrey H.; Adams, David P.

doi:10.1063/5.0015317

Phase mediated dynamics of self-propagating Co/Al nanolaminate reactions

Journal Article · Thu Aug 06 00:00:00 EDT 2020 · AIP Advances

DOI:https://doi.org/10.1063/5.0015317· OSTI ID:1704074

^[1]; ^[2]; ^[1]; Campbell, Geoffrey H. ^[2]; Adams, David P. ^[2]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

The ignition of sputter deposited nanolaminate foils comprised of alternating Co and Al layers results in rapid, self-propagating formation reactions. The propagating waves present after ignition of 150 nm-thick foils are characterized in movie mode dynamic transmission electron microscopy where these are found to have reaction speeds and wave morphology that vary with bilayer thickness. High speed videography reveals different bilayer thickness-wave character relationships in 750 nm- and 7500 nm-thick Co/Al foils. The reaction speed dependencies on bilayer thickness are calculated for each total thickness by treating the effect of radiation loss as a perturbation from an analytical model described by the difference in the heat of reaction measured in calorimetry and the adiabatic heat of product formation. From this model, an effective activation energy, diffusion constant, and flame temperatures are obtained, which allows for an interpretation of the reaction phase variations with laminate design and their effects on propagating wave morphology.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: AC52-07NA27344; NA0003525

OSTI ID:: 1704074

Alternate ID(s):: OSTI ID: 1646532

Report Number(s):: LLNL-JRNL--808124; 1014012

Journal Information:: AIP Advances, Journal Name: AIP Advances Journal Issue: 8 Vol. 10; ISSN 2158-3226

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

References (33)

Diffusion of iron, nickel and cobalt in aluminum Hirano, Ken-ichi; Agarwala, R. P.; Cohen, Morris Acta Metallurgica, Vol. 10, Issue 9 https://doi.org/10.1016/0001-6160(62)90100-1	journal	September 1962
Propagation of gasless reactions in solids—I. Analytical study of exothermic intermetallic reaction rates Hardt, A. P.; Phung, P. V. Combustion and Flame, Vol. 21, Issue 1 https://doi.org/10.1016/0010-2180(73)90009-6	journal	August 1973
Direct characterization of phase transformations and morphologies in moving reaction zones in Al/Ni nanolaminates using dynamic transmission electron microscopy Kim, J. S.; LaGrange, T.; Reed, B. W. Acta Materialia, Vol. 59, Issue 9 https://doi.org/10.1016/j.actamat.2011.02.030	journal	May 2011
In situ dynamic TEM characterization of unsteady crystallization during laser processing of amorphous germanium Egan, Garth C.; Li, Tian T.; Roehling, John D. Acta Materialia, Vol. 143 https://doi.org/10.1016/j.actamat.2017.10.003	journal	January 2018
Melting behaviour and homogeneity range of B2 CoAl and updated thermodynamic description of the Al–Co system Stein, F.; He, C.; Dupin, N. Intermetallics, Vol. 39 https://doi.org/10.1016/j.intermet.2013.03.011	journal	August 2013
Approaches for ultrafast imaging of transient materials processes in the transmission electron microscope LaGrange, Thomas; Reed, Bryan W.; Santala, Melissa K. Micron, Vol. 43, Issue 11, p. 1108-1120 https://doi.org/10.1016/j.micron.2012.04.010	journal	November 2012
Thermophysical properties and structure of stable and metastable liquid cobalt Wang, H. P.; Wei, B. Physics Letters A, Vol. 374, Issue 8 https://doi.org/10.1016/j.physleta.2009.12.045	journal	February 2010
A novel technique for MEMS packaging: Reactive bonding with integrated material systems Braeuer, J.; Besser, J.; Wiemer, M. Sensors and Actuators A: Physical, Vol. 188 https://doi.org/10.1016/j.sna.2012.01.015	journal	December 2012
Reactive multilayers fabricated by vapor deposition: A critical review Adams, D. P. Thin Solid Films, Vol. 576, p. 98-128 https://doi.org/10.1016/j.tsf.2014.09.042	journal	February 2015
Stabilizing effects of oxidation on propagating formation reactions occurring in nanometer-scale metal multilayers Adams, D. P.; Abere, M. J.; Sobczak, C. Thin Solid Films, Vol. 688 https://doi.org/10.1016/j.tsf.2019.05.068	journal	October 2019
Numerical study of the effect of heat losses on self-propagating reactions in multilayer foils Jayaraman, Swaminathan; Mann, Adrian B.; Reiss, Michael Combustion and Flame, Vol. 124, Issue 1-2 https://doi.org/10.1016/s0010-2180(00)00192-9	journal	January 2001
Joining bulk metallic glass using reactive multilayer foils Swiston, A. J.; Hufnagel, T. C.; Weihs, T. P. Scripta Materialia, Vol. 48, Issue 12, p. 1575-1580 https://doi.org/10.1016/s1359-6462(03)00164-7	journal	June 2003
High Heating Rate Reaction Dynamics of Al/CuO Nanolaminates by Nanocalorimetry-Coupled Time-of-Flight Mass Spectrometry DeLisio, Jeffery B.; Yi, Feng; LaVan, David A. The Journal of Physical Chemistry C, Vol. 121, Issue 5 https://doi.org/10.1021/acs.jpcc.6b11114	journal	January 2017
Modeling of thermodiffusion in liquid metal alloys Eslamian, Morteza; Sabzi, Fatemeh; Saghir, M. Ziad Physical Chemistry Chemical Physics, Vol. 12, Issue 41 https://doi.org/10.1039/c0cp00781a	journal	January 2010
Room-temperature soldering with nanostructured foils Wang, J.; Besnoin, E.; Duckham, A. Applied Physics Letters, Vol. 83, Issue 19 https://doi.org/10.1063/1.1623943	journal	November 2003
Time-resolved x-ray microdiffraction studies of phase transformations during rapidly propagating reactions in Al/Ni and Zr/Ni multilayer foils Trenkle, J. C.; Koerner, L. J.; Tate, M. W. Journal of Applied Physics, Vol. 107, Issue 11 https://doi.org/10.1063/1.3428471	journal	June 2010
In situ observation of rapid reactions in nanoscale Ni–Al multilayer foils using synchrotron radiation Fadenberger, Konrad; Gunduz, Ibrahim Emre; Tsotsos, Chrysostomos Applied Physics Letters, Vol. 97, Issue 14 https://doi.org/10.1063/1.3485673	journal	October 2010
Effect of thermal properties on self-propagating fronts in reactive nanolaminates Alawieh, Leen; Knio, Omar M.; Weihs, Timothy P. Journal of Applied Physics, Vol. 110, Issue 1 https://doi.org/10.1063/1.3599847	journal	July 2011
Modeling and characterizing the propagation velocity of exothermic reactions in multilayer foils Mann, A. B.; Gavens, A. J.; Reiss, M. E. Journal of Applied Physics, Vol. 82, Issue 3 https://doi.org/10.1063/1.365886	journal	August 1997
Studying exothermic reactions in the Ni-Al system at rapid heating rates using a nanocalorimeter Swaminathan, P.; Grapes, M. D.; Woll, K. Journal of Applied Physics, Vol. 113, Issue 14 https://doi.org/10.1063/1.4799628	journal	April 2013
Irreversible reactions studied with nanosecond transmission electron microscopy movies: Laser crystallization of phase change materials Santala, M. K.; Reed, B. W.; Raoux, S. Applied Physics Letters, Vol. 102, Issue 17 https://doi.org/10.1063/1.4803921	journal	April 2013
Reaction instabilities in Co/Al nanolaminates due to chemical kinetics variation over micron-scales Reeves, Robert V.; Adams, David P. Journal of Applied Physics, Vol. 115, Issue 4, Article No. 044911 https://doi.org/10.1063/1.4863339	journal	January 2014
Time resolved electron microscopy for in situ experiments Campbell, Geoffrey H.; McKeown, Joseph T.; Santala, Melissa K. Applied Physics Reviews, Vol. 1, Issue 4 https://doi.org/10.1063/1.4900509	journal	December 2014
Ignition and self-propagating reactions in Al/Pt multilayers of varied design Adams, D. P.; Reeves, R. V.; Abere, M. J. Journal of Applied Physics, Vol. 124, Issue 9 https://doi.org/10.1063/1.5026293	journal	September 2018
Heating rate dependent ignition of Al/Pt nanolaminates through pulsed laser irradiation Abere, Michael J.; Yarrington, Cole D.; Adams, David P. Journal of Applied Physics, Vol. 123, Issue 23 https://doi.org/10.1063/1.5026507	journal	June 2018
Exothermic reaction waves in multilayer nanofilms Rogachev, A. S. Russian Chemical Reviews, Vol. 77, Issue 1 https://doi.org/10.1070/rc2008v077n01abeh003748	journal	January 2008
Epitaxial growth of cobalt films on Cu(100): a crystallographic LEED determination Cerda, J. R.; Andres, P. L. de; Cebollada, A. Journal of Physics: Condensed Matter, Vol. 5, Issue 14 https://doi.org/10.1088/0953-8984/5/14/005	journal	April 1993
Complexion dictated thermal resistance with interface density in reactive metal multilayers Saltonstall, Christopher B.; McClure, Zachary D.; Abere, Michael J. Physical Review B, Vol. 101, Issue 24 https://doi.org/10.1103/physrevb.101.245422	journal	June 2020
Self-propagating, high-temperature combustion synthesis of rhombohedral AlPt thin films Adams, D. P.; Rodriguez, M. A.; Tigges, C. P. Journal of Materials Research, Vol. 21, Issue 12 https://doi.org/10.1557/jmr.2006.0387	journal	December 2006
Rare-earth transition-metal intermetallic compounds produced via self-propagating, high-temperature synthesis McDonald, Joel P.; Rodriguez, Mark A.; Jones, Eric D. Journal of Materials Research, Vol. 25, Issue 4 https://doi.org/10.1557/jmr.2010.0091	journal	April 2010
Modeling Self-Propagating Exothermic Reactions in Multilayer Systems Jayaraman, S.; Mann, A. B.; Knio, O. M. MRS Proceedings, Vol. 481 https://doi.org/10.1557/proc-481-563	journal	January 1997
Solid-liquid Interface Energy of Metals at Melting Point and Undercooled State Jian, Zengyun; Kuribayashi, Kazuhiko; Jie, Wanqi MATERIALS TRANSACTIONS, Vol. 43, Issue 4 https://doi.org/10.2320/matertrans.43.721	journal	January 2002
Historical retrospective of SHS: An autoreview Merzhanov, A. G.; Borovinskaya, I. P. International Journal of Self-Propagating High-Temperature Synthesis, Vol. 17, Issue 4 https://doi.org/10.3103/s1061386208040079	journal	December 2008

Similar Records

Reactive Ni/Ti nanolaminates

Journal Article · Sun Nov 01 00:00:00 EDT 2009 · Journal of Applied Physics · OSTI ID:21361903

Heating rate dependent ignition of Al/Pt nanolaminates through pulsed laser irradiation

Journal Article · Wed Jun 20 20:00:00 EDT 2018 · Journal of Applied Physics · OSTI ID:1457521

Related Subjects

36 MATERIALS SCIENCE

Phase mediated dynamics of self-propagating Co/Al nanolaminate reactions

Citation Formats

References (33)

Similar Records

Related Subjects