Addition of Aryl and Fluoroaklyl Radicals to Fullerene C70: ESR Detection of Five Regioisomeric Adducts and Density Functional Calculations

Journal Article · Mon Jan 01 04:00:00 EST 1996 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/ja960979h· OSTI ID:1688452

Borghi, R ^[1]; Lunazzi, L ^[1]; Placcucci, G ^[1]; Krusic, P J. ^[1]; Dixon, David A. ^[2]; Matsuzawa, Nobuyuki ^[3]; Ata, M ^[1]

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1. unknown
2. BATTELLE (PACIFIC NW LAB)
3. VISITORS

The addition of several photochemically generated aryl and fluoroalkyl radicals to fullerene C70 was studied by electron spin resonance and the results were compared with those obtained with C60. While simple alkyl radicals afford only three of the five expected RC70• regioisomers, the more reactive aryl and fluoroalkyl radicals give rise to four, except for the trifluoromethyl radical which yielded for the first time the ESR spectra of all five expected isomers. Semiempirical MO calculations and density functional theory calculations were carried out for HC60• and for the five HC70• regioisomers as models for the corresponding alkyl, aryl, and fluoroalkyl analogs in order to describe the unpaired electron distribution in these radical species and as an aid in the assignment of the observed spectra to specific RC70• regioisomers.

• Research Organization: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
• Sponsoring Organization: USDOE
• DOE Contract Number: AC05-76RL01830
• OSTI ID: 1688452
• Report Number(s): PNWD-SA-4409
• Journal Information: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 32 Vol. 118
• Country of Publication: United States
• Language: English