On the nonlinear temperature dependence of residual stresses in solid oxide fuel cells

Lara‐Curzio, Edgar; Cakmak, Ercan; Lin, Lianshan; Marquez‐Rossy, Andres E.; Armstrong, Beth; Flores‐Betancourt, Alexis; Macias, Antonio

doi:10.1111/jace.17488

On the nonlinear temperature dependence of residual stresses in solid oxide fuel cells

Journal Article · Sat Oct 03 00:00:00 EDT 2020 · Journal of the American Ceramic Society

DOI:https://doi.org/10.1111/jace.17488· OSTI ID:1671423

^[1]; ^[1]; ^[1]; Marquez‐Rossy, Andres E. ^[1]; ^[1]; Flores‐Betancourt, Alexis ^[1]; Macias, Antonio ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The residual stresses in a dense yttria-stabilized zirconia (YSZ) layer bonded to a porous NiO-YSZ substrate were measured by X-ray diffraction in air between 25°C and 900°C. In this work, it was found that the residual stresses on the outer surface of the YSZ layer were compressive, that their magnitude increased with decreasing temperature, and that the temperature dependence was nonlinear particularly at temperatures below 600°C. An elastic model that incorporates micromechanics and laminate theory was formulated to successfully predicts the nonlinearity of the temperature dependence of the residual stresses by accounting for the effect of the order-disorder transition experienced by YSZ around 600°C and the magnetic transition of NiO at the Néel temperature around 265°C, on the properties of these materials. The implications of the results for the reliability of solid oxide fuel cells are discussed.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Fossil Energy (FE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1671423

Alternate ID(s):: OSTI ID: 1805094

Journal Information:: Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Journal Issue: 1; ISSN 0002-7820

Publisher:: American Ceramic SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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On the nonlinear temperature dependence of residual stresses in solid oxide fuel cells

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