Hydrophobic amine-based binary mixtures of active pharmaceutical and food grade ingredients: characterization and application in indium extraction from aqueous hydrochloric acid media

Edgecomb, Joseph; Tereshatov, Evgeny; Zante, Guillaume; Boltoeva, Maria; Folden, III, Charles M.

doi:10.1039/d0gc02452j

Hydrophobic amine-based binary mixtures of active pharmaceutical and food grade ingredients: characterization and application in indium extraction from aqueous hydrochloric acid media

Journal Article · Wed Sep 23 00:00:00 EDT 2020 · Green Chemistry

DOI:https://doi.org/10.1039/d0gc02452j· OSTI ID:1668867

Edgecomb, Joseph ^[1]; Tereshatov, Evgeny ^[2]; Zante, Guillaume ^[3]; Boltoeva, Maria ^[3]; Folden, III, Charles M. ^[2]

Texas A&M University, College Station, TX (United States); Saint Martin’s University, Lacey, WA (United States); Texas A&M University
Texas A&M University, College Station, TX (United States)
Université de Strasbourg (France)

The wide spread use of hazardous and expensive solvents for the liquid-liquid extraction (LLE) of critical metals has been a growing source of waste in the metal refinement industry. We have developed and characterized room temperature liquid hydrophobic binary mixtures based on common pharmaceutical and food grade compounds as sustainable, cost effective alternatives to both ionic liquids and conventional solvents. Additionally, we introduce liquid mixtures with Proton Sponge® (1,8-bis(dimethylamino)naphthalene), one of the strongest known organic bases. These mixtures have been applied to the LLE of indium(III) ions from hydrochloric acid solutions, displaying an extraction efficiency greater than 99% in some systems. Here, a systematic approach to identifying the underlying mechanism of extraction, in particular relating to the charge, solubility, and complexation of the indium species in the organic phase has been developed.

View Accepted Manuscript (DOE)

Research Organization:: Texas A&M University, College Station, TX (United States)

Sponsoring Organization:: USDOE; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Nuclear Physics (NP)

Grant/Contract Number:: FG02-93ER40773; NA0003180

OSTI ID:: 1668867

Alternate ID(s):: OSTI ID: 1670231

Journal Information:: Green Chemistry, Journal Name: Green Chemistry Journal Issue: 22 Vol. 2020; ISSN 1463-9262

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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