Hydrophobic polymerized ionic liquids for trace metal solid phase extraction: thallium transfer from hydrochloric acid media

Tereshatov, Evgeny E.; Boltoeva, Maria; Mazan, Valérie; Baley, Colton; Folden, Charles M.

doi:10.1039/c9nj00689c

Title: Hydrophobic polymerized ionic liquids for trace metal solid phase extraction: thallium transfer from hydrochloric acid media

Journal Article · Thu May 09 00:00:00 EDT 2019 · New Journal of Chemistry

DOI:https://doi.org/10.1039/c9nj00689c· OSTI ID:1529986

^[1];

^[2]; Mazan, Valérie ^[2]; Baley, Colton ^[1];

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Texas A & M Univ., College Station, TX (United States)
Univ. de Strasbourg (France)

It is known that some neat room-temperature hydrophobic ionic liquids can extract metallic species from aqueous solutions. The unique properties of such organic media allow for the application of polymerization techniques to convert the liquid organic phase to a solid one. In this work, a pyrrolidinium-based ionic liquid and a corresponding polymer with bis(trifluoromethanesulfonyl)imide counter anion have been considered for optimization of thallium(III) migration in liquid-liquid and solid-liquid extraction systems. Neither trivalent indium nor monovalent thallium were absorbed by the polymer layer. A mathematical model to describe the mechanism of metal extraction in these systems has been developed. Thermodynamic parameters as adsorption enthalpy, entropy, and Gibbs energy have also been determined.

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Research Organization:: Texas A & M Univ., College Station, TX (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Nuclear Physics (NP)

Grant/Contract Number:: NA0003180; FG02-93ER40773

OSTI ID:: 1529986

Alternate ID(s):: OSTI ID: 1515092

Journal Information:: New Journal of Chemistry, Vol. 43, Issue 23; ISSN 1144-0546

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 4 works

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