Effect of hydrophobic ionic liquids aqueous solubility on metal extraction from hydrochloric acid media: Mathematical modelling and trivalent thallium behavior

Tereshatov, Evgeny E.; Mazan, Valérie; Boltoeva, Maria; Folden, Charles M.

doi:10.1016/j.seppur.2020.117650

Effect of hydrophobic ionic liquids aqueous solubility on metal extraction from hydrochloric acid media: Mathematical modelling and trivalent thallium behavior

Journal Article · Sat Aug 29 00:00:00 EDT 2020 · Separation and Purification Technology

DOI:https://doi.org/10.1016/j.seppur.2020.117650· OSTI ID:1668865

Tereshatov, Evgeny E. ^[1]; Mazan, Valérie ^[2]; Boltoeva, Maria ^[2]; Folden, Charles M. ^[3]

Texas A & M Univ., College Station, TX (United States); Texas A&M University
Univ. of Strasbourg (France)
Texas A & M Univ., College Station, TX (United States)

A mathematical model to explain cations’ solubility of both protic and aprotic ionic liquids in a wide range of hydrochloric acid solutions has been developed. The concept of this model is based on an assumption of the mineral acid extraction into the organic phase, formation of a salt there between an ionic liquid cation and chloride-anion due to ions recombination and partial salt back-extraction. The proposed approach allows estimating corresponding extraction constants. Comparison of calculated and experimentally measured solubility product constants shows that they are in good agreement. It has been determined also that the more the hydrophilicity of the ionic liquids’ cation the more hydrochloric acid is extracted. Furthermore, this model has been utilized to facilitate analysis of thallium transfer into hydrophobic ionic liquids providing insights into the mechanism of metal extraction.

View Accepted Manuscript (DOE)

Research Organization:: Texas A&M University, College Station, TX (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Nuclear Physics (NP)

Grant/Contract Number:: FG02-93ER40773; NA0003180

OSTI ID:: 1668865

Alternate ID(s):: OSTI ID: 1659335

Journal Information:: Separation and Purification Technology, Journal Name: Separation and Purification Technology Vol. 255; ISSN 1383-5866

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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