ToF-SIMS depth profiling of altered glass

Collin, Marie; Gin, Stéphane; Jollivet, Patrick; Dupuy, Laurent; Dauvois, Vincent; Duffours, Laurent

doi:10.1038/s41529-019-0076-3

Title: ToF-SIMS depth profiling of altered glass

Journal Article · Tue Apr 02 00:00:00 EDT 2019 · npj Materials Degradation

DOI:https://doi.org/10.1038/s41529-019-0076-3· OSTI ID:1667377

^[1];

^[1]; Jollivet, Patrick ^[1]; Dupuy, Laurent ^[2]; Dauvois, Vincent ^[3]; Duffours, Laurent ^[4]

Alternative Energies and Atomic Energy Commission (CEA), Bagnols-sur-Ceze (France)
Tescan Analytics, Fuveau (France)
Univ. of Paris-Saclay, Gif-sur-Yvette (France)
PRIME Verre, Montpellier (France)

Glass and mineral corrosion usually leads to the formation of morphologically and compositionally complex surface layers that can be characterized by various analytical techniques to infer rate control mechanisms. In this study, we investigate the capabilities and limitations of time-of-flight secondary ion mass spectrometry (ToF-SIMS) to better understand chemical processes of glass corrosion. In particular, we focus on the potential impact of the ToF-SIMS ion beam on the distribution of several elements of interest in alteration layers formed on International Simple Glass, a six-oxide reference glass altered in a solution enriched in alkalis and spiked with H₂¹⁸O. A thin flake of glass partially altered on both sides is analyzed entirely from one side to the other to determine whether atoms weakly bonded to the solid are displaced by the beams. We highlight the beam effect on cations weakly bonded to the silicate network (Li, Na, K, and B, Ca, Cs to a lesser extent) affecting the profile shape of these elements. No impact is observed on ¹⁸O and H, but it is demonstrated that quantification of isotopic ratios is possible only for a limited range of isotopic enrichment.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Performance and Design of Nuclear Waste Forms and Containers (WastePD); Alternative Energies and Atomic Energy Commission (CEA), Bagnols-sur-Ceze (France)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0016584

OSTI ID:: 1667377

Journal Information:: npj Materials Degradation, Vol. 3, Issue 1; ISSN 2397-2106

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

References (57)

Comprehensive Application of Time-of-flight Secondary Ion Mass Spectrometry (TOF-SIMS) for Ionic Imaging and Bio-energetic Analysis of Club Drug-induced Cognitive Deficiency Youn, Su-Chung; Chen, Li-You; Chiou, Ruei-Jen Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep18420	journal	December 2015
Origin and consequences of silicate glass passivation by surface layers Gin, Stéphane; Jollivet, Patrick; Fournier, Maxime Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7360	journal	February 2015
Nuclear Glass Durability: New Insight into Alteration Layer Properties Gin, Stéphane; Guittonneau, Claire; Godon, Nicole The Journal of Physical Chemistry C, Vol. 115, Issue 38 https://doi.org/10.1021/jp205477q	journal	August 2011
Long-term weathering rate of stained-glass windows using H and O isotopes Sessegolo, Loryelle; Verney-Carron, Aurélie; Saheb, Mandana npj Materials Degradation, Vol. 2, Issue 1 https://doi.org/10.1038/s41529-018-0038-1	journal	June 2018
The controversial role of inter-diffusion in glass alteration Gin, S.; Neill, L.; Fournier, M. Chemical Geology, Vol. 440 https://doi.org/10.1016/j.chemgeo.2016.07.014	journal	November 2016
Impact of alkali on the passivation of silicate glass Collin, Marie; Fournier, Maxime; Charpentier, Thibault npj Materials Degradation, Vol. 2, Issue 1 https://doi.org/10.1038/s41529-018-0036-3	journal	May 2018
Heavy ion radiation ageing impact on long-term glass alteration behavior Mougnaud, Sarah; Tribet, Magaly; Renault, Jean-Philippe Journal of Nuclear Materials, Vol. 510 https://doi.org/10.1016/j.jnucmat.2018.07.046	journal	November 2018
New insight into atmospheric alteration of alkali-lime silicate glasses Alloteau, Fanny; Lehuédé, Patrice; Majérus, Odile Corrosion Science, Vol. 122 https://doi.org/10.1016/j.corsci.2017.03.025	journal	July 2017
The albite-water system: Part III. Characterization of leached and hydrogen-enriched layers formed at 300°C using MeV ion beam techniques Hellmann, Roland; Dran, Jean-Claude; Della Mea, Gianantonio Geochimica et Cosmochimica Acta, Vol. 61, Issue 8 https://doi.org/10.1016/S0016-7037(97)00022-7	journal	April 1997
Atom-Probe Tomography, TEM and ToF-SIMS study of borosilicate glass alteration rim: A multiscale approach to investigating rate-limiting mechanisms Gin, S.; Jollivet, P.; Barba Rossa, G. Geochimica et Cosmochimica Acta, Vol. 202 https://doi.org/10.1016/j.gca.2016.12.029	journal	April 2017
Early stages of glass alteration in the coastal atmosphere Palomar, Teresa; de la Fuente, Daniel; Morcillo, Manuel Building and Environment, Vol. 147 https://doi.org/10.1016/j.buildenv.2018.10.034	journal	January 2019
Unifying natural and laboratory chemical weathering with interfacial dissolution–reprecipitation: A study based on the nanometer-scale chemistry of fluid–silicate interfaces Hellmann, Roland; Wirth, Richard; Daval, Damien Chemical Geology, Vol. 294-295 https://doi.org/10.1016/j.chemgeo.2011.12.002	journal	February 2012
Interdiffusion of hydrogen and alkali ions in a glass surface Doremus, R. H. Journal of Non-Crystalline Solids, Vol. 19 https://doi.org/10.1016/0022-3093(75)90079-4	journal	December 1975
Back side SIMS analysis: Back side SIMS analysis Stevie, F. A.; Garcia, R.; Richardson, C. Surface and Interface Analysis, Vol. 46, Issue S1 https://doi.org/10.1002/sia.5470	journal	March 2014
An international initiative on long-term behavior of high-level nuclear waste glass Gin, S.; Abdelouas, A.; Criscenti, L. J. Materials Today, Vol. 16, Issue 6 https://doi.org/10.1016/j.mattod.2013.06.008	journal	June 2013
The conservation of stained-glass windows in Latin America: A literature overview M. Corrêa Pinto, Amanda; Macedo, Maria Filomena; G. Vilarigues, Márcia Journal of Cultural Heritage, Vol. 34 https://doi.org/10.1016/j.culher.2018.04.019	journal	November 2018
The combined application of FTIR microspectroscopy and ToF-SIMS imaging in the study of prostate cancer Gazi, Ehsan; Dwyer, John; Lockyer, Nicholas Faraday Discussions, Vol. 126 https://doi.org/10.1039/b304883g	journal	January 2004
Impact of Zn, Mg, Ni and Co elements on glass alteration: Additive effects Aréna, H.; Godon, N.; Rébiscoul, D. Journal of Nuclear Materials, Vol. 470 https://doi.org/10.1016/j.jnucmat.2015.11.050	journal	March 2016
Characterization of polymer solar cells by TOF-SIMS depth profiling Bulle-Lieuwma, C. W. T.; van Gennip, W. J. H.; van Duren, J. K. J. Applied Surface Science, Vol. 203-204 https://doi.org/10.1016/S0169-4332(02)00756-0	journal	January 2003
Evidence for 6-Coordinated Zirconium in Inactive Nuclear Waste Glasses Galoisy, Laurence; Pélegrin, Emmanuèle; Arrio, Marie-Anne Journal of the American Ceramic Society, Vol. 82, Issue 8 https://doi.org/10.1111/j.1151-2916.1999.tb02065.x	journal	August 1999
Analysis of insulating specimens with the Cameca IMS4f Migeon, H. N.; Schuhmacher, M.; Slodzian, G. Surface and Interface Analysis, Vol. 16, Issue 1-12 https://doi.org/10.1002/sia.740160105	journal	July 1990
Chemometric evaluation of time-of-flight secondary ion mass spectrometry data of minerals in the frame of futurein situ analyses of cometary material by COSIMA onboard ROSETTA Engrand, Cecile; Kissel, Jochen; Krueger, Franz R. Rapid Communications in Mass Spectrometry, Vol. 20, Issue 8 https://doi.org/10.1002/rcm.2448	journal	January 2006
Differences between Li, Na, and K migration in thin SiO ₂ films during ToF-SIMS O ₂ ⁺ depth profiling Krivec, Stefan; Amsüss, Andreas; Schwab, Stefan Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 36, Issue 3 https://doi.org/10.1116/1.5019659	journal	May 2018
Towards a unifying mechanistic model for silicate glass corrosion Lenting, Christoph; Plümper, Oliver; Kilburn, Matt npj Materials Degradation, Vol. 2, Issue 1 https://doi.org/10.1038/s41529-018-0048-z	journal	September 2018
Solid state diffusion during nuclear glass residual alteration in solution Chave, T.; Frugier, P.; Ayral, A. Journal of Nuclear Materials, Vol. 362, Issue 2-3 https://doi.org/10.1016/j.jnucmat.2007.01.095	journal	May 2007
Diffusion of water in rhyolite glass: diffusion–reaction model Doremus, R. H. Journal of Non-Crystalline Solids, Vol. 261, Issue 1-3 https://doi.org/10.1016/S0022-3093(99)00604-3	journal	January 2000
Alteration of hyaloclastites in the HSDP 2 Phase 1 Drill Core: 2. Mass balance of the conversion of sideromelane to palagonite and chabazite: ALTERATION OF HYALOCLASTITES, 2 Walton, Anthony W.; Schiffman, Peter; Macpherson, G. L. Geochemistry, Geophysics, Geosystems, Vol. 6, Issue 9 https://doi.org/10.1029/2004GC000903	journal	September 2005
Structure and Chemical Durability of Lead Crystal Glass Angeli, Frédéric; Jollivet, Patrick; Charpentier, Thibault Environmental Science & Technology, Vol. 50, Issue 21 https://doi.org/10.1021/acs.est.6b02971	journal	October 2016
The mechanism of borosilicate glass corrosion revisited Geisler, Thorsten; Nagel, Thorsten; Kilburn, Matt R. Geochimica et Cosmochimica Acta, Vol. 158 https://doi.org/10.1016/j.gca.2015.02.039	journal	June 2015
A High Depth Resolution Backside Secondary Ion Mass Spectrometry Technique Used for Studying Metal/Gaas Contacts Palmstrøm, C. J.; Schwarz, S. A.; Marshall, E. D. MRS Proceedings, Vol. 126 https://doi.org/10.1557/PROC-126-283	journal	January 1988
Dynamics of self-reorganization explains passivation of silicate glasses Gin, Stéphane; Collin, Marie; Jollivet, Patrick Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04511-2	journal	June 2018
Insight into silicate-glass corrosion mechanisms Cailleteau, Céline; Angeli, Frédéric; Devreux, François Nature Materials, Vol. 7, Issue 12 https://doi.org/10.1038/nmat2301	journal	October 2008
Aqueous corrosion of borosilicate glass under acidic conditions: A new corrosion mechanism Geisler, Thorsten; Janssen, Arne; Scheiter, Daniel Journal of Non-Crystalline Solids, Vol. 356, Issue 28-30 https://doi.org/10.1016/j.jnoncrysol.2010.04.033	journal	June 2010
Alteration of synthetic basaltic glass in silica saturated conditions: Analogy with nuclear glass Ducasse, T.; Gourgiotis, A.; Pringle, E. Applied Geochemistry, Vol. 97 https://doi.org/10.1016/j.apgeochem.2018.08.001	journal	October 2018
Resumption of Alteration at High Temperature and pH: Rates Measurements and Comparison with Initial Rates Fournier, Maxime; Frugier, Pierre; Gin, Stéphane Procedia Materials Science, Vol. 7 https://doi.org/10.1016/j.mspro.2014.10.026	journal	January 2014
Low-temperature lithium diffusion in simulated high-level boroaluminosilicate nuclear waste glasses Neeway, James J.; Kerisit, Sebastien; Gin, Stéphane Journal of Non-Crystalline Solids, Vol. 405 https://doi.org/10.1016/j.jnoncrysol.2014.08.053	journal	December 2014
Accurate SIMS depth profiling for ultra-shallow implants using backside SIMS Hongo, C.; Tomita, M.; Takenaka, M. Applied Surface Science, Vol. 203-204 https://doi.org/10.1016/S0169-4332(02)00876-0	journal	January 2003
Understanding the mechanisms of Si–K–Ca glass alteration using silicon isotopes Verney-Carron, Aurélie; Sessegolo, Loryelle; Saheb, Mandana Geochimica et Cosmochimica Acta, Vol. 203 https://doi.org/10.1016/j.gca.2017.01.030	journal	April 2017
Development of drug adsorbates onto soluble inorganic silicate glass surface: example with acetaminophen Hristova, Yoanna; Djambaski, Peter; Samuneva, Biserka Journal of Materials Science: Materials in Medicine, Vol. 19, Issue 2 https://doi.org/10.1007/s10856-007-3190-7	journal	August 2007
Nanometre-scale evidence for interfacial dissolution–reprecipitation control of silicate glass corrosion Hellmann, Roland; Cotte, Stéphane; Cadel, Emmanuel Nature Materials, Vol. 14, Issue 3 https://doi.org/10.1038/nmat4172	journal	January 2015
Backside-SIMS profiling of dopants in thin Hf silicate film Hongo, Chie; Takenaka, Miyuki; Kamimuta, Yuuichi Applied Surface Science, Vol. 231-232 https://doi.org/10.1016/j.apsusc.2004.03.118	journal	June 2004
Glass science in art and conservation Murcia-Mascarós, Sonia Journal of Cultural Heritage, Vol. 9 https://doi.org/10.1016/j.culher.2008.10.001	journal	December 2008
Nanoscale imaging of alteration layers of corroded international simple glass particles using ToF-SIMS Zhang, Jiandong; Neeway, James J.; Zhang, Yanyan Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 404 https://doi.org/10.1016/j.nimb.2017.01.053	journal	August 2017
The surface analysis of insulators by SIMS: Charge neutralization and stabilization of the surface potential Hunt, C. P.; Stoddart, C. T. H.; Seah, M. P. Surface and Interface Analysis, Vol. 3, Issue 4 https://doi.org/10.1002/sia.740030404	journal	August 1981
Elemental and isotopic (29Si and 18O) tracing of glass alteration mechanisms Valle, Nathalie; Verney-Carron, Aurélie; Sterpenich, Jérôme Geochimica et Cosmochimica Acta, Vol. 74, Issue 12 https://doi.org/10.1016/j.gca.2010.03.028	journal	June 2010
Nuclear Waste Glasses - How Durable? Grambow, B. Elements, Vol. 2, Issue 6 https://doi.org/10.2113/gselements.2.6.357	journal	December 2006
An investigation of hydrogen depth profiling using ToF-SIMS: Hydrogen depth profiling using ToF-SIMS Zhu, Zihua; Shutthanandan, Vaithiyalingam; Engelhard, Mark Surface and Interface Analysis, Vol. 44, Issue 2 https://doi.org/10.1002/sia.3826	journal	September 2011
Use of Hydrogen Isotopes to Understand Stained Glass Weathering Procedia Earth and Planetary Science, Vol. 13 https://doi.org/10.1016/j.proeps.2015.07.015	journal	January 2015
Structure of International Simple Glass and properties of passivating layer formed in circumneutral pH conditions Collin, Marie; Fournier, Maxime; Frugier, Pierre npj Materials Degradation, Vol. 2, Issue 1 https://doi.org/10.1038/s41529-017-0025-y	journal	February 2018
Contribution of zeolite-seeded experiments to the understanding of resumption of glass alteration Fournier, Maxime; Gin, Stéphane; Frugier, Pierre npj Materials Degradation, Vol. 1, Issue 1 https://doi.org/10.1038/s41529-017-0018-x	journal	November 2017
Resumption of nuclear glass alteration: State of the art Fournier, Maxime; Gin, Stéphane; Frugier, Pierre Journal of Nuclear Materials, Vol. 448, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2014.02.022	journal	May 2014
Long-term alteration of basaltic glass: Mechanisms and rates Parruzot, Benjamin; Jollivet, Patrick; Rébiscoul, Diane Geochimica et Cosmochimica Acta, Vol. 154 https://doi.org/10.1016/j.gca.2014.12.011	journal	April 2015
Glass–water interphase reactivity with calcium rich solutions Chave, T.; Frugier, P.; Gin, S. Geochimica et Cosmochimica Acta, Vol. 75, Issue 15 https://doi.org/10.1016/j.gca.2011.05.005	journal	August 2011
Long-term Behavior Science: The cornerstone approach for reliably assessing the long-term performance of nuclear waste Poinssot, Christophe; Gin, Stéphane Journal of Nuclear Materials, Vol. 420, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2011.09.012	journal	January 2012
ToF-SIMS application in the visualization and analysis of fingerprints after contact with amphetamine drugs Szynkowska, M. I.; Czerski, K.; Rogowski, J. Forensic Science International, Vol. 184, Issue 1-3 https://doi.org/10.1016/j.forsciint.2008.11.003	journal	January 2009
First-order dissolution rate law and the role of surface layers in glass performance assessment Grambow, B.; Müller, R. Journal of Nuclear Materials, Vol. 298, Issue 1-2 https://doi.org/10.1016/s0022-3115(01)00619-5	journal	September 2001
Interaction of water vapor with silicate glass surfaces: Mass-spectrometric investigations Kudriavtsev, Yu.; Asomoza-Palacio, R.; Manzanilla-Naim, L. Technical Physics Letters, Vol. 43, Issue 5 https://doi.org/10.1134/s1063785017050054	journal	May 2017

Similar Records

Nanoscale imaging of hydrogen and sodium in alteration layers of corroded glass using ToF-SIMS: Is an auxiliary sputtering ion beam necessary?

Journal Article · Thu Oct 11 00:00:00 EDT 2018 · Surface and Interface Analysis · OSTI ID:1667377

Zhang, Jiandong; Zhang, Yanyan; Collin, Marie; +4 more

Nanoscale imaging of alteration layers of corroded international simple glass particles using ToF-SIMS

Journal Article · Fri Feb 24 00:00:00 EST 2017 · Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms · OSTI ID:1667377

Zhang, Jiandong; Neeway, James J.; Zhang, Yanyan; +4 more

Nanoscale imaging of alteration layers of corroded international simple glass particles using ToF-SIMS

Journal Article · Tue Aug 01 00:00:00 EDT 2017 · Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms · OSTI ID:1667377

Zhang, Jiandong; Neeway, James J.; Zhang, Yanyan; +4 more

Related Subjects

36 MATERIALS SCIENCE
chemical physics
solid-state chemistry

Title: ToF-SIMS depth profiling of altered glass

Citation Formats

References (57)

Similar Records

Related Subjects