ToF-SIMS depth profiling of altered glass

Collin, Marie; Gin, Stéphane; Jollivet, Patrick; Dupuy, Laurent; Dauvois, Vincent; Duffours, Laurent

doi:10.1038/s41529-019-0076-3

ToF-SIMS depth profiling of altered glass

Journal Article · Tue Apr 02 00:00:00 EDT 2019 · npj Materials Degradation

DOI:https://doi.org/10.1038/s41529-019-0076-3· OSTI ID:1667377

^[1]; ^[2]; Jollivet, Patrick ^[2]; Dupuy, Laurent ^[3]; Dauvois, Vincent ^[4]; Duffours, Laurent ^[5]

Alternative Energies and Atomic Energy Commission (CEA), Bagnols-sur-Ceze (France); CEA, France
Alternative Energies and Atomic Energy Commission (CEA), Bagnols-sur-Ceze (France)
Tescan Analytics, Fuveau (France)
Univ. of Paris-Saclay, Gif-sur-Yvette (France)
PRIME Verre, Montpellier (France)

Glass and mineral corrosion usually leads to the formation of morphologically and compositionally complex surface layers that can be characterized by various analytical techniques to infer rate control mechanisms. In this study, we investigate the capabilities and limitations of time-of-flight secondary ion mass spectrometry (ToF-SIMS) to better understand chemical processes of glass corrosion. In particular, we focus on the potential impact of the ToF-SIMS ion beam on the distribution of several elements of interest in alteration layers formed on International Simple Glass, a six-oxide reference glass altered in a solution enriched in alkalis and spiked with H₂¹⁸O. A thin flake of glass partially altered on both sides is analyzed entirely from one side to the other to determine whether atoms weakly bonded to the solid are displaced by the beams. We highlight the beam effect on cations weakly bonded to the silicate network (Li, Na, K, and B, Ca, Cs to a lesser extent) affecting the profile shape of these elements. No impact is observed on ¹⁸O and H, but it is demonstrated that quantification of isotopic ratios is possible only for a limited range of isotopic enrichment.

View Accepted Manuscript (DOE)

Research Organization:: Alternative Energies and Atomic Energy Commission (CEA), Bagnols-sur-Ceze (France); Energy Frontier Research Centers (EFRC) (United States). Center for Performance and Design of Nuclear Waste Forms and Containers (WastePD)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0016584

OSTI ID:: 1667377

Alternate ID(s):: OSTI ID: 23137871

Journal Information:: npj Materials Degradation, Journal Name: npj Materials Degradation Journal Issue: 1 Vol. 3; ISSN 2397-2106

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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