Sulfur donating extractants for the separation of trivalent actinides and lanthanides

Bessen, N. P.; Jackson, J. A.; Jensen, M. P.; Shafer, J. C.

doi:10.1016/j.ccr.2020.213446

Sulfur donating extractants for the separation of trivalent actinides and lanthanides

Journal Article · Sat Jul 11 00:00:00 EDT 2020 · Coordination Chemistry Reviews

DOI:https://doi.org/10.1016/j.ccr.2020.213446· OSTI ID:1657529

^[1]; Jackson, J. A. ^[2]; Jensen, M. P. ^[2]; Shafer, J. C. ^[2]

Colorado School of Mines, Golden, CO (United States); Colorado School of Mines
Colorado School of Mines, Golden, CO (United States)

The effective separation of trivalent actinides and lanthanides is capable of reducing the long term radiation hazard associated with used nuclear fuel. Here, this class of separation exploits the tendency of ligands containing large and polarizable soft donor atoms to preferentially bind to the trivalent actinides instead of the lanthanides. Among the soft donors, nitrogen and sulfur based ligands have received the most attention with sulfur donors generally having greater selectivity for the actinides. Herein, the speciation, mechanism, and selectivity for the extraction of lanthanides and actinides from aqueous media into an organic phase by various sulfur containing extractants is reviewed.

View Accepted Manuscript (DOE)

Research Organization:: Colorado School of Mines, Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0020189

OSTI ID:: 1657529

Alternate ID(s):: OSTI ID: 1638276

Journal Information:: Coordination Chemistry Reviews, Journal Name: Coordination Chemistry Reviews Vol. 421; ISSN 0010-8545

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (91)

Novel Ligands for the Separation of Trivalent Lanthanides and Actinides – Tetrakis(phosphane sulfide) and -(phosphinic acid) Cavitands Boerrigter, Harold; Tomasberger, Tanja; Verboom, Willem European Journal of Organic Chemistry, Vol. 1999, Issue 3 https://doi.org/10.1002/(SICI)1099-0690(199903)1999:3<665::AID-EJOC665>3.0.CO;2-F	journal	March 1999
Coordination of Actinides and the Chemistry Behind Solvent Extraction Clark, Aurora E.; Yang, Ping; Shafer, Jenifer C. Experimental and Theoretical Approaches to Actinide Chemistry https://doi.org/10.1002/9781119115557.ch5	book	January 2018
Bonding Changes in Plutonium(III) and Americium(III) Borates Polinski, Matthew J.; Wang, Shuao; Alekseev, Evgeny V. Angewandte Chemie International Edition, Vol. 50, Issue 38 https://doi.org/10.1002/anie.201103502	journal	August 2011
Curium(III) Borate Shows Coordination Environments of Both Plutonium(III) and Americium(III) Borates Polinski, Matthew J.; Wang, Shuao; Alekseev, Evgeny V. Angewandte Chemie International Edition, Vol. 51, Issue 8 https://doi.org/10.1002/anie.201107956	journal	January 2012
Comparing the 2,2′-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium Cross, Justin N.; Macor, Joseph A.; Bertke, Jeffery A. Angewandte Chemie International Edition, Vol. 55, Issue 41 https://doi.org/10.1002/anie.201606367	journal	September 2016
Oxidative degradation of bis(2,4,4-trimethylpentyl)dithiophosphinic acid in nitric acid studied by electrospray ionization mass spectrometry: ESI studies of oxidative coupling of a dialkyldithiophosphinic acid Groenewold, Gary S.; Peterman, Dean R.; Klaehn, John R. Rapid Communications in Mass Spectrometry, Vol. 26, Issue 19 https://doi.org/10.1002/rcm.6339	journal	August 2012
Synergic extraction of dioxouranium(VI) with di (2-ethylhexyl) dithiophosphoric acid and triphenylphosphine oxide in benzene Curtui, M.; Haiduc, I. Journal of Radioanalytical and Nuclear Chemistry Letters, Vol. 176, Issue 3 https://doi.org/10.1007/BF02163674	journal	September 1993
Influence of the purity and irradiation stability of Cyanex 301 on the separation of trivalent actinides from lanthanides by solvent extraction Modolo, G.; Odoj, R. Journal of Radioanalytical and Nuclear Chemistry, Vol. 228, Issue 1-2 https://doi.org/10.1007/BF02387304	journal	February 1998
Extraction of Am(III) and Eu(III) with dialkyldi (or mono) thiophosphinic (or phosphoric) acids Xu, Qichu; Wu, Jianfeng; Zhang, Lixing Journal of Radioanalytical and Nuclear Chemistry, Vol. 273, Issue 1 https://doi.org/10.1007/s10967-007-0742-8	journal	June 2007
Tremendous impact of substituent group on the extraction and selectivity to Am(III) over Eu(III) by diaryldithiophosphinic acids: experimental and DFT analysis Pu, Ning; Xu, Lei; Sun, Taoxiang Journal of Radioanalytical and Nuclear Chemistry, Vol. 320, Issue 1 https://doi.org/10.1007/s10967-019-06445-5	journal	February 2019
Glassy Wasteforms for Nuclear Waste Immobilization Ojovan, Michael I.; Lee, William E. Metallurgical and Materials Transactions A, Vol. 42, Issue 4 https://doi.org/10.1007/s11661-010-0525-7	journal	November 2010
ansa-Metallocenderivate des Samariums und Ytterbiums mit ‘weichen’ Donorliganden Edelmann, Frank T.; Rieckhoff, Melanie; Haiduc, Ionel Journal of Organometallic Chemistry, Vol. 447, Issue 2 https://doi.org/10.1016/0022-328X(93)80239-8	journal	April 1993
Ein alter Ligand in neuer Umgebung: Dreifach verbrückendes O,Ó- Dimethyldithiophosphat im Organosamarium-Komplex [(C5Me5)Sm{S2P(OMe)2}2]2 Rieckhoff, Melanie; Noltemeyer, Mathias; Edelmann, Frank T. Journal of Organometallic Chemistry, Vol. 469, Issue 1 https://doi.org/10.1016/0022-328X(94)80092-8	journal	April 1994
Extraction des lanthanides et actinides trivalents par l'acide Di-2-ethylhexyldithiophosphorique: Structure des complexes organiques Pattee, D.; Musikas, C.; Faure, A. Journal of the Less Common Metals, Vol. 122 https://doi.org/10.1016/0022-5088(86)90423-6	journal	August 1986
Disulphides of dithiophosphinic acids as analytical reagents—I Extractive spectrophotometric determination of palladium with some bis(dialkylthiophosphoryl)- and bis(diarylthiophosphoryl)disulphides Shishkov, A. Talanta, Vol. 25, Issue 9 https://doi.org/10.1016/0039-9140(78)80092-7	journal	September 1978
Solvent extraction characteristics of thiosubstituted organophosphinic acid extractants Sole, Kathryn C.; Hiskey, J. Brent Hydrometallurgy, Vol. 30, Issue 1-3 https://doi.org/10.1016/0304-386X(92)90093-F	journal	June 1992
Actinide complexes with chelating ligands containing sulfur and amidic nitrogen donor atoms Casellato, U.; Vidali, M.; Vigato, P. A. Coordination Chemistry Reviews, Vol. 28, Issue 2-3 https://doi.org/10.1016/S0010-8545(00)82015-9	journal	June 1979
Reactions of bis(thiophosphoryl)disulfanes and bis(thiophosphinyl)disulfanes with metal species: an alternative, convenient route to metal complex and organometallic dithiophosphates and dithiophosphinates Haiduc, I. Coordination Chemistry Reviews, Vol. 224, Issue 1-2 https://doi.org/10.1016/S0010-8545(01)00402-7	journal	January 2002
The preparation and crystal structures of [Ln(S2PEt2)4] [Ph4As] (Ln = La, Er) Pinkerton, A. Alan; Schwarzenbach, Dieter; Spiliadis, Stavros Inorganica Chimica Acta, Vol. 128, Issue 2 https://doi.org/10.1016/S0020-1693(00)86559-7	journal	April 1987
Simultaneous solvent extraction of cobalt and nickel in the presence of manganese and magnesium from sulfate solutions by Cyanex 301 Tsakiridis, P. E.; Agatzini, S. L. Hydrometallurgy, Vol. 72, Issue 3-4 https://doi.org/10.1016/S0304-386X(03)00180-4	journal	March 2004
Characterization of extraction complexes of Am(III) with dialkyldithiophosphinic acids by extended X-ray absorption fine structure spectroscopy Tian, Guoxin; Zhu, Yongjun; Xu, Jingming Journal of Alloys and Compounds, Vol. 334, Issue 1-2 https://doi.org/10.1016/S0925-8388(01)01783-2	journal	February 2002
Trivalent minor actinides/lanthanides separation, using organophosphinic acids Hill, C.; Madic, C.; Baron, P. Journal of Alloys and Compounds, Vol. 271-273 https://doi.org/10.1016/S0925-8388(98)00045-0	journal	June 1998
The separation of trivalent actinides from lanthanides by dithiophosphinic acids from HNO3 acid medium Modolo, Giuseppe; Odoj, Reinhard Journal of Alloys and Compounds, Vol. 271-273 https://doi.org/10.1016/S0925-8388(98)00064-4	journal	June 1998
Separation of actinides and fission products in high-level liquid wastes by the improved TRUEX process Ozawa, Masaki; Koma, Yoshikazu; Nomura, Kazunori Journal of Alloys and Compounds, Vol. 271-273 https://doi.org/10.1016/S0925-8388(98)00147-9	journal	June 1998
Complexation thermodynamics and structural aspects of actinide–aminopolycarboxylates Choppin, G.; Thakur, P.; Mathur, J. Coordination Chemistry Reviews, Vol. 250, Issue 7-8 https://doi.org/10.1016/j.ccr.2006.02.003	journal	April 2006
Covalency in f-element complexes Neidig, Michael L.; Clark, David L.; Martin, Richard L. Coordination Chemistry Reviews, Vol. 257, Issue 2 https://doi.org/10.1016/j.ccr.2012.04.029	journal	January 2013
Design, synthesis and evaluation of carbamoylmethylphosphine sulfide (CMPS)-based chelates for separation of lanthanides and actinides Matloka, Kornelia; Sah, Ajay K.; Srinivasan, Priya Comptes Rendus Chimie, Vol. 10, Issue 10-11 https://doi.org/10.1016/j.crci.2007.02.006	journal	October 2007
Synthesis of symmetric dithiophosphinic acids for “minor actinide” extraction Klaehn, John R.; Peterman, Dean R.; Harrup, Mason K. Inorganica Chimica Acta, Vol. 361, Issue 8 https://doi.org/10.1016/j.ica.2008.01.007	journal	June 2008
Degradation of organothiophosphorous extractant Cyanex 301 Wieszczycka, Karolina; Tomczyk, Wiktoria Journal of Hazardous Materials, Vol. 192, Issue 2 https://doi.org/10.1016/j.jhazmat.2011.05.045	journal	August 2011
Separation of Am(III) from Eu(III) by extraction based on in situ extractant formation of dithiocarbamate derivatives Miyashita, Sunao; Satoh, Isamu; Yanaga, Makoto Progress in Nuclear Energy, Vol. 50, Issue 2-6 https://doi.org/10.1016/j.pnucene.2007.11.035	journal	March 2008
Copper and uranyl extraction from aqueous solutions using bis-dithiophosphinate ligands have been characterized DeVore, Michael A.; Gorden, Anne E. V. Polyhedron, Vol. 42, Issue 1 https://doi.org/10.1016/j.poly.2012.05.026	journal	July 2012
Coordination of P(X)-modified (X=O, S) N-aryl-carbamoylmethylphosphine oxides and sulfides with Pd(II) and Re(I) ions: Facile formation of 6,6-membered pincer complexes featuring atropisomerism Aleksenko, V. Yu.; Sharova, E. V.; Artyushin, O. I. Polyhedron, Vol. 51 https://doi.org/10.1016/j.poly.2012.12.025	journal	March 2013
The coordination chemistry of trivalent lanthanides (Ce, Nd, Sm, Eu, Gd, Dy, Yb) with diphenyldithiophosphinate anions Boland, Kevin S.; Hobart, David E.; Kozimor, Stosh A. Polyhedron, Vol. 67 https://doi.org/10.1016/j.poly.2013.09.019	journal	January 2014
Determination of pKa for dithiophosphinic acids using density functional theory Benson, Michael T.; Moser, Megan L.; Peterman, Dean R. Journal of Molecular Structure: THEOCHEM, Vol. 867, Issue 1-3 https://doi.org/10.1016/j.theochem.2008.07.020	journal	October 2008
Behavior of Dialkyl Phosphorodithioic Acids in Liquid Extraction Systems. Zucal, R. H.; Dean, J. A.; Handley, T. H. Analytical Chemistry, Vol. 35, Issue 8 https://doi.org/10.1021/ac60201a021	journal	July 1963
Bonding Study on the Chemical Separation of Am(III) from Eu(III) by S-, N-, and O-Donor Ligands by Means of All-Electron ZORA-DFT Calculation Kaneko, Masashi; Miyashita, Sunao; Nakashima, Satoru Inorganic Chemistry, Vol. 54, Issue 14 https://doi.org/10.1021/acs.inorgchem.5b01204	journal	July 2015
Interactions of Bis(2,4,4-trimethylpentyl)dithiophosphinate with Trivalent Lanthanides in a Homogeneous Medium: Thermodynamics and Coordination Modes Xu, Chao; Sun, Taoxiang; Rao, Linfeng Inorganic Chemistry, Vol. 56, Issue 5 https://doi.org/10.1021/acs.inorgchem.6b02744	journal	February 2017
Uncovering Heavy Actinide Covalency: Implications for Minor Actinide Partitioning Chandrasekar, Aditi; Ghanty, Tapan K. Inorganic Chemistry, Vol. 58, Issue 6 https://doi.org/10.1021/acs.inorgchem.8b03358	journal	February 2019
Quantum Chemistry Study on the Extraction of Trivalent Lanthanide Series by Cyanex301: Insights from Formation of Inner- and Outer-Sphere Complexes Sun, Taoxiang; Xu, Chao; Xie, Xiaofeng ACS Omega, Vol. 3, Issue 4 https://doi.org/10.1021/acsomega.8b00359	journal	April 2018
Investigation of the Extraction Complexes of Light Lanthanides(III) with Bis(2,4,4-trimethylpentyl)dithiophosphinic Acid by EXAFS, IR, and MS in Comparison with the Americium(III) Complex Guoxin, Tian; Yongjun, Zhu; Jingming, Xu Inorganic Chemistry, Vol. 42, Issue 3 https://doi.org/10.1021/ic025783z	journal	February 2003
Selective Americium(III) Complexation by Dithiophosphinates: A Density Functional Theoretical Validation for Covalent Interactions Responsible for Unusual Separation Behavior from Trivalent Lanthanides Bhattacharyya, Arunasis; Ghanty, Tapan Kumar; Mohapatra, Prasanta Kumar Inorganic Chemistry, Vol. 50, Issue 9 https://doi.org/10.1021/ic102238c	journal	May 2011
Theoretical Examination of the Thermodynamic Factors in the Selective Extraction of Am ³⁺ from Eu ³⁺ by Dithiophosphinic Acids Keith, Jason M.; Batista, Enrique R. Inorganic Chemistry, Vol. 51, Issue 1 https://doi.org/10.1021/ic202061b	journal	December 2011
Does Covalency Increase or Decrease across the Actinide Series? Implications for Minor Actinide Partitioning Kaltsoyannis, Nikolas Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic3006025	journal	June 2012
Infrared Spectra of H ₂ ThS and H ₂ US in Noble Gas Matrixes: Enhanced H-An-S Covalent Bonding Wang, Xuefeng; Andrews, Lester; Thanthiriwatte, K. Sahan Inorganic Chemistry, Vol. 52, Issue 18 https://doi.org/10.1021/ic400560k	journal	September 2013
Oxy and thio phosphorus acid derivatives of tin. 1. Triorganotin(IV) dithiophosphate esters Lefferts, J. L.; Molloy, K. C.; Zuckerman, J. J. Inorganic Chemistry, Vol. 19, Issue 6 https://doi.org/10.1021/ic50208a046	journal	June 1980
Experimental and Theoretical Comparison of Actinide and Lanthanide Bonding in M[N(EPR ₂ ) ₂ ] ₃ Complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, i Pr, H) Gaunt, Andrew J.; Reilly, Sean D.; Enriquez, Alejandro E. Inorganic Chemistry, Vol. 47, Issue 1 https://doi.org/10.1021/ic701618a	journal	January 2008
Characterization of Actinide Bonding in Th(S ₂ PMe ₂ ) ₄ by Synchrotron X-ray Diffraction Iversen, Bo B.; Larsen, Finn K.; Pinkerton, Alan A. Inorganic Chemistry, Vol. 37, Issue 18 https://doi.org/10.1021/ic9715613	journal	September 1998
Degradation of CYANEX 301 in Contact with Nitric Acid Media Marc, Philippe; Custelcean, Radu; Groenewold, Gary S. Industrial & Engineering Chemistry Research, Vol. 51, Issue 40 https://doi.org/10.1021/ie300757r	journal	September 2012
Actinide Lanthanide Separation Process—ALSEP Gelis, Artem V.; Lumetta, Gregg J. Industrial & Engineering Chemistry Research, Vol. 53, Issue 4 https://doi.org/10.1021/ie403569e	journal	January 2014
Hard and Soft Acids and Bases Pearson, Ralph G. Journal of the American Chemical Society, Vol. 85, Issue 22 https://doi.org/10.1021/ja00905a001	journal	November 1963
The Separation of Americium and Curium from the Rare Earth Elements Street, Kenneth; Seaborg, Glenn T. Journal of the American Chemical Society, Vol. 72, Issue 6 https://doi.org/10.1021/ja01162a530	journal	June 1950
Aromatic Phosphinic Acids and Derivatives. I. Diphenylphosphinodithoic Acid and Its Derivatives Higgins, Wm. A.; Vogel, Paul W.; Craig, W. G. Journal of the American Chemical Society, Vol. 77, Issue 7 https://doi.org/10.1021/ja01612a047	journal	April 1955
Comparison of Covalency in the Complexes of Trivalent Actinide and Lanthanide Cations Jensen, Mark P.; Bond, Andrew H. Journal of the American Chemical Society, Vol. 124, Issue 33 https://doi.org/10.1021/ja0178620	journal	August 2002
U(SMes) _n , ( n = 3, 4) and Ln(SMes) ₃ (Ln = La, Ce, Pr, Nd): Lanthanide(III)/Actinide(III) Differentiation in Agostic Interactions and an Unprecedented η ³ Ligation Mode of the Arylthiolate Ligand, from X-ray Diffraction and DFT Analysis Roger, Mathieu; Barros, Noémi; Arliguie, Thérèse Journal of the American Chemical Society, Vol. 128, Issue 27 https://doi.org/10.1021/ja0584830	journal	July 2006
Sulfur K-edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory of Dithiophosphinate Extractants: Minor Actinide Selectivity and Electronic Structure Correlations Daly, Scott R.; Keith, Jason M.; Batista, Enrique R. Journal of the American Chemical Society, Vol. 134, Issue 35 https://doi.org/10.1021/ja303999q	journal	August 2012
On the Origin of Covalent Bonding in Heavy Actinides Kelley, Morgan P.; Su, Jing; Urban, Matthew Journal of the American Chemical Society, Vol. 139, Issue 29 https://doi.org/10.1021/jacs.7b03251	journal	July 2017
Single but Stronger UO, Double but Weaker UNMe Bonds: The Tale Told by Cp ₂ UO and Cp ₂ UNR Barros, Noémi; Maynau, Daniel; Maron, Laurent Organometallics, Vol. 26, Issue 20 https://doi.org/10.1021/om700628e	journal	September 2007
Unusual structure, bonding and properties in a californium borate Polinski, Matthew J.; Garner, Edward B.; Maurice, Rémi Nature Chemistry, Vol. 6, Issue 5 https://doi.org/10.1038/nchem.1896	journal	March 2014
Emergence of californium as the second transitional element in the actinide series Cary, Samantha K.; Vasiliu, Monica; Baumbach, Ryan E. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7827	journal	April 2015
Characterization of the extracted complexes of trivalent lanthanides with purified cyanex 301 in comparison with trivalent actinide complexes He, Xihong; Tian, Guoxin; Chen, Jing Dalton Trans., Vol. 43, Issue 46 https://doi.org/10.1039/C4DT02553A	journal	January 2014
Formation of W/O microemulsions in the extraction of Nd( iii ) by bis(2,4,4-trimethylpentyl)dithiophosphinic acid and its effects on Nd( iii ) coordination Sun, Taoxiang; Xu, Chao; Chen, Jing Dalton Transactions, Vol. 45, Issue 3 https://doi.org/10.1039/C5DT03964A	journal	January 2016
Revisiting complexation thermodynamics of transplutonium elements up to einsteinium Kelley, Morgan P.; Bessen, Nathan P.; Su, Jing Chemical Communications, Vol. 54, Issue 75 https://doi.org/10.1039/C8CC05230A	journal	January 2018
A series of dithiocarbamates for americium, curium, and californium Cary, Samantha K.; Su, Jing; Galley, Shane S. Dalton Transactions, Vol. 47, Issue 41 https://doi.org/10.1039/C8DT02658K	journal	January 2018
Mechanism of trivalent actinide/lanthanide separation using synergistic mixtures of di(chlorophenyl)dithiophosphinic acid and neutral O-bearing co-extractants Ionova, Galina; Ionov, Sergei; Rabbe, Catherine New Journal of Chemistry, Vol. 25, Issue 3 https://doi.org/10.1039/b006745h	journal	January 2001
Solution Phase Coordination Chemistry of Trivalent Lanthanide and Actinide Cations with Bis(2,4,4-trimethylpentyl)dithiophosphinic Acid Jensen, Mark P.; Bond, Andrew H.; Rickert, Paul G. Journal of Nuclear Science and Technology, Vol. 39, Issue sup3 https://doi.org/10.1080/00223131.2002.10875456	journal	November 2002
Selective Extraction of Minor Actinides from Acidic Media Using Symmetric and Asymmetric Dithiophosphinic Acids Peterman, D. R.; Greenhalgh, M. R.; Tillotson, R. D. Separation Science and Technology, Vol. 45, Issue 12-13 https://doi.org/10.1080/01496395.2010.493787	journal	July 2010
Studies of the Synergistic Effect Choppin, G. R. Separation Science and Technology, Vol. 16, Issue 9 https://doi.org/10.1080/01496398108057602	journal	October 1981
Separations Chemistry for Actinide Elements: Recent Developments and Historical Perspective Nash, Kenneth L.; Choppin, Gregory R. Separation Science and Technology, Vol. 32, Issue 1-4 https://doi.org/10.1080/01496399708003198	journal	January 1997
Synergistic Selective Extraction of Actinides(Iii) over Lanthanides from Nitric acid Using new Aromatic Diorganyldithiophosphinic Acids and Neutral Organophosphorus Compounds Modolo, Giuseppe; Odoj, Reinhard Solvent Extraction and Ion Exchange, Vol. 17, Issue 1 https://doi.org/10.1080/07360299908934599	journal	January 1999
Separation of Americium(III) and Europium(III) from Nitrate Medium Using a Binary Mixture of Cyanex‐301 with N‐donor Ligands Bhattacharyya, A.; Mohapatra,, P. K.; Manchanda, V. K. Solvent Extraction and Ion Exchange, Vol. 24, Issue 1 https://doi.org/10.1080/07366290500388459	journal	March 2006
Metal Extraction by Sulfur‐Containing Symmetrically‐Substituted Bisphosphonic Acids. Part I. P,P′‐di(2‐ethylhexyl) Methylenebisthio‐Phosphonic Acid Zalupski, P. R.; Chiarizia, R.; Jensen, M. P. Solvent Extraction and Ion Exchange, Vol. 24, Issue 3 https://doi.org/10.1080/07366290600646988	journal	July 2006
Investigation of the State of Bis(2,4,4‐Trimethylpentyl)dithiophosphinic Acid in Nonane and Toluene Solutions Grigorieva, N. A.; Pavlenko, N. I.; Pleshkov, M. A. Solvent Extraction and Ion Exchange, Vol. 27, Issue 5-6 https://doi.org/10.1080/07366290903113983	journal	December 2009
Diphasic Acido-Basic Properties of Organophosphorus Acids. Sella, C.; Bauer, D. Solvent Extraction and Ion Exchange, Vol. 6, Issue 5 https://doi.org/10.1080/07366298808917967	journal	January 1988
Thermodynamic Considerations of Covalency in Trivalent Actinide-(poly)aminopolycarboxylate Interactions Drader, Jessica A.; Luckey, Morgan; Braley, Jenifer C. Solvent Extraction and Ion Exchange, Vol. 34, Issue 2 https://doi.org/10.1080/07366299.2016.1140436	journal	January 2016
Formation of W/O Microemulsions in the Extraction of the Lanthanide Series by Purified Cyanex 301 Sun, Taoxiang; Xu, Chao; Chen, Jing Solvent Extraction and Ion Exchange, Vol. 35, Issue 3 https://doi.org/10.1080/07366299.2017.1326729	journal	April 2017
An Assessment of the Long-Term Stabilities of Cyanex302 and Cyanex301 in Sulfuric and Nitric Acids Sole, Kathryn C.; Brent Hiskey, J.; Ferguson, Tonya L. Solvent Extraction and Ion Exchange, Vol. 11, Issue 5 https://doi.org/10.1080/07366299308918186	journal	October 1993
Extraction of Am(III) and Eu(III) from Nitrate Solution with Purified Cyanex 301 Zhu, Yongjun; Chen, Jing; Jiao, Rongzhou Solvent Extraction and Ion Exchange, Vol. 14, Issue 1 https://doi.org/10.1080/07366299608918326	journal	January 1996
Extraction of Americium and Fission Product Lanthanides with Cyanex 272 and Cyanex 301 Zhu, Yongjun; Chen, Jianfeng; Choppin, Gregory R. Solvent Extraction and Ion Exchange, Vol. 14, Issue 4 https://doi.org/10.1080/07366299608918355	journal	July 1996
A Study on the Radiolytic Stability of Commercial and Purified Cyanex 301 Chen, Jing; Jiao, Rongzhou; Zhu, Yongjun Solvent Extraction and Ion Exchange, Vol. 14, Issue 4 https://doi.org/10.1080/07366299608918356	journal	July 1996
Separation of Americium(III) from Europium(III) by Extraction Based on in situ Formation of Dioctylammonium Dioctyldithiocarbamate Extractant Miyashita, Sunao; Yanaga, Makoto; Satoh, Isamu Journal of Nuclear Science and Technology, Vol. 44, Issue 2 https://doi.org/10.1080/18811248.2007.9711277	journal	February 2007
Mechanism of Trivalent Actinide/Lanthanide Separation Using Bis(2,4,4-Trimethylpentyl) Dithiophosphinic acid (Cyanex 301) and Neutral O-Bearing Co-Extractant Synergistic Mixtures Ionova, G.; Ionov, S.; Rabbe, C. Solvent Extraction and Ion Exchange, Vol. 19, Issue 3 https://doi.org/10.1081/SEI-100103277	journal	May 2001
Investigation of the Aggregation of the Neodymium Complexes of Dialkylphosphoric, -Oxothiophosphinic, and -Dithiophosphinic Acids in Toluene Jensen, M. P.; Chiarizia, R.; Urban, V. Solvent Extraction and Ion Exchange, Vol. 19, Issue 5 https://doi.org/10.1081/SEI-100107027	journal	October 2001
EXTRACTION OF Am(III) AND Ln(III) BY DIALKYLDITHIOPHOSPHINIC ACID WITH DIFFERENT ALKYL GROUPS Guoxin, Tian; Yongjun, Zhu; Jingming, Xu Solvent Extraction and Ion Exchange, Vol. 19, Issue 6 https://doi.org/10.1081/SEI-100107615	journal	January 2001
Hydrolysis and Radiation Stability of the Alina Solvent for Actinide(Iii)/Lanthanide(Iii) Separation During the Partitioning of Minor Actinides Modolo, Giuseppe; Seekamp, Stefan Solvent Extraction and Ion Exchange, Vol. 20, Issue 2 https://doi.org/10.1081/SEI-120003021	journal	April 2002
Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state Silver, M. A.; Cary, S. K.; Johnson, J. A. Science, Vol. 353, Issue 6302 https://doi.org/10.1126/science.aaf3762	journal	August 2016
Studies on the Cobalt(III) Complexes of Monothiophosphate Ion Hidaka, Jinsai; Fujita, Junnosuke; Shimura, Yoichi Bulletin of the Chemical Society of Japan, Vol. 32, Issue 12 https://doi.org/10.1246/bcsj.32.1317	journal	December 1959
Separation of Americium(III) from Europium(III) by Dioctylammonium Dioctyldithiocarbamate/Nitrobenzene Extraction Miyasita, Sunao; Yanaga, Makoto; Satoh, Isamu Chemistry Letters, Vol. 35, Issue 2 https://doi.org/10.1246/cl.2006.236	journal	February 2006
Roles of d- and f-orbital electrons in the complexation of Eu(III) and Am(III) ions with alkyldithiophosphinic acid and alkylphosphinic acid using scalar-relativistic DFT calculations Kaneko, Masashi; Watanabe, Masayuki; Miyashita, Sunao Journal of Nuclear and Radiochemical Sciences, Vol. 17, Issue 0 https://doi.org/10.14494/jnrs.17.9	journal	January 2017
Influence of aggregation on the extraction of trivalent lanthanide and actinide cations by purified Cyanex 272, Cyanex 301, and Cyanex 302 Jensen, M. P.; Bond, A. H. Radiochimica Acta, Vol. 90, Issue 4 https://doi.org/10.1524/ract.2002.90.4_2002.205	journal	January 2002
Extraction of Am(III) and lanthanides(III) with organo dithiophosphinic acids Xu, Qichu; Wu, Jianfeng; Chang, Yinzhong Radiochimica Acta, Vol. 96, Issue 12 https://doi.org/10.1524/ract.2008.1565	journal	January 2008
Solvent extraction of trivalent actinides with di(2-ethylhexyl) phosphoric acid Takayama, R.; Ooe, K.; Yahagi, W. Proceedings in Radiochemistry, Vol. 1, Issue 1 https://doi.org/10.1524/rcpr.2011.0029	journal	September 2011

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