Hydrogenation of Pyrolysis Oil from Loblolly Pine Residue

Journal Article · Tue Dec 31 23:00:00 EST 2019 · Paper and Biomaterials (PBM)

DOI:https://doi.org/10.12103/j.issn.2096-2355.2020.01.001· OSTI ID:1651298

Ragauskas, Arthur J. ^[1]; Mondal, Ajoy Kanti ^[2]; Qin, Chengrong ^[3]; Ni, Yonghao ^[4]; Huang, Fang ^[5]

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1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
2. Fujian Agriculture and Forestry Univ., Fuzhou (China); Bangladesh Council of Scientific and Industrial Research (Bangladesh)
3. Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, Nanning (China)
4. Fujian Agriculture and Forestry Univ., Fuzhou (China); Univ. of New Brunswick, Fredericton NB (Canada)
5. Fujian Agriculture and Forestry Univ., Fuzhou (China); Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, Nanning (China)

Loblolly pine residue prepared with and without zeolite ZSM-5 was pyrolyzed at 60°C and the pyrolysis oil was hydrogenated using formic acid as a hydrogen source, in the presence of a Ru/activated carbon catalyst. As indicated by the pyrolysis yield, addition of the zeolite ZSM-5 increased the yield of light oil but decreased the yield of heavy oil. The pyrolysis oils were analyzed by ¹³C, ³¹P, ¹⁹F, and heteronuclear single quantum coherence or heteronuclear single quantum correlation nuclear magnetic resonance (HSQC-NMR), demonstrating that the zeolite ZSM-5 can efficiently induce decarboxylation reactions and decrease the content of aliphatic hydroxyl groups in the heavy oil by 57%. After hydrogenation of the pyrolysis oil, the aromatic carbon content decreased by 78%, with a significant increase in the aliphatic carbon content.

• Research Organization: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
• Sponsoring Organization: USDOE; National Key Research and Development Program of China; Foundation of Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control
• DOE Contract Number: AC05-00OR22725; EE0003144
• OSTI ID: 1651298
• Journal Information: Paper and Biomaterials (PBM), Journal Name: Paper and Biomaterials (PBM) Journal Issue: 1 Vol. 5; ISSN 2096-2355
• Country of Publication: United States
• Language: English

Related Subjects

Loblolly pine residue
hydrogenation
pyrolysis oil
zeolite ZSM-5