High-pressure synthesis, crystal structure, and magnetic properties of the Shastry-Sutherland-lattice oxides BaLn2ZnO5 (Ln = Pr, Sm, Eu)

Ishii, Yuto; Chen, Jie; Yoshida, Hiroyuki K.; Oda, Migaku; Christianson, Andrew D.; Yamaura, Kazunari

doi:10.1016/j.jssc.2020.121489

High-pressure synthesis, crystal structure, and magnetic properties of the Shastry-Sutherland-lattice oxides BaLn₂ZnO₅ (Ln = Pr, Sm, Eu)

Journal Article · Fri Jun 05 00:00:00 EDT 2020 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2020.121489· OSTI ID:1649046

Ishii, Yuto ^[1]; Chen, Jie ^[2]; Yoshida, Hiroyuki K. ^[1]; Oda, Migaku ^[1]; ^[3]; Yamaura, Kazunari ^[2]

Hokkaido Univ., Sapporo (Japan)
National Institute for Materials Science, Tsukuba, Ibaraki (Japan). International Center for Materials Nanoarchitectonics (WPI-MANA); Hokkaido Univ., Sapporo (Japan)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division

BaPr₂ZnO₅, BaSm₂ZnO₅, and BaEu₂ZnO₅ – a series of 4f magnetic insulators comprising the Shastry-Sutherland lattice – were synthesized via a solid-state reaction under high-pressure and high-temperature conditions. The magnetic behaviors are well characterized by the localized 4f electrons of each Ln³⁺ (= Pr, Sm, Eu) under the influence of the crystal-electric field of the surrounding ions. The magnetic susceptibility and heat capacity measurements of BaPr₂ZnO₅ (Pr³⁺; 4f² ³H₄) indicate the splitting of the ground state J-multiplet due to the crystal-electric field. BaSm₂ZnO₅ (Sm³⁺; 4f⁵ ⁶H_5/2) is a strong Van Vleck paramagnet, while BaEu₂ZnO₅ is non-magnetic due to the ⁷F₀ ground state (Eu³⁺; 4f^{6 7}F₀). The series of new oxides enriches a group of the Shastry-Sutherland lattice materials and helps to develop a range of two-dimensional quantum materials.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: Japan Society for the Promotion of Science (JSPS); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1649046

Journal Information:: Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Vol. 289; ISSN 0022-4596

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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High-pressure synthesis, crystal structure, and magnetic properties of the Shastry-Sutherland-lattice oxides BaLn2ZnO5 (Ln = Pr, Sm, Eu)

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High-pressure synthesis, crystal structure, and magnetic properties of the Shastry-Sutherland-lattice oxides BaLn₂ZnO₅ (Ln = Pr, Sm, Eu)