High-Performance Titanium Oxynitride Thin Films for Electrocatalytic Water Oxidation

Mucha, Nikhil Reddy; Som, Jacob; Choi, Jonghyun; Shaji, Surabhi; Gupta, Ram K.; Meyer, Harry M.; Cramer, Corson L.; Elliott, Amy M.; Kumar, Dhananjay

doi:10.1021/acsaem.0c00988

High-Performance Titanium Oxynitride Thin Films for Electrocatalytic Water Oxidation

Journal Article · Tue Aug 04 00:00:00 EDT 2020 · ACS Applied Energy Materials

DOI:https://doi.org/10.1021/acsaem.0c00988· OSTI ID:1648935

Mucha, Nikhil Reddy ^[1]; Som, Jacob ^[1]; Choi, Jonghyun ^[2]; Shaji, Surabhi ^[1]; ^[2]; ^[3]; ^[4]; ^[4]; ^[1]

North Carolina A & T State Univ., Greensboro, NC (United States). Dept. of Mechanical Engineering
Pittsburg State Univ., Pittsburg, KS (United States). Dept. of Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Energy and Transportation Sciences Division

TiN_xO_y (TiNO) thin films with superior electrochemical properties have been synthesized in situ using a pulsed laser deposition method and a varied oxygen partial pressure from 5 to 25 mTorr. In this study, the electrochemical overpotential of these TiNO films for water oxidation was found to be as low as 290 mV at 10 mA/cm², which is among the lowest overpotential values reported. The Tafel slopes, indicative of a rate of increase of electrode potential with respect to current, for these films are determined to be in the range of 85–57 mV/decade. These results further demonstrate the superiority of TiNO thin film as electrocatalyst for water oxidation to generate fossil-free fuels. The improvement in the electrocatalytic behavior of the semiconducting TiNO thin films is explained based on an adjustment in the valence band maximum edge and an enhancement in the number of electrochemically active sites. Both effects are realized by the substitution of N by O, forming a TiNO lattice that is isostructural with the rock-salt TiN lattice. These findings appear to assume significant importance in light of water electrolysis to produce fuels for the development of environmentally friendly power sources.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1648935

Journal Information:: ACS Applied Energy Materials, Journal Name: ACS Applied Energy Materials Journal Issue: 9 Vol. 3; ISSN 2574-0962

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (78)

Electrochemical Impedance Spectroscopy Orazem, Mark E.; Tribollet, Bernard https://doi.org/10.1002/9781119363682	book	April 2017
Formation of Oxynitride as the Photocatalytic Enhancing Site in Nitrogen-Doped Titania Nanocatalysts: Comparison to a Commercial Nanopowder Chen, X.; Lou, Y. -B.; Samia, A. C. S. Advanced Functional Materials, Vol. 15, Issue 1 https://doi.org/10.1002/adfm.200400184	journal	January 2005
Metal Nitride/Graphene Nanohybrids: General Synthesis and Multifunctional Titanium Nitride/Graphene Electrocatalyst Wen, Zhenhai; Cui, Shumao; Pu, Haihui Advanced Materials, Vol. 23, Issue 45, p. 5445-5450 https://doi.org/10.1002/adma.201102772	journal	October 2011
Formation of Prussian-Blue-Analog Nanocages via a Direct Etching Method and their Conversion into Ni-Co-Mixed Oxide for Enhanced Oxygen Evolution Han, Lei; Yu, Xin-Yao; Lou, Xiong Wen David Advanced Materials, Vol. 28, Issue 23 https://doi.org/10.1002/adma.201506315	journal	March 2016
Trinary Layered Double Hydroxides as High-Performance Bifunctional Materials for Oxygen Electrocatalysis Qian, Li; Lu, Zhiyi; Xu, Tianhao Advanced Energy Materials, Vol. 5, Issue 13 https://doi.org/10.1002/aenm.201500245	journal	May 2015
Ultrathin Spinel-Structured Nanosheets Rich in Oxygen Deficiencies for Enhanced Electrocatalytic Water Oxidation Bao, Jian; Zhang, Xiaodong; Fan, Bo Angewandte Chemie International Edition, Vol. 54, Issue 25 https://doi.org/10.1002/anie.201502226	journal	May 2015
Amorphous Fe−Co−P−C Film on a Carbon Fiber Paper Support as an Efficient Electrocatalyst for the Oxygen Evolution Reaction Lian, Jun; Zhang, Fabao; Lu, ShuQiang ChemElectroChem, Vol. 6, Issue 15 https://doi.org/10.1002/celc.201900978	journal	May 2019
Flexible Molecular Precursors for Selective Decomposition to Nickel Sulfide or Nickel Phosphide for Water Splitting and Supercapacitance Ayom, Gwaza E.; Khan, Malik D.; Ingsel, Tenzin Chemistry – A European Journal, Vol. 26, Issue 12 https://doi.org/10.1002/chem.201904583	journal	February 2020
Electrochemical and thermal oxidation of TiN coatings studied by XPS Milo?v, I.; Strehblow, H. -H.; Navin?ek, B. Surface and Interface Analysis, Vol. 23, Issue 7-8 https://doi.org/10.1002/sia.740230713	journal	July 1995
Titanium Dioxide/Electrolyte Solution Interface: Electron Transfer Phenomena Fernández-Ibáñez, P.; de las Nieves, F. J.; Malato, S. Journal of Colloid and Interface Science, Vol. 227, Issue 2 https://doi.org/10.1006/jcis.2000.6917	journal	July 2000
Structural and dielectric properties of ion beam deposited titanium oxynitride thin films Jia, Liuwei; Lu, Huiping; Ran, Yujing Journal of Materials Science, Vol. 54, Issue 2 https://doi.org/10.1007/s10853-018-2923-y	journal	September 2018
Electrical and optical properties of titanium oxynitride thin films Mucha, Nikhil R.; Som, Jacob; Shaji, Surabhi Journal of Materials Science, Vol. 55, Issue 12 https://doi.org/10.1007/s10853-019-04278-x	journal	January 2020
Enhancement in corrosion resistance and vibration damping performance in titanium by titanium nitride coating Sarkar, Kaushik; Jaipan, Panupong; Choi, Jonghyun SN Applied Sciences, Vol. 2, Issue 5 https://doi.org/10.1007/s42452-020-2777-1	journal	April 2020
XPS study of the nitrides, oxides and oxynitrides of titanium Kuznetsov, M. V.; Zhuravlev, Ju. F.; Zhilyaev, V. A. Journal of Electron Spectroscopy and Related Phenomena, Vol. 58, Issue 1-2 https://doi.org/10.1016/0368-2048(92)80001-O	journal	March 1992
XPS analysis of adsorption of oxygen molecules on the surface of Ti and TiNx films in vacuum Kuznetsov, M. V.; Zhuravlev, Ju. F.; Gubanov, V. A. Journal of Electron Spectroscopy and Related Phenomena, Vol. 58, Issue 3 https://doi.org/10.1016/0368-2048(92)80016-2	journal	April 1992
Alkali- and hydrogen ion sensing properties of LPCVD silicon oxynitride thin films Shin, Paik-Kyun; Mikolajick, Thomas Thin Solid Films, Vol. 426, Issue 1-2 https://doi.org/10.1016/S0040-6090(03)00041-5	journal	February 2003
Structural, magnetic and magnetotransport properties of bi-epitaxial La0.7Sr0.3MnO3 (110) thin films integrated on Si (001) Punugupati, Sandhyarani; Kumar, Raj; Nori, Sudhakar Acta Materialia, Vol. 106 https://doi.org/10.1016/j.actamat.2015.12.054	journal	March 2016
Promoting electrocatalytic overall water splitting with nanohybrid of transition metal nitride-oxynitride Dutta, Soumen; Indra, Arindam; Feng, Yi Applied Catalysis B: Environmental, Vol. 241 https://doi.org/10.1016/j.apcatb.2018.09.061	journal	February 2019
Structured titanium oxynitride (TiO N ) nanotube arrays for a continuous electrocatalytic phenol-degradation process: Synthesis, characterization, mechanisms and the chemical reaction micro-kinetics Suhadolnik, Luka; Lašič Jurković, Damjan; Likozar, Blaž Applied Catalysis B: Environmental, Vol. 257 https://doi.org/10.1016/j.apcatb.2019.117894	journal	November 2019
Effect of ambient gas on structural and optical properties of titanium oxynitride films Rawal, Sushant K.; Chawla, Amit Kumar; Chawla, Vipin Applied Surface Science, Vol. 256, Issue 13 https://doi.org/10.1016/j.apsusc.2010.01.096	journal	April 2010
Fabrication, characterization, and mechanism of vertically aligned titanium nitride nanowires Faruque, Mainul K.; M-Darkwa, Kwadwo; Xu, Zhigang Applied Surface Science, Vol. 260 https://doi.org/10.1016/j.apsusc.2012.01.056	journal	November 2012
Analysis of nitrogen species in titanium oxynitride ALD films Sowińska, Małgorzata; Brizzi, Simone; Das, Chittaranjan Applied Surface Science, Vol. 381 https://doi.org/10.1016/j.apsusc.2016.02.096	journal	September 2016
Morphological data on soft ferromagnetic Fe90Ta10 thin films Shaji, Surabhi; Mucha, Nikhil R.; Fialkova, Svitlana Data in Brief, Vol. 27 https://doi.org/10.1016/j.dib.2019.104714	journal	December 2019
Nonlinear electrochemical impedance spectroscopy for solid oxide fuel cell cathode materials Wilson, J. R.; Schwartz, D. T.; Adler, S. B. Electrochimica Acta, Vol. 51, Issue 8-9, p. 1389-1402 https://doi.org/10.1016/j.electacta.2005.02.109	journal	January 2006
Electrochemical oxidation behavior of titanium nitride based electrocatalysts under PEM fuel cell conditions Avasarala, Bharat; Haldar, Pradeep Electrochimica Acta, Vol. 55, Issue 28 https://doi.org/10.1016/j.electacta.2010.08.035	journal	December 2010
A Carbon-Support-Free Titanium Oxynitride Catalyst for Proton Exchange Membrane Fuel Cell Cathodes Chisaka, Mitsuharu; Ando, Yuta; Yamamoto, Yusuke Electrochimica Acta, Vol. 214 https://doi.org/10.1016/j.electacta.2016.08.032	journal	October 2016
Preparation of new titanium oxy nitride based electro catalysts using an anhydrous sol-gel method for water electrolysis in acid medium Wang, Wanli; Savadogo, Oumarou; Ma, Zi-Feng International Journal of Hydrogen Energy, Vol. 37, Issue 9 https://doi.org/10.1016/j.ijhydene.2012.02.025	journal	May 2012
Effect of solvent for tailoring the nanomorphology of multinary CuCo2S4 for overall water splitting and energy storage Zequine, Camila; Bhoyate, Sanket; Wang, Fangzhou Journal of Alloys and Compounds, Vol. 784 https://doi.org/10.1016/j.jallcom.2019.01.012	journal	May 2019
Visible light induced electron transfer process over nitrogen doped TiO2 nanocrystals prepared by oxidation of titanium nitride Wu, Zhongbiao; Dong, Fan; Zhao, Weirong Journal of Hazardous Materials, Vol. 157, Issue 1 https://doi.org/10.1016/j.jhazmat.2007.12.079	journal	August 2008
Magnetic and electrical properties of Fe90Ta10 thin films Shaji, Surabhi; Mucha, Nikhil R.; Majumdar, A. K. Journal of Magnetism and Magnetic Materials, Vol. 489 https://doi.org/10.1016/j.jmmm.2019.165446	journal	November 2019
Corrosion Protective Conversion Coatings on Magnesium Disks Using a Hydrothermal Technique Gupta, R. K.; Mensah-Darkwa, K.; Kumar, D. Journal of Materials Science & Technology, Vol. 30, Issue 1 https://doi.org/10.1016/j.jmst.2013.07.012	journal	January 2014
Titanium oxynitride films for a bipolar plate of polymer electrolyte membrane fuel cell prepared by inductively coupled plasma assisted reactive sputtering Kim, S. Y.; Han, D. H.; Kim, J. N. Journal of Power Sources, Vol. 193, Issue 2 https://doi.org/10.1016/j.jpowsour.2009.03.076	journal	September 2009
Partial oxidation of TiN coating by hydrothermal treatment and ozone treatment to improve its osteoconductivity Shi, Xingling; Xu, Lingli; Le, Thi Bang Materials Science and Engineering: C, Vol. 59 https://doi.org/10.1016/j.msec.2015.10.024	journal	February 2016
Cobalt sulfide nanoparticles: Synthesis, water splitting and supercapacitance studies Akram, Rehana; Khan, Malik Dilshad; Zequine, Camila Materials Science in Semiconductor Processing, Vol. 109 https://doi.org/10.1016/j.mssp.2020.104925	journal	April 2020
Performance of titanium oxynitrides in the electrocatalytic oxygen evolution reaction Gebauer, C.; Fischer, P.; Wassner, M. Nano Energy, Vol. 29 https://doi.org/10.1016/j.nanoen.2016.05.034	journal	November 2016
Quantum interference effects in titanium nitride films at low temperatures Roy, Manosi; Mucha, Nikhil R.; Ponnam, Rahul G. Thin Solid Films, Vol. 681 https://doi.org/10.1016/j.tsf.2019.05.005	journal	July 2019
Room Temperature Growth of Epitaxial Titanium Nitride Films by Pulsed Laser Deposition Rasic, Daniel; Sachan, Ritesh; Chisholm, Matthew F. Crystal Growth & Design, Vol. 17, Issue 12 https://doi.org/10.1021/acs.cgd.7b01278	journal	October 2017
Challenges in Co-Alloyed Titanium Oxynitrides, a Promising Class of Photochemically Active Materials Brancho, James J.; Bartlett, Bart M. Chemistry of Materials, Vol. 27, Issue 21 https://doi.org/10.1021/acs.chemmater.5b02357	journal	October 2015
Energetics at the Surface of Photoelectrodes and Its Influence on the Photoelectrochemical Properties Thorne, James E.; Li, Song; Du, Chun The Journal of Physical Chemistry Letters, Vol. 6, Issue 20 https://doi.org/10.1021/acs.jpclett.5b01372	journal	September 2015
Catalysts and Reaction Pathways for the Electrochemical Reduction of Carbon Dioxide Kortlever, Ruud; Shen, Jing; Schouten, Klaas Jan P. The Journal of Physical Chemistry Letters, Vol. 6, Issue 20 https://doi.org/10.1021/acs.jpclett.5b01559	journal	September 2015
Physical and Chemical Defects in WO ₃ Thin Films and Their Impact on Photoelectrochemical Water Splitting Zhao, Y.; Balasubramanyam, S.; Sinha, R. ACS Applied Energy Materials, Vol. 1, Issue 11 https://doi.org/10.1021/acsaem.8b00849	journal	October 2018
Oxynitride Thin Films versus Particle-Based Photoanodes: A Comparative Study for Photoelectrochemical Solar Water Splitting Haydous, Fatima; Döbeli, Max; Si, Wenping ACS Applied Energy Materials, Vol. 2, Issue 1 https://doi.org/10.1021/acsaem.8b01811	journal	December 2018
Manganese Doping of MoSe ₂ Promotes Active Defect Sites for Hydrogen Evolution Kuraganti, Vasu; Jain, Akash; Bar-Ziv, Ronen ACS Applied Materials & Interfaces, Vol. 11, Issue 28 https://doi.org/10.1021/acsami.9b05670	journal	June 2019
Amorphous Molybdenum Sulfide Catalysts for Electrochemical Hydrogen Production: Insights into the Origin of their Catalytic Activity Benck, Jesse D.; Chen, Zhebo; Kuritzky, Leah Y. ACS Catalysis, Vol. 2, Issue 9, p. 1916-1923 https://doi.org/10.1021/cs300451q	journal	August 2012
Catalyzing the Hydrogen Evolution Reaction (HER) with Molybdenum Sulfide Nanomaterials Benck, Jesse D.; Hellstern, Thomas R.; Kibsgaard, Jakob ACS Catalysis, Vol. 4, Issue 11 https://doi.org/10.1021/cs500923c	journal	October 2014
Visible Light-Driven Pure Water Splitting by a Nature-Inspired Organic Semiconductor-Based System Martin, David James; Reardon, Philip James Thomas; Moniz, Savio J. A. Journal of the American Chemical Society, Vol. 136, Issue 36 https://doi.org/10.1021/ja506386e	journal	August 2014
Designed Formation of Co ₃ O ₄ /NiCo ₂ O ₄ Double-Shelled Nanocages with Enhanced Pseudocapacitive and Electrocatalytic Properties Hu, Han; Guan, Buyuan; Xia, Baoyu Journal of the American Chemical Society, Vol. 137, Issue 16 https://doi.org/10.1021/jacs.5b02465	journal	April 2015
Efficient Water Oxidation Using CoMnP Nanoparticles Li, Da; Baydoun, Habib; Verani, Cláudio N. Journal of the American Chemical Society, Vol. 138, Issue 12 https://doi.org/10.1021/jacs.6b01543	journal	March 2016
Photocatalytic Water Splitting: Recent Progress and Future Challenges Maeda, Kazuhiko; Domen, Kazunari The Journal of Physical Chemistry Letters, Vol. 1, Issue 18, p. 2655-2661 https://doi.org/10.1021/jz1007966	journal	September 2010
Electrochemical Photolysis of Water at a Semiconductor Electrode Fujishima, Akira; Honda, Kenichi Nature, Vol. 238, Issue 5358, p. 37-38 https://doi.org/10.1038/238037a0	journal	July 1972
Nickel–vanadium monolayer double hydroxide for efficient electrochemical water oxidation Fan, Ke; Chen, Hong; Ji, Yongfei Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11981	journal	June 2016
Functional links between stability and reactivity of strontium ruthenate single crystals during oxygen evolution Chang, Seo Hyoung; Danilovic, Nemanja; Chang, Kee-Chul Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5191	journal	June 2014
Exfoliation of layered double hydroxides for enhanced oxygen evolution catalysis Song, Fang; Hu, Xile Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5477	journal	July 2014
Reversible adapting layer produces robust single-crystal electrocatalyst for oxygen evolution Tung, Ching-Wei; Hsu, Ying-Ya; Shen, Yen-Ping Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9106	journal	August 2015
Noble metal-free hydrogen evolution catalysts for water splitting Zou, Xiaoxin; Zhang, Yu Chemical Society Reviews, Vol. 44, Issue 15 https://doi.org/10.1039/C4CS00448E	journal	January 2015
Facile synthesis and morphogenesis of superparamagnetic iron oxide nanoparticles for high-performance supercapacitor applications Mitchell, Elias; Gupta, Ram K.; Mensah-Darkwa, Kwadwo New J. Chem., Vol. 38, Issue 9 https://doi.org/10.1039/C4NJ00741G	journal	January 2014
A new approach to prepare highly active and stable black titania for visible light-assisted hydrogen production Sinhamahapatra, Apurba; Jeon, Jong-Pil; Yu, Jong-Sung Energy & Environmental Science, Vol. 8, Issue 12 https://doi.org/10.1039/C5EE02443A	journal	January 2015
Titanium oxynitride microspheres with the rock-salt structure for use as visible-light photocatalysts Yoo, Jung Bo; Yoo, Hyo Jin; Jung, Hyuk Joon Journal of Materials Chemistry A, Vol. 4, Issue 3 https://doi.org/10.1039/C5TA06758H	journal	January 2016
High-performance electrolytic oxygen evolution with a seamless armor core–shell FeCoNi oxynitride Di, Jun; Zhu, Huiyuan; Xia, Jiexiang Nanoscale, Vol. 11, Issue 15 https://doi.org/10.1039/C8NR10191D	journal	January 2019
Structural and magnetoresistance properties of La2/3Ca1/3MnO3 thin films on buffered silicon substrates Kumar, D.; Chattopadhyay, S.; Gilmore, Walter M. Applied Physics Letters, Vol. 78, Issue 8 https://doi.org/10.1063/1.1350603	journal	February 2001
Scaling exponent within the side-jump mechanism of Hall effect size-dependence in Ni nanocrystals Kumar, Dhananjay; Oh, Sang Ho; Pennycook, Stephen J. Applied Physics Letters, Vol. 93, Issue 13 https://doi.org/10.1063/1.2987517	journal	September 2008
The initial stages of the oxidation of titanium nitride Tompkins, Harland G. Journal of Applied Physics, Vol. 71, Issue 2 https://doi.org/10.1063/1.351324	journal	January 1992
Effect of substrate temperature on the microstructural properties of titanium nitride nanowires grown by pulsed laser deposition Gbordzoe, S.; Kotoka, R.; Craven, Eric Journal of Applied Physics, Vol. 116, Issue 6 https://doi.org/10.1063/1.4893298	journal	August 2014
Structure, electronic properties, and oxygen incorporation/diffusion characteristics of the Σ 5 TiN(310)[001] tilt grain boundary McKenna, Keith P. Journal of Applied Physics, Vol. 123, Issue 7 https://doi.org/10.1063/1.5016626	journal	February 2018
Magnetic and magnetocaloric properties of Fe ₂ Ta thin films Shaji, S.; Mucha, Nikhil. R.; Giri, P. AIP Advances, Vol. 10, Issue 2 https://doi.org/10.1063/1.5134796	journal	February 2020
Formation of thin superconducting films by the laser processing method Narayan, J.; Biunno, N.; Singh, R. Applied Physics Letters, Vol. 51, Issue 22 https://doi.org/10.1063/1.98489	journal	November 1987
Changing the physical and chemical properties of titanium oxynitrides TiN 1 − x O x by changing the composition Graciani, Jesús; Hamad, Said; Sanz, Javier Fdez. Physical Review B, Vol. 80, Issue 18 https://doi.org/10.1103/PhysRevB.80.184112	journal	November 2009
Single Crystalline Oxygen-free Titanium Nitride by XPS Jaeger, Dominik; Patscheider, Jörg Surface Science Spectra, Vol. 20, Issue 1 https://doi.org/10.1116/11.20121107	journal	December 2013
Combining theory and experiment in electrocatalysis: Insights into materials design Seh, Zhi Wei; Kibsgaard, Jakob; Dickens, Colin F. Science, Vol. 355, Issue 6321 https://doi.org/10.1126/science.aad4998	journal	January 2017
A highly active and stable IrO _x /SrIrO ₃ catalyst for the oxygen evolution reaction Seitz, Linsey C.; Dickens, Colin F.; Nishio, Kazunori Science, Vol. 353, Issue 6303 https://doi.org/10.1126/science.aaf5050	journal	September 2016
Band-Gap Narrowing of Titanium Dioxide by Nitrogen Doping Morikawa, Takeshi; Asahi, Ryoji; Ohwaki, Takeshi Japanese Journal of Applied Physics, Vol. 40, Issue Part 2, No. 6A https://doi.org/10.1143/JJAP.40.L561	journal	June 2001
Facile Synthesis of Bio-Templated Tubular Co ₃ O ₄ Microstructure and Its Electrochemical Performance in Aqueous Electrolytes Guragain, D.; Zequine, C.; Poudel, T. Journal of Nanoscience and Nanotechnology, Vol. 20, Issue 5 https://doi.org/10.1166/jnn.2020.17414	journal	May 2020
Influence of Gold Catalyst on the Growth of Titanium Nitride Nanowires Jaipan, Panupong; Nannuri, Chandra; Mucha, Nikhil Reddy Materials Focus, Vol. 7, Issue 5 https://doi.org/10.1166/mat.2018.1571	journal	October 2018
Z-scheme photocatalyst systems for water splitting under visible light irradiation Kudo, Akihiko MRS Bulletin, Vol. 36, Issue 1 https://doi.org/10.1557/mrs.2010.3	journal	January 2011
Oxynitride materials for solar water splitting Maeda, Kazuhiko; Domen, Kazunari MRS Bulletin, Vol. 36, Issue 1 https://doi.org/10.1557/mrs.2010.4	journal	January 2011
Fast and efficient molecular electrocatalysts for H ₂ production: Using hydrogenase enzymes as guides Yang, Jenny Y.; Bullock, R. Morris; DuBois, M. Rakowski MRS Bulletin, Vol. 36, Issue 1 https://doi.org/10.1557/mrs.2010.8	journal	January 2011
Metal oxide nanomaterials for solar hydrogen generation from photoelectrochemical water splitting Zhang, Jin Zhong MRS Bulletin, Vol. 36, Issue 1 https://doi.org/10.1557/mrs.2010.9	journal	January 2011
Water Oxidation Catalysts: The Quest for New Oxide-Based Materials Mavrokefalos, Christos; Patzke, Greta Inorganics, Vol. 7, Issue 3 https://doi.org/10.3390/inorganics7030029	journal	February 2019

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36 MATERIALS SCIENCE
electrocatalysis
electrochemical overpotential
oxygen evolution reaction
oxynitrides
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thin films
water splitting

High-Performance Titanium Oxynitride Thin Films for Electrocatalytic Water Oxidation

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