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Ion-pairing in polyoxometalate chemistry: impact of fully hydrated alkali metal cations on properties of the keggin [PW 12 O 40 ] 3− anion

Journal Article · · Dalton Transactions
DOI:https://doi.org/10.1039/D0DT02239J· OSTI ID:1644706
 [1];  [2];  [2];  [2];  [3]
  1. Cherry L. Emerson Center for Scientific Computation, Emory University, Atlanta, USA
  2. Department of Chemistry, Emory University, Atlanta, USA
  3. Cherry L. Emerson Center for Scientific Computation, Emory University, Atlanta, USA, Department of Chemistry
+ Show Author Affiliations

The [PW 12 O 40 ] 3− [M + (H 2 O) 16 ] 3 is a “hydrogen bonded” ion-pair complex for M = Li, Na and K, but is a “contact” ion-pair complex for M = Rb and Cs, intermolecular charge transfer from the solvated counter cations M + (H 2 O) 16 to the anion [PW 12 O 40 ] 3− .

Sponsoring Organization:
USDOE
Grant/Contract Number:
FG02-07ER15906
OSTI ID:
1644706
Alternate ID(s):
OSTI ID: 1800432
Journal Information:
Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 32 Vol. 49; ISSN 1477-9226; ISSN ICHBD9
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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