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Title: Function of a PETN‐Based Exploding Bridgewire Detonator Post Melt

Journal Article · · Propellants, Explosives, Pyrotechnics
 [1];  [1];  [2];  [2];  [2]
  1. High Explosives Science &, Technology
  2. Physical Chemistry &, Applied Spectroscopy Los Alamos National Laboratory Los Alamos NM 87545

Abstract Exploding bridgewire (EBW) detonators are used for a variety of purposes and subjected to a wide range of conditions during transport and use, however, few studies have been conducted on stability at high temperatures. Many EBW's contain pentaerythritol tetranitrate (PETN) as the initiating explosive, which has been shown to exhibit a relatively low melt at 141 °C, followed by an onset of decomposition of approximately 160 °C. In the present work, we have evaluated the behavior of PETN with X‐ray radiography in commercial RP‐80 EBW detonators at temperatures just above the melt. These experiments show that PETN remains stable in the solid‐state, but after reaching the melt temperature is vulnerable to mixing, followed by rapid evolution of gases and decomposition. Our results indicate that the orientation of the thermally treated detonator with respect to gravity is important after the PETN reaches the melted state: this shows for the first time why thermal tests on PETN‐based detonators often result in varied outcomes.

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
89233218CNA000001
OSTI ID:
1643729
Alternate ID(s):
OSTI ID: 1726194; OSTI ID: 1786522
Report Number(s):
LA-UR-20-22596
Journal Information:
Propellants, Explosives, Pyrotechnics, Journal Name: Propellants, Explosives, Pyrotechnics Vol. 45 Journal Issue: 10; ISSN 0721-3115
Publisher:
WileyCopyright Statement
Country of Publication:
Germany
Language:
English
Citation Metrics:
Cited by: 4 works
Citation information provided by
Web of Science

References (13)

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Molten composition B-3 yield stress model
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conference January 2018
Thermochemistry of explosives journal February 1975
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