Effective Bipyridine and Pyrazine–Based Polysulfide Dissolution Resistant Complex Framework Material Systems for High Capacity Rechargeable Lithium–Sulfur Batteries

Shanthi, Pavithra M.; Hanumantha, Prashanth J.; Kuruba, Ramalinga; Gattu, Bharat; Datta, Moni K.; Kumta, Prashant N.

doi:10.1002/ente.201900141

Title: Effective Bipyridine and Pyrazine–Based Polysulfide Dissolution Resistant Complex Framework Material Systems for High Capacity Rechargeable Lithium–Sulfur Batteries

Journal Article · Thu Apr 11 00:00:00 EDT 2019 · Energy Technology

DOI:https://doi.org/10.1002/ente.201900141· OSTI ID:1640024

Shanthi, Pavithra M. ^[1]; Hanumantha, Prashanth J. ^[1]; Kuruba, Ramalinga ^[1]; Gattu, Bharat ^[1]; Datta, Moni K. ^[1];

^[1]

Univ. of Pittsburgh, PA (United States)

Lithium–sulfur (Li–S) batteries with high theoretical capacity (≈1650 mAh g^–1) and specific energy density (≈2567 Wh g^–1) have not achieved commercialization status due to low cycling stability arising from lithium polysulfide dissolution. Herein, sulfur infiltrated noncarbonized noncarbonate containing metal organic complex framework material (CFM) systems; sulfur–copper–bipyridine–CFM (S–Cu–bpy–CFM) and sulfur–copper–pyrazine–CFM (S–Cu–pyz–CFM) are developed as sulfur cathodes for the first time. The S–Cu–bpy–CFM and S–Cu–pyz–CFM show an initial capacity of 1626 and 1565 mAh g^–1 with stable capacities of 1063 and 1025 mAh g^–1, respectively, after 150 cycles. An X–ray photoelectron spectroscopy (XPS) analysis after sulfur infiltration reveals the presence of —C—S— bonds arising from the Lewis acid–base interaction of the CFMs with sulfur. The battery separators cycled with the CMF cathodes display complete absence of polysulfides after 150 cycles. These CFM cathodes exhibit an initial fade in capacity during the first ≈25 cycles attributed to the irreversible reaction of nitrogen with sulfur (—N—S—) during cycling. Furthermore, a clear understanding of this chemical interaction between sulfur and nitrogen present in the sulfur–infiltrated CFMs is essential for engineering nitrogen containing hosts for trapping polysulfides effectively. Understanding reported here will lead to new materials for achieving the high specific energy densities characteristic to Li–S batteries.

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Research Organization:: Univ. of Pittsburgh, PA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office. Batteries for Advanced Transportation Technologies (BATT) Program; USDOE

Grant/Contract Number:: EE0008199; EE0006825; EE0007797

OSTI ID:: 1640024

Alternate ID(s):: OSTI ID: 1513059

Journal Information:: Energy Technology, Vol. 7, Issue 12; ISSN 2194-4288

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 4 works

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References (121)

Contributions to screening in the solid state by electron systems of remote atoms: Effects to photoelectron and Auger transitions Wagner, C. D.; Taylor, J. A. Journal of Electron Spectroscopy and Related Phenomena, Vol. 28, Issue 2 https://doi.org/10.1016/0368-2048(82)85044-5	journal	January 1982
Infrared spectra of soluble polyaniline Tang, Jinsong; Jing, Xiabin; Wang, Baochen Synthetic Metals, Vol. 24, Issue 3 https://doi.org/10.1016/0379-6779(88)90261-5	journal	May 1988
Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium–Sulfur Battery Cathode Material with High Capacity and Cycling Stability Wang, Hailiang; Yang, Yuan; Liang, Yongye Nano Letters, Vol. 11, Issue 7, p. 2644-2647 https://doi.org/10.1021/nl200658a	journal	July 2011
Elaborately Designed Micro–Mesoporous Graphitic Carbon Spheres as Efficient Polysulfide Reservoir for Lithium–Sulfur Batteries Zheng, Jiahui; Guo, Guannan; Li, Hanwen ACS Energy Letters, Vol. 2, Issue 5 https://doi.org/10.1021/acsenergylett.7b00230	journal	April 2017
A two dimensional infrared correlation spectroscopic study on the structure changes of PVDF during the melting process Peng, Yun; Wu, Peiyi Polymer, Vol. 45, Issue 15 https://doi.org/10.1016/j.polymer.2004.05.034	journal	July 2004
Evaluation of FTIR Spectroscopy as a diagnostic tool for lung cancer using sputum Lewis, Paul D.; Lewis, Keir E.; Ghosal, Robin BMC Cancer, Vol. 10, Issue 1 https://doi.org/10.1186/1471-2407-10-640	journal	November 2010
Heterostructures for Improved Stability of Lithium Sulfur Batteries Hanumantha, Prashanth Jampani; Gattu, Bharat; Velikokhatnyi, Oleg Journal of The Electrochemical Society, Vol. 161, Issue 6 https://doi.org/10.1149/2.107406jes	journal	January 2014
Interwoven MXene Nanosheet/Carbon-Nanotube Composites as Li-S Cathode Hosts Liang, Xiao; Rangom, Yverick; Kwok, Chun Yuen Advanced Materials, Vol. 29, Issue 3 https://doi.org/10.1002/adma.201603040	journal	November 2016
FTIR study of adsorption and photoreactions of acetic acid on TiO2 Liao, Li-Fen; Lien, Chen-Fu; Lin, Jong-Liang Physical Chemistry Chemical Physics, Vol. 3, Issue 17 https://doi.org/10.1039/b103419g	journal	January 2001
A dual coaxial nanocable sulfur composite for high-rate lithium–sulfur batteries Li, Zhen; Yuan, Lixia; Yi, Ziqi Nanoscale, Vol. 6, Issue 3 https://doi.org/10.1039/C3NR04347A	journal	January 2014
Use of FTIR, FT-Raman and 13C-NMR spectroscopy for identification of some seaweed phycocolloids Pereira, Leonel; Sousa, Ana; Coelho, Helena Biomolecular Engineering, Vol. 20, Issue 4-6 https://doi.org/10.1016/S1389-0344(03)00058-3	journal	July 2003
Carbon–sulfur composites for Li–S batteries: status and prospects Wang, Da-Wei; Zeng, Qingcong; Zhou, Guangmin Journal of Materials Chemistry A, Vol. 1, Issue 33 https://doi.org/10.1039/c3ta11045a	journal	January 2013
Porous Metal-Organic Frameworks: Promising Materials for Methane Storage Li, Bin; Wen, Hui-Min; Zhou, Wei Chem, Vol. 1, Issue 4 https://doi.org/10.1016/j.chempr.2016.09.009	journal	October 2016
Sulfur Encapsulated in Graphitic Carbon Nanocages for High-Rate and Long-Cycle Lithium-Sulfur Batteries Zhang, Juan; Yang, Chun-Peng; Yin, Ya-Xia Advanced Materials, Vol. 28, Issue 43 https://doi.org/10.1002/adma.201602913	journal	September 2016
The mechanism of the desulfurization of benzenethiol by nickel (110) Huntley, D. R. The Journal of Physical Chemistry, Vol. 96, Issue 11 https://doi.org/10.1021/j100190a077	journal	May 1992
Embedding Sulfur in MOF-Derived Microporous Carbon Polyhedrons for Lithium-Sulfur Batteries Wu, Hao Bin; Wei, Shuya; Zhang, Lei Chemistry - A European Journal, Vol. 19, Issue 33 https://doi.org/10.1002/chem.201301689	journal	June 2013
Li-ion battery materials: present and future Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae Materials Today, Vol. 18, Issue 5 https://doi.org/10.1016/j.mattod.2014.10.040	journal	June 2015
Encapsulating Sulfur into Hierarchically Ordered Porous Carbon as a High-Performance Cathode for Lithium-Sulfur Batteries Ding, Bing; Yuan, Changzhou; Shen, Laifa Chemistry - A European Journal, Vol. 19, Issue 3 https://doi.org/10.1002/chem.201202127	journal	November 2012
A Metal–Organic Framework with Open Metal Sites for Enhanced Confinement of Sulfur and Lithium–Sulfur Battery of Long Cycling Life Wang, Ziqi; Li, Xiang; Cui, Yuanjing Crystal Growth & Design, Vol. 13, Issue 11 https://doi.org/10.1021/cg401304x	journal	October 2013
Analysis of oxyanion (BO 3 3? , CO 3 2? , SO 4 2? , PO 4 3? , SeO 4 4- ) substitution in Y123 compounds studied by X-ray photoelectron spectroscopy Kurmaev, E. Z.; Fedorenko, V. V.; Galakhov, V. R. Journal of Superconductivity, Vol. 9, Issue 1 https://doi.org/10.1007/BF00728433	journal	February 1996
The gap between long lifespan Li-S coin and pouch cells: The importance of lithium metal anode protection Cheng, Xin-Bing; Yan, Chong; Huang, Jia-Qi Energy Storage Materials, Vol. 6 https://doi.org/10.1016/j.ensm.2016.09.003	journal	January 2017
Tuning the Adsorption of Polysulfides in Lithium–Sulfur Batteries with Metal–Organic Frameworks Park, Haesun; Siegel, Donald J. Chemistry of Materials, Vol. 29, Issue 11 https://doi.org/10.1021/acs.chemmater.7b01166	journal	May 2017
A strategic approach to recharging lithium-sulphur batteries for long cycle life Su, Yu-Sheng; Fu, Yongzhu; Cochell, Thomas Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3985	journal	December 2013
Mesoporous carbon/sulfur composite with polyaniline coating for lithium sulfur batteries Jin, Jun; Wen, Zhaoyin; Ma, Guoqiang Solid State Ionics, Vol. 262 https://doi.org/10.1016/j.ssi.2013.09.060	journal	September 2014
X-ray photoelectron spectroscopy of merocyanine dyes Chehimi, Mohamed M.; Delamar, Michel Journal of Electron Spectroscopy and Related Phenomena, Vol. 49, Issue 2 https://doi.org/10.1016/0368-2048(89)85010-8	journal	January 1989
Highly dispersed sulfur in ordered mesoporous carbon sphere as a composite cathode for rechargeable polymer Li/S battery Liang, Xiao; Wen, Zhaoyin; Liu, Yu Journal of Power Sources, Vol. 196, Issue 7 https://doi.org/10.1016/j.jpowsour.2010.12.052	journal	April 2011
FTIR spectroscopy shows weak symmetric hydrogen bonding of the Q _B carbonyl groups in Rhodobacter sphaeroides R26 reaction centres Brudler, R.; de Groot, H. J. M.; van Liemt, W. B. S. FEBS Letters, Vol. 370, Issue 1-2 https://doi.org/10.1016/0014-5793(95)00805-J	journal	August 1995
Sulfur–mesoporous carbon composites in conjunction with a novel ionic liquid electrolyte for lithium rechargeable batteries Wang, J.; Chew, S. Y.; Zhao, Z. W. Carbon, Vol. 46, Issue 2, p. 229-235 https://doi.org/10.1016/j.carbon.2007.11.007	journal	February 2008
Lithium-sulfur cell with combining carbon nanofibers–sulfur cathode and gel polymer electrolyte Rao, Mumin; Geng, Xiuyu; Li, Xiaoping Journal of Power Sources, Vol. 212 https://doi.org/10.1016/j.jpowsour.2012.03.111	journal	August 2012
Tetrathiafulvalenium salts of planar Pt ^II , Pd ^II , and Cu ^II 1,2-dithio-oxalato-S,S′ anions. Synthesis, chemistry and molecular structures of bis(tetrathiafulvalenium) bis(1,2-dithio-oxalato-S,S′)palladate( II ), [ttf] ₂ [Pd(S ₂ C ₂ O ₂ ) ₂ ], and of bis(tetrathiafulvalenium)tetrathiafulvalene bis(1,2-dithio-oxalato-S,S′)platinate( II ), [ttf] ₃ [Pt(S ₂ C ₂ O ₂ ) ₂ ] Bellitto, Carlo; Bonamico, Mario; Fares, Vincenzo J. Chem. Soc., Dalton Trans., Issue 4 https://doi.org/10.1039/DT9890000719	journal	January 1989
Carbon Materials for Lithium Sulfur Batteries-Ten Critical Questions Borchardt, Lars; Oschatz, Martin; Kaskel, Stefan Chemistry - A European Journal, Vol. 22, Issue 22 https://doi.org/10.1002/chem.201600040	journal	March 2016
To mitigate self-discharge of lithium–sulfur batteries by optimizing ionic liquid electrolytes Wang, Lina; Liu, Jingyuan; Yuan, Shouyi Energy & Environmental Science, Vol. 9, Issue 1 https://doi.org/10.1039/C5EE02837J	journal	January 2016
Safer lithium metal battery based on advanced ionic liquid gel polymer nonflammable electrolytes Guo, Qingpeng; Han, Yu; Wang, Hui RSC Advances, Vol. 6, Issue 103 https://doi.org/10.1039/C6RA10394D	journal	January 2016
Ethylene sulfate as film formation additive to improve the compatibility of graphite electrode for lithium-ion battery Li, Xuecheng; Yin, Zhoulan; Li, Xinhai Ionics, Vol. 20, Issue 6 https://doi.org/10.1007/s11581-013-1036-5	journal	December 2013
Spherical Ordered Mesoporous Carbon Nanoparticles with High Porosity for Lithium-Sulfur Batteries Schuster, Jörg; He, Guang; Mandlmeier, Benjamin Angewandte Chemie International Edition, Vol. 51, Issue 15, p. 3591-3595 https://doi.org/10.1002/anie.201107817	journal	March 2012
High Sulfur Loading Cathodes Fabricated Using Peapodlike, Large Pore Volume Mesoporous Carbon for Lithium–Sulfur Battery Li, Duo; Han, Fei; Wang, Shuai ACS Applied Materials & Interfaces, Vol. 5, Issue 6 https://doi.org/10.1021/am4000535	journal	March 2013
Lewis Acid–Base Interactions between Polysulfides and Metal Organic Framework in Lithium Sulfur Batteries Zheng, Jianming; Tian, Jian; Wu, Dangxin Nano Letters, Vol. 14, Issue 5 https://doi.org/10.1021/nl404721h	journal	April 2014
Enhanced performance of lithium sulfur batteries with conductive polymer modified separators Ma, Guoqiang; Huang, Feifei; Wen, Zhaoyin Journal of Materials Chemistry A, Vol. 4, Issue 43 https://doi.org/10.1039/C6TA07198H	journal	January 2016
Microwave assisted hydrothermal synthesis of a novel CuI-sulfate-pyrazine MOF Amo-Ochoa, Pilar; Givaja, Gonzalo; Miguel, Pablo J. Sanz Inorganic Chemistry Communications, Vol. 10, Issue 8 https://doi.org/10.1016/j.inoche.2007.04.024	journal	August 2007
Hierarchically Structured Sulfur/Carbon Nanocomposite Material for High-Energy Lithium Battery Liang, Chengdu; Dudney, Nancy J.; Howe, Jane Y. Chemistry of Materials, Vol. 21, Issue 19, p. 4724-4730 https://doi.org/10.1021/cm902050j	journal	October 2009
Adsorption of Gases and Vapors on Nanoporous Ni ₂ (4,4‘-Bipyridine) ₃ (NO ₃ ) ₄ Metal−Organic Framework Materials Templated with Methanol and Ethanol: Structural Effects in Adsorption Kinetics Fletcher, Ashleigh J.; Cussen, Edmund J.; Bradshaw, Darren Journal of the American Chemical Society, Vol. 126, Issue 31 https://doi.org/10.1021/ja0490267	journal	August 2004
Lithium-sulfur batteries: Problems and solutions Kolosnitsyn, V. S.; Karaseva, E. V. Russian Journal of Electrochemistry, Vol. 44, Issue 5 https://doi.org/10.1134/S1023193508050029	journal	May 2008
Nanostructured sulfur cathodes Yang, Yuan; Zheng, Guangyuan; Cui, Yi Chemical Society Reviews, Vol. 42, Issue 7, p. 3018-3032 https://doi.org/10.1039/c2cs35256g	journal	January 2013
Long-life Li/polysulphide batteries with high sulphur loading enabled by lightweight three-dimensional nitrogen/sulphur-codoped graphene sponge Zhou, Guangmin; Paek, Eunsu; Hwang, Gyeong S. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8760	journal	July 2015
Lanthanum Nitrate As Electrolyte Additive To Stabilize the Surface Morphology of Lithium Anode for Lithium–Sulfur Battery Liu, Sheng; Li, Guo-Ran; Gao, Xue-Ping ACS Applied Materials & Interfaces, Vol. 8, Issue 12 https://doi.org/10.1021/acsami.5b12231	journal	March 2016
More Reliable Lithium-Sulfur Batteries: Status, Solutions and Prospects Fang, Ruopian; Zhao, Shiyong; Sun, Zhenhua Advanced Materials, Vol. 29, Issue 48 https://doi.org/10.1002/adma.201606823	journal	April 2017
Carbon dioxide capture and conversion by an acid-base resistant metal-organic framework Liang, Linfeng; Liu, Caiping; Jiang, Feilong Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01166-3	journal	November 2017
Porous Spherical Carbon/Sulfur Nanocomposites by Aerosol-Assisted Synthesis: The Effect of Pore Structure and Morphology on Their Electrochemical Performance As Lithium/Sulfur Battery Cathodes Sohn, Hiesang; Gordin, Mikhail L.; Xu, Terrence ACS Applied Materials & Interfaces, Vol. 6, Issue 10 https://doi.org/10.1021/am404508t	journal	May 2014
Novel Composite Polymer Electrolytes of PVdF-HFP Derived by Electrospinning with Enhanced Li-Ion Conductivities for Rechargeable Lithium–Sulfur Batteries M. Shanthi, Pavithra; J. Hanumantha, Prashanth; Albuquerque, Taciana ACS Applied Energy Materials, Vol. 1, Issue 2 https://doi.org/10.1021/acsaem.7b00094	journal	January 2018
High-performance supercapacitors and batteries derived from activated banana-peel with porous structures Zhang, Yunya; Gao, Zan; Song, Ningning Electrochimica Acta, Vol. 222 https://doi.org/10.1016/j.electacta.2016.11.099	journal	December 2016
FTIR characterization of PEO + LiN(CF3SO2)2 electrolytes Wen, S. J.; Richardson, T. J.; Ghantous, D. I. Journal of Electroanalytical Chemistry, Vol. 408, Issue 1-2 https://doi.org/10.1016/0022-0728(96)04536-6	journal	May 1996
Contribution to the Infrared Spectra of Organosulphur Compounds Rao, C. N. R.; Venkataraghavan, R.; Kasturi, T. R. Canadian Journal of Chemistry, Vol. 42, Issue 1 https://doi.org/10.1139/v64-006	journal	January 1964
Prospects for nanoporous metal-organic materials in advanced separations processes Snurr, Randall Q.; Hupp, Joseph T.; Nguyen, SonBinh T. AIChE Journal, Vol. 50, Issue 6, p. 1090-1095 https://doi.org/10.1002/aic.10101	journal	January 2004
High performance lithium sulfur batteries with a cassava-derived carbon sheet as a polysulfides inhibitor Qin, Furong; Zhang, Kai; Fang, Jing New J. Chem., Vol. 38, Issue 9 https://doi.org/10.1039/C4NJ00701H	journal	January 2014
Hysteretic Adsorption and Desorption of Hydrogen by Nanoporous Metal-Organic Frameworks Zhao, X. Science, Vol. 306, Issue 5698 https://doi.org/10.1126/science.1101982	journal	November 2004
An Advanced Lithium-Sulfur Battery Kim, Junghoon; Lee, Dong-Ju; Jung, Hun-Gi Advanced Functional Materials, Vol. 23, Issue 8 https://doi.org/10.1002/adfm.201200689	journal	May 2012
FTIR, TGA and DC electrical conductivity studies of phthalocyanine and its complexes Seoudi, R.; El-Bahy, G. S.; El Sayed, Z. A. Journal of Molecular Structure, Vol. 753, Issue 1-3 https://doi.org/10.1016/j.molstruc.2005.06.003	journal	October 2005
Electronic structure of sulphur-containing conducting polymers Riga, J.; Snauwaert, Ph; De Pryck, A. Synthetic Metals, Vol. 21, Issue 1-3 https://doi.org/10.1016/0379-6779(87)90090-7	journal	August 1987
Ionic liquid-enhanced solid state electrolyte interface (SEI) for lithium–sulfur batteries Zheng, Jianming; Gu, Meng; Chen, Honghao Journal of Materials Chemistry A, Vol. 1, Issue 29 https://doi.org/10.1039/c3ta11553d	journal	January 2013
Insight into lithium–metal anodes in lithium–sulfur batteries with a fluorinated ether electrolyte Zu, Chenxi; Azimi, Nasim; Zhang, Zhengcheng Journal of Materials Chemistry A, Vol. 3, Issue 28 https://doi.org/10.1039/C5TA03195H	journal	January 2015
An FTIR investigation of hexadecyltrimethylammonium intercalation into rectorite Li, Zhaohui; Jiang, Wei-Teh; Hong, Hanlie Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 71, Issue 4 https://doi.org/10.1016/j.saa.2008.05.015	journal	December 2008
The electrical conductivity of liquid sulphur Edeling, M.; Schmutzler, R. W.; Hensel, F. Philosophical Magazine B, Vol. 39, Issue 6 https://doi.org/10.1080/13642817908246005	journal	June 1979
Multiobjective Optimal Sizing of Hybrid Energy Storage System for Electric Vehicles Zhang, Lei; Hu, Xiaosong; Wang, Zhenpo IEEE Transactions on Vehicular Technology, Vol. 67, Issue 2 https://doi.org/10.1109/TVT.2017.2762368	journal	February 2018
π* ← π Shakeup Satellites for the Analysis of Structure and Bonding in Aromatic Polymers by X-Ray Photoelectron Spectroscopy Gardella, Joseph A.; Ferguson, Susan A.; Chin, Roland L. Applied Spectroscopy, Vol. 40, Issue 2 https://doi.org/10.1366/0003702864509565	journal	February 1986
Vinyl ethylene sulfite as a new additive in propylene carbonate-based electrolyte for lithium ion batteries Yao, Wanhao; Zhang, Zhongru; Gao, Jun Energy & Environmental Science, Vol. 2, Issue 10 https://doi.org/10.1039/b905162g	journal	January 2009
Infrared spectra of new sulfur-nitrogen species in solid argon Hassanzadeh, Parviz; Andrews, Lester Journal of the American Chemical Society, Vol. 114, Issue 1 https://doi.org/10.1021/ja00027a012	journal	January 1992
Highly reversible Li/dissolved polysulfide batteries with binder-free carbon nanofiber electrodes Zu, Chenxi; Fu, Yongzhu; Manthiram, Arumugam Journal of Materials Chemistry A, Vol. 1, Issue 35 https://doi.org/10.1039/c3ta11958k	journal	January 2013
Optimization of mesoporous carbon structures for lithium–sulfur battery applications Li, Xiaolin; Cao, Yuliang; Qi, Wen Journal of Materials Chemistry, Vol. 21, Issue 41 https://doi.org/10.1039/c1jm12979a	journal	January 2011
Suppressing Self-Discharge and Shuttle Effect of Lithium-Sulfur Batteries with V ₂ O ₅ -Decorated Carbon Nanofiber Interlayer Liu, Ming; Li, Qing; Qin, Xianying Small, Vol. 13, Issue 12 https://doi.org/10.1002/smll.201602539	journal	January 2017
Rheooptical Fourier transform infrared spectroscopy of the deformation behavior in quenched and slow-cooled isotactic polypropylene films Parthasarthy, Gautam; Sevegney, Michael; Kannan, Rangaramanujam M. Journal of Polymer Science Part B: Polymer Physics, Vol. 40, Issue 22 https://doi.org/10.1002/polb.10304	journal	October 2002
3D Carbonaceous Current Collectors: The Origin of Enhanced Cycling Stability for High-Sulfur-Loading Lithium-Sulfur Batteries Peng, Hong-Jie; Xu, Wen-Tao; Zhu, Lin Advanced Functional Materials, Vol. 26, Issue 35 https://doi.org/10.1002/adfm.201602071	journal	June 2016
An optimised method to determine the degree of acetylation of chitin and chitosan by FTIR spectroscopy Duarte, M. L.; Ferreira, M. C.; Marvão, M. R. International Journal of Biological Macromolecules, Vol. 31, Issue 1-3 https://doi.org/10.1016/S0141-8130(02)00039-9	journal	December 2002
A Long-Life, High-Rate Lithium/Sulfur Cell: A Multifaceted Approach to Enhancing Cell Performance Song, Min-Kyu; Zhang, Yuegang; Cairns, Elton J. Nano Letters, Vol. 13, Issue 12 https://doi.org/10.1021/nl402793z	journal	November 2013
X-ray photoelectron spectroscopic studies on some dithiolate complexes Lalitha, S.; Manoharan, P. T. Journal of Electron Spectroscopy and Related Phenomena, Vol. 49, Issue 1 https://doi.org/10.1016/0368-2048(89)80037-4	journal	January 1989
Sulfur embedded in metal organic framework-derived hierarchically porous carbon nanoplates for high performance lithium–sulfur battery Xu, Guiyin; Ding, Bing; Shen, Laifa Journal of Materials Chemistry A, Vol. 1, Issue 14 https://doi.org/10.1039/c3ta00004d	journal	January 2013
Carbon with hierarchical pores from carbonized metal–organic frameworks for lithium sulphur batteries Xi, Kai; Cao, Shuai; Peng, Xiaoyu Chemical Communications, Vol. 49, Issue 22 https://doi.org/10.1039/c3cc38009b	journal	January 2013
Designing high-energy lithium–sulfur batteries Seh, Zhi Wei; Sun, Yongming; Zhang, Qianfan Chemical Society Reviews, Vol. 45, Issue 20 https://doi.org/10.1039/C5CS00410A	journal	January 2016
A hierarchical micro/mesoporous carbon fiber/sulfur composite for high-performance lithium–sulfur batteries Gong, Zhijie; Wu, Qixing; Wang, Fang RSC Advances, Vol. 6, Issue 44 https://doi.org/10.1039/C6RA04146A	journal	January 2016
ESCA characterization of heparin-like fluoropolymers obtained by functionalization after grafting induced by swift heavy ion irradiation Dapoz, Sylvie; Betz, Natacha; Guittet, Marie-Jo Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 105, Issue 1-4 https://doi.org/10.1016/0168-583X(95)00823-3	journal	November 1995
Understanding the Origin of Irreversible Capacity loss in Non-Carbonized Carbonate − based Metal Organic Framework (MOF) Sulfur hosts for Lithium − Sulfur battery Shanthi, Pavithra M.; Hanumantha, Prashanth J.; Gattu, Bharat Electrochimica Acta, Vol. 229 https://doi.org/10.1016/j.electacta.2017.01.115	journal	March 2017
Graphene-wrapped chromium-MOF(MIL-101)/sulfur composite for performance improvement of high-rate rechargeable Li–S batteries Zhao, Zhenxia; Wang, Sha; Liang, Rui J. Mater. Chem. A, Vol. 2, Issue 33 https://doi.org/10.1039/C4TA01241K	journal	January 2014
3D Porous Cu Current Collector/Li-Metal Composite Anode for Stable Lithium-Metal Batteries Li, Qi; Zhu, Shoupu; Lu, Yingying Advanced Functional Materials, Vol. 27, Issue 18 https://doi.org/10.1002/adfm.201606422	journal	March 2017
Adsorption of benzonitrile and alkyl cyanides on evaporated nickel and palladium films studied by XPS Nakayama, T.; Inamura, K.; Inoue, Y. Surface Science, Vol. 179, Issue 1 https://doi.org/10.1016/0039-6028(87)90119-1	journal	January 1987
Confinement of polysulfides within bi-functional metal–organic frameworks for high performance lithium–sulfur batteries Hong, Xu-Jia; Tan, Tian-Xiong; Guo, Yu-Kai Nanoscale, Vol. 10, Issue 6 https://doi.org/10.1039/C7NR07118C	journal	January 2018
Spectroscopic changes in human dentine exposed to various storage solutions — short term Strawn, S. E.; White, J. M.; Marshall, G. W. Journal of Dentistry, Vol. 24, Issue 6 https://doi.org/10.1016/0300-5712(95)00106-9	journal	November 1996
Thermal stability of LiPF6 salt and Li-ion battery electrolytes containing LiPF6 Yang, Hui; Zhuang, Guorong V.; Ross, Philip N. Journal of Power Sources, Vol. 161, Issue 1 https://doi.org/10.1016/j.jpowsour.2006.03.058	journal	October 2006
An overview of the research and development of solid polymer electrolyte batteries Murata, Kazuo; Izuchi, Shuichi; Yoshihisa, Youetsu Electrochimica Acta, Vol. 45, Issue 8-9 https://doi.org/10.1016/S0013-4686(99)00365-5	journal	January 2000
Sulfur@graphene oxide core–shell particles as a rechargeable lithium–sulfur battery cathode material with high cycling stability and capacity Xiao, Min; Huang, Miao; Zeng, Songshan RSC Advances, Vol. 3, Issue 15 https://doi.org/10.1039/c3ra00017f	journal	January 2013
Untersuchungen der Ladungsverteilung in freiem und gebundenem 1,1-Dicyanoethylen-2,2-dithiolat Eine ab initio-HF-MO- und XPS-Studie Hummel, Hans-U.; F�rner, W.; Krogmann, K. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 540, Issue 9-10 https://doi.org/10.1002/zaac.19865400933	journal	September 1986
Highly Reversible Lithium/Dissolved Polysulfide Batteries with Carbon Nanotube Electrodes Fu, Yongzhu; Su, Yu-Sheng; Manthiram, Arumugam Angewandte Chemie International Edition, Vol. 52, Issue 27 https://doi.org/10.1002/anie.201301250	journal	May 2013
Electron-, x-ray-, and ion-stimulated decomposition of nitrate salts Aduru, Subhodaya; Contarini, Salvatore; Rabalais, J. Wayne The Journal of Physical Chemistry, Vol. 90, Issue 8 https://doi.org/10.1021/j100399a045	journal	April 1986
Valence band structures and core-electron energy levels in the monochalcogenides of gallium. Photoelectron spectroscopic study Thomas, J. M.; Adams, I.; Williams, R. H. Journal of the Chemical Society, Faraday Transactions 2, Vol. 68 https://doi.org/10.1039/f29726800755	journal	January 1972
Lithium-Sulfur Batteries: Electrochemistry, Materials, and Prospects Yin, Ya-Xia; Xin, Sen; Guo, Yu-Guo Angewandte Chemie International Edition, Vol. 52, Issue 50 https://doi.org/10.1002/anie.201304762	journal	November 2013
Polysulfide Shuttle Study in the Li/S Battery System Mikhaylik, Yuriy V.; Akridge, James R. Journal of The Electrochemical Society, Vol. 151, Issue 11, p. A1969-A1976 https://doi.org/10.1149/1.1806394	journal	January 2004
ESCA study of molecular GeS3-x Tex As2 glasses Hollinger, G.; Kumurdjian, P.; Mackowski, J. M. Journal of Electron Spectroscopy and Related Phenomena, Vol. 5, Issue 1 https://doi.org/10.1016/0368-2048(74)85015-2	journal	January 1974
Growth and characterization of new semiorganic nonlinear optical and piezoelectric lithium sulfate monohydrate oxalate single crystals Yadav, Harsh; Sinha, Nidhi; Kumar, Binay Materials Research Bulletin, Vol. 64 https://doi.org/10.1016/j.materresbull.2014.12.065	journal	April 2015
A Lithium-Sulfur Battery with a High Areal Energy Density Kim, Joo-Seong; Hwang, Tae Hoon; Kim, Byung Gon Advanced Functional Materials, Vol. 24, Issue 34 https://doi.org/10.1002/adfm.201400935	journal	June 2014
High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites Lin, Xiang; Telepeni, Irvin; Blake, Alexander J. Journal of the American Chemical Society, Vol. 131, Issue 6 https://doi.org/10.1021/ja806624j	journal	February 2009
Effect of tensile strain rate and elongation on crystalline structure and piezoelectric properties of PVDF thin films Mohammadi, Behzad; Yousefi, Ali Akbar; Bellah, Samad Moemen Polymer Testing, Vol. 26, Issue 1 https://doi.org/10.1016/j.polymertesting.2006.08.003	journal	February 2007
Lithium-Sulfur Batteries: Progress and Prospects Manthiram, Arumugam; Chung, Sheng-Heng; Zu, Chenxi Advanced Materials, Vol. 27, Issue 12 https://doi.org/10.1002/adma.201405115	journal	February 2015
Metal-organic framework based on copper(I) sulfate and 4,4′-bipyridine catalyzes the cyclopropanation of styrene Shi, Fa-Nian; Silva, Ana Rosa; Rocha, João Journal of Solid State Chemistry, Vol. 184, Issue 8 https://doi.org/10.1016/j.jssc.2011.06.023	journal	August 2011
An investigation of the thermal degradation of melamine phosphonite by XPS and thermal analysis techniques Feng, Daming; Zhou, Zhengmao; Bo, Meiping Polymer Degradation and Stability, Vol. 50, Issue 1 https://doi.org/10.1016/0141-3910(95)00123-4	journal	January 1995
Novel gel polymer electrolyte for high-performance lithium–sulfur batteries Liu, Ming; Zhou, Dong; He, Yan-Bing Nano Energy, Vol. 22 https://doi.org/10.1016/j.nanoen.2016.02.008	journal	April 2016
A lithium anode protection guided highly-stable lithium–sulfur battery Ma, Guoqiang; Wen, Zhaoyin; Wu, Meifen Chem. Commun., Vol. 50, Issue 91 https://doi.org/10.1039/C4CC05535G	journal	January 2014
Ni(II), Co(II), Cu(II), Zn(II) and Na(I) complexes of a hybrid ligand 4′-(4‴-benzo-15-crown-5)-methyloxy-2,2′:6′,2″-terpyridine Logacheva, Nadezhda M.; Baulin, Vladimir E.; Tsivadze, Aslan Yu. Dalton Transactions, Issue 14 https://doi.org/10.1039/b819805e	journal	January 2009
A highly efficient polysulfide mediator for lithium–sulfur batteries Liang, Xiao; Hart, Connor; Pang, Quan Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms6682	journal	January 2015
Molecular Spectroscopy by Means of ESCA II. Sulfur compounds. Correlation of electron binding energy with structure Lindberg, B. J.; Hamrin, K.; Johansson, G. Physica Scripta, Vol. 1, Issue 5-6 https://doi.org/10.1088/0031-8949/1/5-6/020	journal	May 1970
Roles of the Lewis Acid and Base in the Chemical Reduction of CO ₂ Catalyzed by Frustrated Lewis Pairs Lim, Chern-Hooi; Holder, Aaron M.; Hynes, James T. Inorganic Chemistry, Vol. 52, Issue 17 https://doi.org/10.1021/ic4013729	journal	August 2013
Ionic shield for polysulfides towards highly-stable lithium–sulfur batteries Huang, Jia-Qi; Zhang, Qiang; Peng, Hong-Jie Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE42223B	journal	January 2014
Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit? Farha, Omar K.; Eryazici, Ibrahim; Jeong, Nak Cheon Journal of the American Chemical Society, Vol. 134, Issue 36, p. 15016-15021 https://doi.org/10.1021/ja3055639	journal	August 2012
New diversity in the sulfur cycle Hofer, Ursula Nature Reviews Microbiology, Vol. 16, Issue 5 https://doi.org/10.1038/nrmicro.2018.32	journal	March 2018
Building better lithium-sulfur batteries: from LiNO3 to solid oxide catalyst Ding, Ning; Zhou, Lan; Zhou, Changwei Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep33154	journal	September 2016
A layer-by-layer supramolecular structure for a sulfur cathode Bucur, Claudiu B.; Muldoon, John; Lita, Adrian Energy & Environmental Science, Vol. 9, Issue 3 https://doi.org/10.1039/C5EE02367J	journal	January 2016
Raman and FTIR spectroscopic study of carboxymethylated non-starch polysaccharides Yuen, Sze-Nga; Choi, Siu-Mei; Phillips, David Lee Food Chemistry, Vol. 114, Issue 3 https://doi.org/10.1016/j.foodchem.2008.10.053	journal	June 2009
Improved cycle stability and high security of Li-B alloy anode for lithium–sulfur battery Zhang, Xiaolin; Wang, Weikun; Wang, Anbang J. Mater. Chem. A, Vol. 2, Issue 30 https://doi.org/10.1039/C4TA01709A	journal	January 2014
FTIR study of water in cast Nafion films Ludvigsson, M.; Lindgren, J.; Tegenfeldt, J. Electrochimica Acta, Vol. 45, Issue 14 https://doi.org/10.1016/S0013-4686(99)00438-7	journal	March 2000
Nanoarchitectured Graphene/CNT@Porous Carbon with Extraordinary Electrical Conductivity and Interconnected Micro/Mesopores for Lithium-Sulfur Batteries Peng, Hong-Jie; Huang, Jia-Qi; Zhao, Meng-Qiang Advanced Functional Materials, Vol. 24, Issue 19 https://doi.org/10.1002/adfm.201303296	journal	January 2014
Structural analysis of photodegraded wood by means of FTIR spectroscopy Colom, X.; Carrillo, F.; Nogués, F. Polymer Degradation and Stability, Vol. 80, Issue 3 https://doi.org/10.1016/S0141-3910(03)00051-X	journal	January 2003
Effect of chemical reactivity of polysulfide toward carbonate-based electrolyte on the electrochemical performance of Li–S batteries Yim, Taeeun; Park, Min-Sik; Yu, Ji-Sang Electrochimica Acta, Vol. 107 https://doi.org/10.1016/j.electacta.2013.06.039	journal	September 2013
Conducting linear chains of sulphur inside carbon nanotubes Fujimori, Toshihiko; Morelos-Gómez, Aarón; Zhu, Zhen Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3162	journal	July 2013
Bonding in some donor–acceptor complexes involving boron trifluoride. Study by means of ESCA and molecular orbital calculations Barber, M.; Connor, J. A.; Guest, M. F. J. Chem. Soc., Faraday Trans. 2, Vol. 69, Issue 0 https://doi.org/10.1039/F29736900551	journal	January 1973

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