Sulfonic Acid Based Complex Framework Materials (CFM): Nanostructured Polysulfide Immobilization Systems for Rechargeable Lithium–Sulfur Battery

Shanthi, Pavithra M.; Hanumantha, Prashanth J.; Ramalinga, Kuruba; Gattu, Bharat; Datta, Moni K.; Kumta, Prashant N.

doi:10.1149/2.0251910jes

Title: Sulfonic Acid Based Complex Framework Materials (CFM): Nanostructured Polysulfide Immobilization Systems for Rechargeable Lithium–Sulfur Battery

Journal Article · Tue Jun 04 00:00:00 EDT 2019 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0251910jes· OSTI ID:1524478

Shanthi, Pavithra M.; Hanumantha, Prashanth J.; Ramalinga, Kuruba; Gattu, Bharat; Datta, Moni K.;

Lithium-sulfur (Li-S) secondary batteries with sulfur cathodes and theoretical energy density of ~2600 Wh/kg, are promising high energy-density system for next-generation electric-vehicles (EVs) potentially mitigating the gravimetric and volumetric energy density limitations of existing lithium-ion (Li-ion) batteries. Herein, a chemically synthesized sulfonic acid-based complex framework material (CFM) termed as (SCFM), was used as sulfur host (S-SCFM) to prevent polysulfide dissolution in Li-S batteries. The S-SCFM based CFM cathodes show an initial capacity of 1190 mAh/g and a capacity of 1044 mAh/g after 100 cycles. In addition, the S-SCFM based CFM cathodes exhibited good cycling stability with a minimal fade rate of ~0.0012% per cycle. XPS analysis of the cycled separators with the S-SCFM electrodes shows complete absence of polysulfide species after 100 charge-discharge cycles. It was also identified that the SCFM based CFM chemically binds sulfur via -C-S- linkages thereby exhibiting an affinity for the polysulfide species formed during the charge-discharge cycles. As a result, the SCFM based CFM prevent polysulfide species from dissolving and diffusing into the electrolyte. A thorough understanding of these engineered SCFM based CFM sulfur host in Li-S battery outlined herein will be vital in designing promising sulfur hosts for next generation sulfur cathodes in Li-S batteries.

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Research Organization:: Univ. of Pittsburgh, PA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

Grant/Contract Number:: EE0006825; EE0007797; EE000819; EE0008199

OSTI ID:: 1524478

Alternate ID(s):: OSTI ID: 1613998; OSTI ID: 1640023

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Vol. 166 Journal Issue: 10; ISSN 0013-4651

Publisher:: IOP Publishing - The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 44 works

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