Giant Superelastic Piezoelectricity in Flexible Ferroelectric BaTiO3 Membranes

Elangovan, Hemaprabha; Barzilay, Maya; Seremi, Sahar; Cohen, Noy; Jiang, Yizhe; Martin, Lane W.; Ivry, Yachin

doi:10.1021/acsnano.0c01615

Title: Giant Superelastic Piezoelectricity in Flexible Ferroelectric BaTiO3 Membranes

Journal Article · Thu Apr 09 00:00:00 EDT 2020 · ACS Nano

DOI:https://doi.org/10.1021/acsnano.0c01615· OSTI ID:1637316

Elangovan, Hemaprabha ^[1]; Barzilay, Maya ^[1];

^[2];

^[3]; Jiang, Yizhe ^[2]; Martin, Lane W. ^[2];

^[1]

Technion-Israel Inst. of Technology, Haifa (Israel). Solid State Institute
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Technion-Israel Inst. of Technology, Haifa (Israel)

Mechanical displacement in commonly used piezoelectric materials is typically restricted to linear or biaxial in nature and to a few percent of the material dimensions. Here in this paper, we show that free-standing BaTiO₃ membranes exhibit nonconventional electromechanical coupling. Under an external electric field, these superelastic membranes undergo controllable and reversible “sushi-rolling-like” 180° folding–unfolding cycles. This crease-free folding is mediated by charged ferroelectric domains, leading to giant >3.8 and 4.6 μm displacements for a 30 nm thick membrane at room temperature and 60 °C, respectively. Further increasing the electric field above the coercive value changes the fold curvature, hence augmenting the effective piezoresponse. Finally, it is found that the membranes fold with increasing temperature followed by complete immobility of the membrane above the Curie temperature, allowing us to model the ferroelectric domain origin of the effect.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Israel Science Foundation (ISF); Technion Russel Barry Nanoscience Institute

Grant/Contract Number:: AC02-05CH11231; SC0012375; 602/17; DMR-1708615

OSTI ID:: 1637316

Journal Information:: ACS Nano, Vol. 14, Issue 4; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 22 works

Citation information provided by
Web of Science

References (37)

High-sensitivity acoustic sensors from nanofibre webs Lang, Chenhong; Fang, Jian; Shao, Hao Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11108	journal	March 2016
Designing electromechanical metamaterial with full nonzero piezoelectric coefficients Yang, Jikun; Li, Zhanmiao; Xin, Xudong Science Advances, Vol. 5, Issue 11 https://doi.org/10.1126/sciadv.aax1782	journal	November 2019
Conjuncted Pyro‐Piezoelectric Effect for Self‐Powered Simultaneous Temperature and Pressure Sensing Song, Kai; Zhao, Rudai; Wang, Zhong Lin Advanced Materials, Vol. 31, Issue 36 https://doi.org/10.1002/adma.201902831	journal	June 2019
Piezoelectric Nanogenerators Based on Zinc Oxide Nanowire Arrays Wang, Z. L. Science, Vol. 312, Issue 5771 https://doi.org/10.1126/science.1124005	journal	April 2006
Enhanced Piezoelectricity and Stretchability in Energy Harvesting Devices Fabricated from Buckled PZT Ribbons Qi, Yi; Kim, Jihoon; Nguyen, Thanh D. Nano Letters, Vol. 11, Issue 3 https://doi.org/10.1021/nl104412b	journal	March 2011
Highly Stretchable Piezoelectric-Pyroelectric Hybrid Nanogenerator Lee, Ju-Hyuck; Lee, Keun Young; Gupta, Manoj Kumar Advanced Materials, Vol. 26, Issue 5 https://doi.org/10.1002/adma.201303570	journal	October 2013
A Hybrid Piezoelectric Structure for Wearable Nanogenerators Lee, Minbaek; Chen, Chih-Yen; Wang, Sihong Advanced Materials, Vol. 24, Issue 13 https://doi.org/10.1002/adma.201200150	journal	March 2012
PZT-Based Piezoelectric MEMS Technology Smith, Gabriel L.; Pulskamp, Jeffrey S.; Sanchez, Luz M. Journal of the American Ceramic Society, Vol. 95, Issue 6 https://doi.org/10.1111/j.1551-2916.2012.05155.x	journal	April 2012
Cellular Polypropylene Piezoelectret for Human Body Energy Harvesting and Health Monitoring Wu, Nan; Cheng, Xiaofeng; Zhong, Qize Advanced Functional Materials, Vol. 25, Issue 30 https://doi.org/10.1002/adfm.201501695	journal	June 2015
Piezoelectric Biomaterials for Sensors and Actuators Chorsi, Meysam T.; Curry, Eli J.; Chorsi, Hamid T. Advanced Materials, Vol. 31, Issue 1 https://doi.org/10.1002/adma.201802084	journal	October 2018
Conformable amplified lead zirconate titanate sensors with enhanced piezoelectric response for cutaneous pressure monitoring Dagdeviren, Canan; Su, Yewang; Joe, Pauline Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5496	journal	August 2014
Subatomic deformation driven by vertical piezoelectricity from CdS ultrathin films Wang, Xuewen; He, Xuexia; Zhu, Hongfei Science Advances, Vol. 2, Issue 7 https://doi.org/10.1126/sciadv.1600209	journal	July 2016
Electronic Transport and Ferroelectric Switching in Ion-Bombarded, Defect-Engineered BiFeO ₃ Thin Films Saremi, Sahar; Xu, Ruijuan; Dedon, Liv R. Advanced Materials Interfaces, Vol. 5, Issue 3 https://doi.org/10.1002/admi.201700991	journal	November 2017
Nonstoichiometry, Structure, and Properties of BiFeO ₃ Films Dedon, Liv R.; Saremi, Sahar; Chen, Zuhuang Chemistry of Materials, Vol. 28, Issue 16 https://doi.org/10.1021/acs.chemmater.6b02542	journal	August 2016
Oxide Heteroepitaxy-Based Flexible Ferroelectric Transistor Tsai, Meng-Fu; Jiang, Jie; Shao, Pao-Wen ACS Applied Materials & Interfaces, Vol. 11, Issue 29 https://doi.org/10.1021/acsami.9b06332	journal	July 2019
Enhanced Ferroelectric Functionality in Flexible Lead Zirconate Titanate Films with In Situ Substrate‐Clamping Compensation Onn Winestook, Rachel; Saguy, Cecile; Ma, Chun‐Hao Advanced Electronic Materials, Vol. 5, Issue 10 https://doi.org/10.1002/aelm.201900428	journal	July 2019
Untethered flight of an insect-sized flapping-wing microscale aerial vehicle Jafferis, Noah T.; Helbling, E. Farrell; Karpelson, Michael Nature, Vol. 570, Issue 7762 https://doi.org/10.1038/s41586-019-1322-0	journal	June 2019
Enhancement of Ferroelectricity in Strained BaTiO₃ Thin Films Choi, K. J.; Biegalski, M.; Li, Y. L. Science, Vol. 306, Issue 5698, p. 1005-1009 https://doi.org/10.1126/science.1103218	journal	November 2004
Room-temperature ferroelectricity in strained SrTiO₃ Haeni, J. H.; Irvin, P.; Chang, W. Nature, Vol. 430, Issue 7001, p. 758-761 https://doi.org/10.1038/nature02773	journal	August 2004
Dynamics of ferroelastic domains in ferroelectric thin films Nagarajan, V.; Roytburd, A.; Stanishevsky, A. Nature Materials, Vol. 2, Issue 1 https://doi.org/10.1038/nmat800	journal	December 2002
Observation of polar vortices in oxide superlattices Yadav, A. K.; Nelson, C. T.; Hsu, S. L. Nature, Vol. 530, Issue 7589 https://doi.org/10.1038/nature16463	journal	January 2016
Enhanced pyroelectric effect in self-supported films of BaTiO3 with polycrystalline macrodomains Ivry, Yachin; Lyahovitskaya, Vera; Zon, Ilya Applied Physics Letters, Vol. 90, Issue 17 https://doi.org/10.1063/1.2730749	journal	April 2007
Synthesis of freestanding single-crystal perovskite films and heterostructures by etching of sacrificial water-soluble layers Lu, Di; Baek, David J.; Hong, Seung Sae Nature Materials, Vol. 15, Issue 12 https://doi.org/10.1038/nmat4749	journal	September 2016
Super-elastic ferroelectric single-crystal membrane with continuous electric dipole rotation Dong, Guohua; Li, Suzhi; Yao, Mouteng Science, Vol. 366, Issue 6464 https://doi.org/10.1126/science.aay7221	journal	October 2019
Domain Dynamics During Ferroelectric Switching Nelson, C. T.; Gao, P.; Jokisaari, J. R. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1206980	journal	November 2011
Ferroelastic domain switching dynamics under electrical and mechanical excitations Gao, Peng; Britson, Jason; Nelson, Christopher T. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4801	journal	May 2014
Epitaxial TiO _x Surface in Ferroelectric BaTiO ₃ : Native Structure and Dynamic Patterning at the Atomic Scale Barzilay, Maya; Qiu, Tian; Rappe, Andrew M. Advanced Functional Materials, Vol. 30, Issue 18 https://doi.org/10.1002/adfm.201902549	journal	June 2019
Polarization reorientation in ferroelectric lead zirconate titanate thin films with electron beams Li, D. B.; Strachan, D. R.; Ferris, J. H. Journal of Materials Research, Vol. 21, Issue 4 https://doi.org/10.1557/jmr.2006.0107	journal	April 2006
Electron-beam-induced ferroelectric domain behavior in the transmission electron microscope: Toward deterministic domain patterning Hart, James L.; Liu, Shi; Lang, Andrew C. Physical Review B, Vol. 94, Issue 17 https://doi.org/10.1103/PhysRevB.94.174104	journal	November 2016
Surface Nucleation of the Paraelectric Phase in Ferroelectric BaTiO ₃ : Atomic Scale Mapping Barzilay, Maya; Elangovan, Hemaprabha; Ivry, Yachin ACS Applied Electronic Materials, Vol. 1, Issue 11 https://doi.org/10.1021/acsaelm.9b00580	journal	October 2019
Scaling of domain periodicity with thickness measured in $Ba Ti O_{3}$ single crystal lamellae and comparison with other ferroics Schilling, A.; Adams, T. B.; Bowman, R. M. Physical Review B, Vol. 74, Issue 2 https://doi.org/10.1103/PhysRevB.74.024115	journal	July 2006
All-inkjet-printed flexible piezoelectric generator made of solvent evaporation assisted BaTiO3 hybrid material Lim, Jongwoo; Jung, Hyunsung; Baek, Changyeon Nano Energy, Vol. 41 https://doi.org/10.1016/j.nanoen.2017.09.046	journal	November 2017
Atomic mechanism of polarization-controlled surface reconstruction in ferroelectric thin films Gao, Peng; Liu, Heng-Jui; Huang, Yen-Lin Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11318	journal	April 2016
A flexoelectric microelectromechanical system on silicon Bhaskar, Umesh Kumar; Banerjee, Nirupam; Abdollahi, Amir Nature Nanotechnology, Vol. 11, Issue 3 https://doi.org/10.1038/nnano.2015.260	journal	November 2015
Piezoelectric Mimicry of Flexoelectricity Abdollahi, Amir; Vásquez-Sancho, Fabián; Catalan, Gustau Physical Review Letters, Vol. 121, Issue 20 https://doi.org/10.1103/PhysRevLett.121.205502	journal	November 2018
Nanometer resolution piezoresponse force microscopy to study deep submicron ferroelectric and ferroelastic domains Ivry, Yachin; Chu, DaPing; Durkan, Colm Applied Physics Letters, Vol. 94, Issue 16 https://doi.org/10.1063/1.3105942	journal	April 2009
Surface-screening mechanisms in ferroelectric thin films and their effect on polarization dynamics and domain structures Kalinin, Sergei V.; Kim, Yunseok; Fong, Dillon D. Reports on Progress in Physics, Vol. 81, Issue 3 https://doi.org/10.1088/1361-6633/aa915a	journal	January 2018

Similar Records

Understanding the structure–property relationships of the ferroelectric to relaxor transition of the (1-x)BaTiO3–(x)BiInO3 lead-free piezoelectric system

Journal Article · Mon May 01 00:00:00 EDT 2017 · Journal of Materials Science · OSTI ID:1637316

Manjón-Sanz, Alicia; Berger, Caitlin; Dolgos, Michelle R.

Atomic Resolution Probing of Phase Transformations and Domain Evolution During Large Superelastic Deformation in Ferroelectrics with in situ TEM

Journal Article · Mon Aug 05 00:00:00 EDT 2019 · Microscopy and Microanalysis · OSTI ID:1637316

Deng, Y.; Gammer, C.; Ciston, J.; +6 more

Beyond Substrates: Strain Engineering of Ferroelectric Membranes

Journal Article · Tue Sep 22 00:00:00 EDT 2020 · Advanced Materials · OSTI ID:1637316

Pesquera, David; Parsonnet, Eric; Qualls, Alexander; +9 more

Related Subjects

36 MATERIALS SCIENCE
flexible piezoelectrics
flexible ferroelectrics
piezoelectric membrane
ferroelectric membrane
crease-free folding
in situ microscopy

Title: Giant Superelastic Piezoelectricity in Flexible Ferroelectric BaTiO3 Membranes

Citation Formats

References (37)

Similar Records

Related Subjects