Postsynthetic Modification: An Enabling Technology for the Advancement of Metal–Organic Frameworks

Kalaj, Mark; Cohen, Seth M.

doi:10.1021/acscentsci.0c00690

Title: Postsynthetic Modification: An Enabling Technology for the Advancement of Metal–Organic Frameworks

Journal Article · Thu Jul 02 00:00:00 EDT 2020 · ACS Central Science

DOI:https://doi.org/10.1021/acscentsci.0c00690· OSTI ID:1635736

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Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093-0358, United States

Metal-organic frameworks (MOFs) are a class of porous materials with immense chemical tunability derived from their organic and inorganic building blocks. Presynthetic approaches have been used to construct tailor-made MOFs, but with a rather restricted functional group scope limited by the typical MOF solvothermal synthesis conditions. Postsynthetic modification (PSM) of MOFs has matured into an alternative strategy to broaden the functional group scope of MOFs. PSM has many incarnations, but two main avenues include (1) covalent PSM, in which the organic linkers of the MOF are modified with a reagent resulting in new functional groups, and (2) coordinative PSM, where organic molecules containing metal ligating groups are introduced onto the inorganic secondary building units (SBUs) of the MOF. These methods have evolved from simple efforts to modifying MOFs to demonstrate proof-of-concept, to becoming key synthetic tools for advancing MOFs for a range of emerging applications, including selective gas sorption, catalysis, and drug delivery. Moreover, both covalent and coordinative PSM have been used to create hierarchal MOFs, MOF-based porous liquids, and other unusual MOF materials. This Outlook highlights recent reports that have extended the scope of PSM in MOFs, some seminal reports that have contributed to the advancement of PSM in MOFs, and our view on future directions of the field.

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Research Organization:: University of California San Diego, La Jolla, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: FG02-08ER46519; CHE-1661655; DMR-1506059

OSTI ID:: 1635736

Alternate ID(s):: OSTI ID: 1643985; OSTI ID: 1779730

Journal Information:: ACS Central Science, Journal Name: ACS Central Science Vol. 6 Journal Issue: 7; ISSN 2374-7943

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 223 works

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Hierarchically porous metal–organic frameworks: synthetic strategies and applications Feng, Liang; Wang, Kun-Yu; Lv, Xiu-Liang National Science Review, Vol. 7, Issue 11 https://doi.org/10.1093/nsr/nwz170	journal	November 2019
New Class of Type III Porous Liquids: A Promising Platform for Rational Adjustment of Gas Sorption Behavior Shan, Weida; Fulvio, Pasquale F.; Kong, Liyun ACS Applied Materials & Interfaces, Vol. 10, Issue 1 https://doi.org/10.1021/acsami.7b15873	journal	December 2017

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