Postsynthetic Tuning of Metal–Organic Frameworks for Targeted Applications

Islamoglu, Timur; Goswami, Subhadip; Li, Zhanyong; Howarth, Ashlee J.; Farha, Omar K.; Hupp, Joseph T.

doi:10.1021/acs.accounts.6b00577

Title: Postsynthetic Tuning of Metal–Organic Frameworks for Targeted Applications

Journal Article · Wed Feb 08 00:00:00 EST 2017 · Accounts of Chemical Research

DOI:https://doi.org/10.1021/acs.accounts.6b00577· OSTI ID:1871011

^[1]; Goswami, Subhadip ^[1];

^[1]; Howarth, Ashlee J. ^[1];

^[2];

^[1]

Northwestern Univ., Evanston, IL (United States)
Northwestern Univ., Evanston, IL (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)

Metal–organic frameworks (MOFs) are periodic, hybrid, atomically well-defined porous materials that typically form by self-assembly and consist of inorganic nodes (metal ions or clusters) and multitopic organic linkers. MOFs as a whole offer many intriguing properties, including ultrahigh porosity, tunable chemical functionality, and low density. These properties point to numerous potential applications, including gas storage, chemical separations, catalysis, light harvesting, and chemical sensing, to name a few. Reticular chemistry, or the linking of molecular building blocks into predetermined network structures, has been employed to synthesize thousands of MOFs. Given the vast library of candidate nodes and linkers, the number of potentially synthetically accessible MOFs is enormous. Nevertheless, a powerful complementary approach to obtain specific structures with desired chemical functionality is to modify known MOFs after synthesis. This approach is particularly useful when incorporation of particular chemical functionalities via direct synthesis is challenging or impossible. Here, the challenges may stem from limited stability or solubility of precursors, unwanted secondary reactivity of precursors, or incompatibility of functional groups with the conditions needed for direct synthesis. MOFs can be postsynthetically modified by replacing the metal nodes and/or organic linkers or via functionalization of the metal nodes and/or organic linkers.

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Research Organization:: Northwestern Univ., Evanston, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: FG02-03ER15457; FG02-87ER13808; SC0012702; SC0001059

OSTI ID:: 1871011

Journal Information:: Accounts of Chemical Research, Vol. 50, Issue 4; ISSN 0001-4842

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 525 works

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