High Coulombic efficiency cycling of metal batteries

Zhang, Ji-Guang; Adams, Brian D. G.; Xu, Wu; Zheng, Jianming

Title: High Coulombic efficiency cycling of metal batteries

Patent · Tue Jan 28 00:00:00 EST 2020

OSTI ID:1632503

Zhang, Ji-Guang; Adams, Brian D. G.; Xu, Wu; Zheng, Jianming

Embodiments of a method for cycling a rechargeable alkali metal battery with high Coulombic efficiency (CE) are disclosed. A slow charge/rapid discharge protocol is used in conjunction with a concentrated electrolyte to achieve high CE in rechargeable lithium and sodium batteries, include anode-free batteries. In some examples, the CE is ≥99.8%.

View Patent

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Number(s):: 10,547,088

Application Number:: 15/142,322

OSTI ID:: 1632503

Resource Relation:: Patent File Date: 04/29/2016

Country of Publication:: United States

Language:: English

References (25)

High rate and stable cycling of lithium metal anode Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7362	journal	February 2015
Symmetrical Impedance Study on Inactivation Induced Degradation of Lithium Electrodes for Batteries Beyond Lithium-Ion Woo, Jung-Je; Maroni, Victor A.; Liu, Gao Journal of The Electrochemical Society, Vol. 161, Issue 5 https://doi.org/10.1149/2.089405jes	journal	January 2014
Buried anode lithium thin film battery and process for forming the same Lee, Se-Hee; Tracy, C. Edwin; Liu, Ping https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6805999 US Patent Document 6,805,999	patent	October 2004
“Lithium-Free” Thin-Film Battery with In Situ Plated Li Anode Neudecker, B. J.; Dudney, N. J.; Bates, J. B. Journal of The Electrochemical Society, Vol. 147, Issue 2 https://doi.org/10.1149/1.1393226	journal	January 2000
High Voltage Lithium Ion Batteries Having Fluorinated Electrolytes and Lithium-Based Additives Zhang, Zhengcheng; Hu, Libo; Amine, Khalil https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150050561 US Patent Application 13/969134; 20150050561	patent-application	February 2015
Active Substance for Electrode for a Sodium Ion Battery Senguttuvan, Premkumar; Palacin, Rose Maria; Tarascon, Jean-Marie https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150295236 US Patent Application 14/129,756; 2015/0295236 Al	patent-application	October 2015
Aliovalent Protective Layers for Active Metal Anodes Jonghe, Lutgard C. De; Nimon, Yevgeniy S.; Visco, Steven J. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040253510 US Patent Application 10/861336; 20040253510	patent-application	December 2004
Morphological Transitions on Lithium Metal Anodes López, Carmen M.; Vaughey, John T.; Dees, Dennis W. Journal of The Electrochemical Society, Vol. 156, Issue 9 https://doi.org/10.1149/1.3158548	journal	January 2009
Composite Cathode Active Material, Cathode and Lithium Battery Including the Composite Cathode Active Material, and Method of Preparing the Composite Cathode Active Material Kim, Gue-Sang; Choi, Young-Min; Choi, Won-Chang https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120326079 US Patent Application 13/530142; 20120326079	patent-application	December 2012
Multi-layered, chemically bonded lithium-ion and lithium/air batteries Narula, Chaitanya K.; Nanda, Jagjit; Bischoff, Brian L. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8722256 US Patent Document 8,722,256	patent	May 2014
Molten Salt Composition and Use Thereof Hagiwara, Rika; Matsumoto, Kazuhiko; Tamaki, Kenichiro https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090212743 US Patent Application 11/886781; 20090212743	patent-application	August 2009
Optimization of the lithium-ion cell electrolyte composition through the use of the LiTDI salt Niedzicki, L.; Karpierz, E.; Bitner, A. Electrochimica Acta, Vol. 117 https://doi.org/10.1016/j.electacta.2013.11.134	journal	January 2014
Effects of High and Low Salt Concentration in Electrolytes at Lithium–Metal Anode Surfaces Camacho-Forero, Luis E.; Smith, Taylor W.; Balbuena, Perla B. The Journal of Physical Chemistry C, Vol. 121, Issue 1 https://doi.org/10.1021/acs.jpcc.6b10774	journal	December 2016
The Application of Atomic Force Microscopy for the Study of Li Deposition Processes Aurbach, Doron Journal of The Electrochemical Society, Vol. 143, Issue 11 https://doi.org/10.1149/1.1837248	journal	January 1996
A Highly Reversible Lithium Metal Anode Park, Min Sik; Ma, Sang Bok; Lee, Dong Joon Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep03815	journal	January 2014
Microscopic observations of the formation, growth and shrinkage of lithium moss during electrodeposition and dissolution Steiger, Jens; Kramer, Dominik; Mönig, Reiner Electrochimica Acta, Vol. 136 https://doi.org/10.1016/j.electacta.2014.05.120	journal	August 2014
High Energy Density Non-Aqueous Electrochemical Cell with Extended Operating Temperature Window Janakiraman, Umamaheswari; Ndzebet, Ernest; Destephen, Mario https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160359158 US Patent Application 14/054454; 20160359158	patent-application	December 2016
Rechargeable Seawater Battery and Its Electrochemical Mechanism Kim, Jae-Kwang; Lee, Eungje; Kim, Hyojin ChemElectroChem, Vol. 2, Issue 3 https://doi.org/10.1002/celc.201402344	journal	November 2014
History, Evolution, and Future Status of Energy Storage Whittingham, M. S. Proceedings of the IEEE, Vol. 100, Issue Special Centennial Issue https://doi.org/10.1109/JPROC.2012.2190170	journal	May 2012
Fabrication and characterization of amorphous lithium electrolyte thin films and rechargeable thin-film batteries Bates, J. B.; Dudney, N. J.; Gruzalski, G. R. Journal of Power Sources, Vol. 43, Issue 1-3, p. 103-110 https://doi.org/10.1016/0378-7753(93)80106-Y	journal	March 1993
Electrolytic Solution, Electrochemical Device, Lithium Ion Secondary Battery, and Module Taeda, Mayuko; Koh, Meiten; Nakazono, Aoi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160006078 US Patent Application 14/769863; 20160006078	patent-application	January 2016
Lithium Metal Batteries: Highly Stable Operation of Lithium Metal Batteries Enabled by the Formation of a Transient High‐Concentration Electrolyte Layer (Adv. Energy Mater. 8/2016) Zheng, Jianming; Yan, Pengfei; Mei, Donghai Advanced Energy Materials, Vol. 6, Issue 8 https://doi.org/10.1002/aenm.201670050	journal	April 2016
Thin-film rechargeable lithium batteries Bates, J. B.; Dudney, N. J.; Lubben, D. C. Journal of Power Sources, Vol. 54, Issue 1, p. 58-62 https://doi.org/10.1016/0378-7753(94)02040-A	journal	March 1995
Solid-State Sodium-Based Secondary Cell Having a Sodium Ion Conductive Ceramic Separator Boxley, Chett; Coors, W. Grover; Watkins, John Joseph https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20110104526 US Patent Application 12/940864; 20110104526	patent-application	May 2011
Partially And Fully Surface-enabled Alkali Metal Ion-exchanging Energy Storage Devices Zhamu, Aruna; Jang, Bor Z. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20160028122 US Patent Application 14/121050; 20160028122	patent-application	January 2016

Similar Records

Electrolyte for high efficiency cycling of sodium metal and rechargeable sodium-based batteries comprising the electrolyte

Patent · Tue Jan 01 00:00:00 EST 2019 · OSTI ID:1632503

Zhang, Ji-Guang; Cao, Ruiguo; Henderson, Wesley A.; +2 more

Anode-Free Rechargeable Lithium Metal Batteries

Journal Article · Thu Aug 18 00:00:00 EDT 2016 · Advanced Functional Materials · OSTI ID:1632503

Qian, Jiangfeng; Adams, Brian D.; Zheng, Jianming; +7 more

Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries

Journal Article · Wed Oct 11 00:00:00 EDT 2017 · Advanced Energy Materials · OSTI ID:1632503

Adams, Brian D.; Zheng, Jianming; Ren, Xiaodi; +2 more

Related Subjects

42 ENGINEERING
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
25 ENERGY STORAGE

Title: High Coulombic efficiency cycling of metal batteries

Citation Formats

References (25)

Similar Records

Related Subjects