Anode-Free Rechargeable Lithium Metal Batteries

Journal Article · Thu Aug 18 04:00:00 EDT 2016 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.201602353· OSTI ID:1340845

Qian, Jiangfeng ^[1]; Adams, Brian D. ^[1]; Zheng, Jianming ^[2]; Xu, Wu ^[1]; Henderson, Wesley A. ^[2]; Wang, Jun ^[3]; Bowden, Mark E. ^[4]; Xu, Suochang ^[5]; Hu, Jianzhi ^[6]; Zhang, Ji-Guang ^[1]

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1. The Joint Center for Energy Storage Research (JCESR), Pacific Northwest National Laboratory, Richland WA 99354 USA; Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA
2. Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA
3. A123 Systems Research and Development, Waltham MA 02451 USA
4. Environmental and Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland WA 99354 USA
5. Earth and Biological Science Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA
6. The Joint Center for Energy Storage Research (JCESR), Pacific Northwest National Laboratory, Richland WA 99354 USA; Earth and Biological Science Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA

Anode-free rechargeable lithium (Li) batteries (AFLBs) are phenomenal energy storage systems due to their significantly increased energy density and reduced cost relative to Li-ion batteries, as well as ease of assembly owing to the absence of an active (reactive) anode material. However, significant challenges, including Li dendrite growth and low cycling Coulombic efficiency (CE), have prevented their practical implementation. Here, we report for the first time an anode-free rechargeable lithium battery based on a Cu||LiFePO4 cell structure with an extremely high CE (> 99.8%). This results from the utilization of both an exceptionally stable electrolyte and optimized charge/discharge protocols which minimize the corrosion of the in-situ formed Li metal anode.

• Research Organization: Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
• Sponsoring Organization: USDOE
• DOE Contract Number: AC05-76RL01830
• OSTI ID: 1340845
• Report Number(s): PNNL-SA-117788; 48776; 48379; KC0208010
• Journal Information: Advanced Functional Materials, Journal Name: Advanced Functional Materials Journal Issue: 39 Vol. 26; ISSN 1616-301X
• Publisher: Wiley
• Country of Publication: United States
• Language: English

Related Subjects

Environmental Molecular Sciences Laboratory
Li battery
anode-free
charge rate
coullombic efficiency
dendrite
discharge rate