skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Late-stage diagenetic concretions in the Murray formation, Gale crater, Mars

Journal Article · · Icarus
 [1];  [1]; ORCiD logo [2];  [3];  [1];  [4];  [5]; ORCiD logo [6];  [2];  [1];  [7];  [8]
  1. California Institute of Technology (CalTech), Pasadena, CA (United States)
  2. Univ. of Tennessee, Knoxville, TN (United States)
  3. Univ. of New Brunswick, Fredericton NB (Canada)
  4. Univ. of Florida, Gainesville, FL (United States)
  5. Georgetown Univ., Washington, DC (United States)
  6. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  7. Pennsylvania State Univ., University Park, PA (United States)
  8. Washington Univ., St. Louis, MO (United States)

Concretions are prevalent features in the generally lacustrine deposits of the Murray formation in Gale crater. Here, we document the morphologic, textural, and chemical properties of these concretions throughout 300 m of Murray formation stratigraphy from Mars Science Laboratory observations between Sols 750–1900. We interpret these observations to constrain the timing and composition of post-depositional fluid events at Gale crater. We determine that the overall diversity of concretion morphology, size, texture, and chemistry throughout the Murray formation indicates that concretions formed in multiple, likely late diagenetic, episodes with varying fluid chemistries. Four major concretion assemblages are observed at distinct stratigraphic intervals and approximately correlate with major distinct chemical enrichments in Mg-S-Ni-Cl, Mn-P, and Ca-S, among other local enrichments. Different concretion size populations and complex relationships between concretions and veins also suggest multiple precipitation events at Gale crater. Many concretions likely formed during late diagenesis after sediment compaction and lithification, based on observations of concretions preserving primary host rock laminations without differential compaction. An upsection decrease in overall concretion size corresponds to an inferred upsection decrease in porosity and permeability, thus constraining concretion formation as postdating fluid events that produced initial cementation and porosity loss. The combined observations of late diagenetic concretions and distinct chemical enrichments related to concretions allow constraints to be placed on the chemistry of late stage fluids at Gale crater. Collectively, concretion observations from this work and previous studies of other diagenetic features (veins, alteration halos) suggest at least six post-depositional events that occurred at Gale crater after the deposition of the Murray formation.

Research Organization:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE; National Aeronautics and Space Administration (NASA)
Grant/Contract Number:
89233218CNA000001
OSTI ID:
1630877
Report Number(s):
LA-UR-19-32321; TRN: US2200710
Journal Information:
Icarus, Vol. 321, Issue C; ISSN 0019-1035
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 43 works
Citation information provided by
Web of Science

References (51)

Diagenetic origin of nodules in the Sheepbed member, Yellowknife Bay formation, Gale crater, Mars: Diagenetic Nodules in Gale Crater journal July 2014
Early Diagenetic Mineralization and Fossil Preservation in Modern Carbonate Concretions journal December 1994
Microbial processes: Controls on the shape and composition of carbonate concretions journal July 1993
Carbonate concretions-explained journal March 2013
Modeling and mitigation of sample relief effects applied to chemistry measurements by the Mars Science Laboratory Alpha Particle X-ray Spectrometer: Target relief effect mitigation and modeling for the MSL APXS journal March 2017
Diagenesis of mudrocks and concretions from the London Clay Formation in the London Basin journal October 1994
Hematite spherules at Meridiani: Results from MI, Mini-TES, and Pancam journal January 2008
Chemistry of diagenetic features analyzed by ChemCam at Pahrump Hills, Gale crater, Mars journal January 2017
In Situ Compositional Measurements of Rocks and Soils with the Alpha Particle X-ray Spectrometer on NASA's Mars Rovers journal February 2015
Mineralogy of an ancient lacustrine mudstone succession from the Murray formation, Gale crater, Mars journal August 2017
A Habitable Fluvio-Lacustrine Environment at Yellowknife Bay, Gale Crater, Mars journal December 2013
Joint controlled fluid flow patterns and iron mass transfer in Jurassic Navajo Sandstone, Southern Utah, USA: Navajo sandstone fluid flow patterns journal April 2011
Clay-Ironstone Concretion Preserving Fabrics Due to Progressive Compaction journal January 1972
A possible terrestrial analogue for haematite concretions on Mars journal June 2004
The internal structure of carbonate concretions in mudrocks: a critical evaluation of the conventional concentric model of concretion growth journal May 1996
Syndepositional precipitation of calcium sulfate in Gale Crater, Mars journal September 2018
Rate of concretion growth journal May 1968
Evidence for surface reaction-controlled growth of carbonate concretions in shales journal August 1988
Ancient Martian aeolian processes and palaeomorphology reconstructed from the Stimson formation on the lower slope of Aeolis Mons, Gale crater, Mars journal April 2018
Concretion morphologies reflecting diagenetic and epigenetic pathways journal August 2001
Models of iron oxide concretion formation: field, numerical, and laboratory comparisons journal August 2007
Recalibration of the Mars Science Laboratory ChemCam instrument with an expanded geochemical database journal March 2017
Desiccation cracks provide evidence of lake drying on Mars, Sutton Island member, Murray formation, Gale Crater journal April 2018
Multiple stages of aqueous alteration along fractures in mudstone and sandstone strata in Gale Crater, Mars journal August 2017
The stratigraphy and evolution of lower Mount Sharp from spectral, morphological, and thermophysical orbital data sets: Stratigraphy and Evolution of Mount Sharp journal September 2016
Deposition, exhumation, and paleoclimate of an ancient lake deposit, Gale crater, Mars journal October 2015
Calcium sulfate veins characterized by ChemCam/Curiosity at Gale crater, Mars: CALCIUM SULFATE VEINS AT GALE CRATER journal September 2014
Concretion Formation In Volcaniclastic Host Rocks: Evaluating the Role of Organics, Mineralogy, and Geochemistry On Early Diagenesis journal September 2014
Hematitic concretions at Meridiani Planum, Mars: Their growth timescale and possible relationship with iron sulfates journal May 2008
Characterization of Navajo Sandstone concretions: Mars comparison and criteria for distinguishing diagenetic origins journal January 2011
Evidence for hydraulic fracturing at Gale crater, Mars: Implications for burial depth of the Yellowknife Bay formation journal June 2017
Distance to Nearest Neighbor as a Measure of Spatial Relationships in Populations journal October 1954
Curiosity’s Mars Hand Lens Imager (MAHLI) Investigation journal July 2012
The ChemCam Instrument Suite on the Mars Science Laboratory (MSL) Rover: Science Objectives and Mast Unit Description journal July 2012
Geologic overview of the Mars Science Laboratory rover mission at the Kimberley, Gale crater, Mars: Overview of MSL at the Kimberley journal January 2017
Geochemistry of the Hepworth Carboniferous sediment sequence and origin of the diagenetic iron minerals and concretions journal June 1979
Provenance and diagenesis of the evaporite-bearing Burns formation, Meridiani Planum, Mars journal November 2005
Deconvolution of distinct lithology chemistry through oversampling with the Mars Science Laboratory Alpha Particle X-Ray Spectrometer: Deconvolution of distinct lithology chemistry with the MSL APXS journal February 2016
Active hematite concretion formation in modern acid saline lake sediments, Lake Brown, Western Australia journal April 2008
The ChemCam Instrument Suite on the Mars Science Laboratory (MSL) Rover: Body Unit and Combined System Tests journal June 2012
Marshrock formed by iron sulphide and siderite cementation in saltmarsh sediments journal December 1981
Subaqueous shrinkage cracks in the Sheepbed mudstone: Implications for early fluid diagenesis, Gale crater, Mars journal July 2014
The Mars Science Laboratory Curiosity rover Mastcam instruments: Preflight and in-flight calibration, validation, and data archiving : MSL/Mastcam Calibration journal July 2017
Origin of Highly Elongate, Calcite-Cemented Concretions in Some Italian Coastal Beach and Dune Sands journal January 2001
Mudrock‐hosted carbonate concretions: a review of growth mechanisms and their influence on chemical and isotopic composition journal January 2000
Diagenetic silica enrichment and late-stage groundwater activity in Gale crater, Mars: Silica Enriching Diagenesis, Gale, Mars journal May 2017
Chemical variability in mineralized veins observed by ChemCam on the lower slopes of Mount Sharp in Gale crater, Mars journal September 2018
Geochemical and textural evidence for early (shallow) diagenetic growth of stratigraphically confined carbonate concretions, Upper Devonian Rhinestreet black shale, western New York journal June 2004
Red rock and red planet diagenesis: Comparisons of Earth and Mars concretions journal January 2005
Concretion morphology, classification and genesis journal November 1996
Centimeter to decimeter hollow concretions and voids in Gale Crater sediments, Mars journal June 2017

Cited By (1)

Extensive Polygonal Fracture Network in Siccar Point group Strata: Fracture Mechanisms and Implications for Fluid Circulation in Gale Crater, Mars journal October 2019