Four-step iron( ii ) spin state cascade driven by antagonistic solid state interactions

Sciortino, Natasha F.; Zenere, Katrina A.; Corrigan, Maggie E.; Halder, Gregory J.; Chastanet, Guillaume; Létard, Jean-François; Kepert, Cameron J.; Neville, Suzanne M.

doi:10.1039/c6sc03114e

Four-step iron( ii ) spin state cascade driven by antagonistic solid state interactions

Journal Article · Sun Jan 01 00:00:00 EST 2017 · Chemical Science

DOI:https://doi.org/10.1039/c6sc03114e· OSTI ID:1624943

Sciortino, Natasha F. ^[1]; Zenere, Katrina A. ^[2]; Corrigan, Maggie E. ^[2]; Halder, Gregory J. ^[3]; Chastanet, Guillaume ^[4]; Létard, Jean-François ^[4]; Kepert, Cameron J. ^[2]; Neville, Suzanne M. ^[2]

School of Chemistry; The University of Sydney; Australia; DOE/OSTI
School of Chemistry; The University of Sydney; Australia
X-ray Science Division; Advanced Photon Source; Argonne National Laboratory; USA
CNRS; Univ. Bordeaux; ICMCB; UPR 9048; Pessac

A rare four-step spin crossover transition has been attained in a two-dimensional Hofmann-type material through the presence of an array of antagonistic host–host and host–guest interactions.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1624943

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 1 Vol. 8; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Two-Step Spin-Crossover with Three Inequivalent Fe ^II Sites in a Two-Dimensional Hofmann-Type Coordination Polymer Meng, Yan; Sheng, Qing-Qing; Hoque, Md. Najbul Chemistry - A European Journal, Vol. 23, Issue 42 https://doi.org/10.1002/chem.201702356	journal	July 2017
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Reversible three equal-step spin crossover in an iron( ii ) Hofmann-type metal–organic framework Liu, Fu-Ling; Li, Dong; Su, Li-Jie Dalton Transactions, Vol. 47, Issue 5 https://doi.org/10.1039/c7dt04205a	journal	January 2018
A ladder-type iron( ii ) coordination polymer with enhanced spin-crossover behavior Yan, Zheng; Zhu, Long-Feng; Zhu, Lian-Wen Inorganic Chemistry Frontiers, Vol. 4, Issue 6 https://doi.org/10.1039/c7qi00180k	journal	January 2017
Heteroatom substitution effects in spin crossover dinuclear complexes Zaiter, Samantha; Kirk, Charlotte; Taylor, Matthew Dalton Transactions, Vol. 48, Issue 21 https://doi.org/10.1039/c8dt05010d	journal	January 2019
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Thermo- and photo-modulation of exciplex fluorescence in a 3D spin crossover Hofmann-type coordination polymer Delgado, Teresa; Meneses-Sánchez, Manuel; Piñeiro-López, Lucía Chemical Science, Vol. 9, Issue 44 https://doi.org/10.1039/c8sc02677g	journal	January 2018
The substituent guest effect on four-step spin-crossover behavior Zhang, Cui-Juan; Lian, Kai-Ting; Wu, Si-Guo Inorganic Chemistry Frontiers, Vol. 7, Issue 4 https://doi.org/10.1039/c9qi01420a	journal	January 2020
Light- and temperature-assisted spin state annealing: accessing the hidden multistability Chen, Yan-Cong; Meng, Yan; Dong, Yan-Jie Chemical Science, Vol. 11, Issue 12 https://doi.org/10.1039/c9sc05971g	journal	January 2020
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Asymmetric seven-/eight-step spin-crossover in a three-dimensional Hofmann-type metal–organic framework Peng, Yuan-Yuan; Wu, Si-Guo; Chen, Yan-Cong Inorganic Chemistry Frontiers, Vol. 7, Issue 8 https://doi.org/10.1039/d0qi00245c	journal	January 2020
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Four-step iron( ii ) spin state cascade driven by antagonistic solid state interactions

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