Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal

Zenere, Katrina A.; Duyker, Samuel G.; Trzop, Elzbieta; Collet, Eric; Chan, Bun; Doheny, Patrick W.; Kepert, Cameron J.; Neville, Suzanne M.

doi:10.1039/C8SC01040D

Title: Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal

Journal Article · Mon Jan 01 00:00:00 EST 2018 · Chemical Science

DOI:https://doi.org/10.1039/C8SC01040D· OSTI ID:1440796

^[1]; Duyker, Samuel G. ^[1]; Trzop, Elzbieta ^[2]; Collet, Eric ^[2];

^[3];

^[1]; Kepert, Cameron J. ^[1]; Neville, Suzanne M. ^[4]

School of Chemistry, The University of Sydney, Sydney, Australia
Univ Rennes, CNRS, IPR (Institut de Physique de Rennes) – UMR 6251, F-35000 Rennes, France
Graduate School of Engineering, Nagasaki University, Nagasaki-shi Nagasaki 852-8521, Japan
School of Chemistry, The University of Sydney, Sydney, Australia, School of Chemistry

Ambient temperature spin crossover with wide hysteresis has been achieved in 2D Hofmann-type materials, where removal of guest molecules optimises ligand–ligand interactions, resulting in increased cooperativity.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1440796

Journal Information:: Chemical Science, Journal Name: Chemical Science Vol. 9 Journal Issue: 25; ISSN 2041-6520

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Cited by: 68 works

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