Increasing spin crossover cooperativity in 2D Hofmann-type materials with guest molecule removal

Journal Article · Mon Jan 01 00:00:00 EST 2018 · Chemical Science

DOI:https://doi.org/10.1039/C8SC01040D· OSTI ID:1485677

Zenere, Katrina A.  ^[1]; Duyker, Samuel G. ^[1]; Trzop, Elzbieta ^[2]; Collet, Eric ^[2]; Chan, Bun  ^[3]; Doheny, Patrick W.  ^[1]; Kepert, Cameron J. ^[1]; Neville, Suzanne M. ^[4]

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1. School of Chemistry; The University of Sydney; Sydney; Australia
2. Univ Rennes; CNRS; IPR (Institut de Physique de Rennes) – UMR 6251; F-35000 Rennes; France
3. Graduate School of Engineering; Nagasaki University; Nagasaki-shi Nagasaki 852-8521; Japan
4. School of Chemistry; The University of Sydney; Sydney; Australia; School of Chemistry

Ambient temperature spin crossover with wide hysteresis has been achieved in 2D Hofmann-type materials, where removal of guest molecules optimises ligand–ligand interactions, resulting in increased cooperativity.

• Research Organization: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
• Sponsoring Organization: FOREIGN
• OSTI ID: 1485677
• Journal Information: Chemical Science, Vol. 9, Issue 25; ISSN 2041-6520
• Publisher: Royal Society of Chemistry
• Country of Publication: United States
• Language: ENGLISH