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Synthesis and Isolation of the Titanium-Scandium Endohedral Fullerenes-Sc 2 TiC@ Ih -C 80 , Sc 2 TiC@ D 5h -C 80 and Sc 2 TiC 2 @ Ih -C 80 : Metal Size Tuning of the Ti IV /Ti III Redox Potentials

Journal Article · · Chemistry - A European Journal
 [1];  [2];  [3];  [3];  [3];  [2];  [2];  [3]
  1. Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstraße 20 01069 Dresden Germany; DOE/OSTI
  2. Department of Chemistry, University of California, Davis 95616 USA
  3. Leibniz Institute for Solid State and Materials Research (IFW Dresden), Helmholtzstraße 20 01069 Dresden Germany
The formation of endohedral metallofullerenes (EMFs) in an electric arc is reported for the mixed-metal Sc–Ti system utilizing methane as a reactive gas. Comparison of these results with those from the Sc/CH4 and Ti/CH4 systems as well as syntheses without methane revealed a strong mutual influence of all key components on the product distribution. Whereas a methane atmosphere alone suppresses the formation of empty cage fullerenes, the Ti/CH4 system forms mainly empty cage fullerenes. In contrast, the main fullerene products in the Sc/CH4 system are Sc4C2@C80 (the most abundant EMF from this synthesis), Sc3C2@C80, isomers of Sc2C2@C82, and the family Sc2C2n (2 n=74, 76, 82, 86, 90, etc.), as well as Sc3CH@C80. The Sc–Ti/CH4 system produces the mixed-metal Sc2TiC@C2n (2 n=68, 78, 80) and Sc2TiC2@C2n (2 n=80) clusterfullerene families. The molecular structures of the new, transition-metal-containing endohedral fullerenes, Sc2TiC@Ih-C80, Sc2TiC@D5h-C80, and Sc2TiC2@Ih-C80, were characterized by NMR spectroscopy. The structure of Sc2TiC@Ih-C80
Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
1623509
Journal Information:
Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Journal Issue: 37 Vol. 22; ISSN 0947-6539
Publisher:
ChemPubSoc EuropeCopyright Statement
Country of Publication:
United States
Language:
English

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Cited By (10)

Single Molecule Magnetism with Strong Magnetic Anisotropy and Enhanced Dy∙∙∙Dy Coupling in Three Isomers of Dy‐Oxide Clusterfullerene Dy 2 O@C 82 journal August 2019
Purification of Uranium-based Endohedral Metallofullerenes (EMFs) by Selective Supramolecular Encapsulation and Release journal July 2018
A Design Criteria to Achieve Giant Ising‐Type Anisotropy in Co II ‐Encapsulated Metallofullerenes journal November 2019
Pivotal Role of Nonmetal Atoms in the Stabilities, Geometries, Electronic Structures, and Isoelectronic Chemistry of Sc 3 X@C 80 (X = C, N, and O) journal August 2019
When metal clusters meet carbon cages: endohedral clusterfullerenes journal January 2017
Record-high thermal barrier of the relaxation of magnetization in the nitride clusterfullerene Dy 2 ScN@C 80 -I h journal January 2017
Selective arc-discharge synthesis of Dy 2 S-clusterfullerenes and their isomer-dependent single molecule magnetism journal January 2017
Carbide clusterfullerene DyYTiC@C 80 featuring three different metals in the endohedral cluster and its single-ion magnetism journal January 2018
Recent advances in single molecule magnetism of dysprosium-metallofullerenes journal January 2019
Trapping an unprecedented Ti 3 C 3 unit inside the icosahedral C 80 fullerene: a crystallographic survey journal January 2019


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