Prediction of mixed‐gas adsorption equilibria from pure component adsorption isotherms

Tun, Hla; Chen, Chau‐Chyun

doi:10.1002/aic.16243

Prediction of mixed‐gas adsorption equilibria from pure component adsorption isotherms

Journal Article · Mon May 04 00:00:00 EDT 2020 · AIChE Journal

DOI:https://doi.org/10.1002/aic.16243· OSTI ID:1617096

Tun, Hla ^[1]; ^[1]

Department of Chemical Engineering Texas Tech University Lubbock Texas USA

Abstract

Using only a single binary interaction parameter per adsorbate‐adsorbate pair, the adsorption nonrandom two‐liquid theory successfully correlates binary gas adsorption experimental data and predicts multicomponent gas adsorption equilibria. This work estimates the binary adsorbate–adsorbate interaction parameters from pure component isotherms and shows very promising agreement with the binary interaction parameters identified from regression of binary gas adsorption data. The results support the feasibility to predict binary and multicomponent gas adsorption equilibria from pure component isotherms for various adsorbents including silica gel, activated carbon, zeolites, and metal–organic frameworks.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: EE0007888

OSTI ID:: 1617096

Alternate ID(s):: OSTI ID: 1799389

Journal Information:: AIChE Journal, Journal Name: AIChE Journal Journal Issue: 7 Vol. 66; ISSN 0001-1541

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United States

Language:: English

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