Polymer Zwitterions for Stabilization of CsPbBr3 Perovskite Nanoparticles and Nanocomposite Films

Kim, Hyunki; Hight‐Huf, Nicholas; Kang, Ji‐Hwan; Bisnoff, Phoebe; Sundararajan, Suvin; Thompson, Theo; Barnes, Michael; Hayward, Ryan C.; Emrick, Todd

doi:10.1002/anie.201916492

Polymer Zwitterions for Stabilization of CsPbBr₃ Perovskite Nanoparticles and Nanocomposite Films

Journal Article · Thu Mar 05 00:00:00 EST 2020 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201916492· OSTI ID:1802860

Kim, Hyunki ^[1]; Hight‐Huf, Nicholas ^[2]; Kang, Ji‐Hwan ^[3]; Bisnoff, Phoebe ^[3]; Sundararajan, Suvin ^[3]; Thompson, Theo ^[3]; Barnes, Michael ^[2]; Hayward, Ryan C. ^[3]; ^[3]

Univ. of Massachusetts, Amherst, MA (United States). Polymer Science and Engineering Dept.; OSTI
Univ. of Massachusetts, Amherst, MA (United States). Dept. of Chemistry
Univ. of Massachusetts, Amherst, MA (United States). Polymer Science and Engineering Dept.

Functional polymers with sulfobetaine or phosphorylcholine zwitterions as pendent groups are demonstrated as both ligands and host matrices for CsPbBr₃ perovskite nanoparticles (PNPs). These polymers produce nanocomposite films with excellent NP dispersion, optical transparency, and impressive resistance to NP degradation upon exposure to water. Multidentate interactions of the zwitterion-containing copolymers with the PNPs induce dispersed or weakly aggregated nanocomposite morphologies, depending on the extent of zwitterionic functionality in the polymer. Incorporating additional functionality into the polymers, such as benzophenone pendent groups, yields lithographically patternable films, while time-resolved photoluminescence measurements provide insight into the electronic impact of PNPs in zwitterionic polymer matrices.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Massachusetts, Amherst, MA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0016208

OSTI ID:: 1802860

Alternate ID(s):: OSTI ID: 1615439
OSTI ID: 22937939

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 27 Vol. 59; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Polymer Zwitterions for Stabilization of CsPbBr3 Perovskite Nanoparticles and Nanocomposite Films

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Polymer Zwitterions for Stabilization of CsPbBr₃ Perovskite Nanoparticles and Nanocomposite Films