Polymer Zwitterions for Stabilization of CsPbBr 3 Perovskite Nanoparticles and Nanocomposite Films

Kim, Hyunki; Hight‐Huf, Nicholas; Kang, Ji‐Hwan; Bisnoff, Phoebe; Sundararajan, Suvin; Thompson, Theo; Barnes, Michael; Hayward, Ryan C.; Emrick, Todd

doi:10.1002/ange.201916492

Polymer Zwitterions for Stabilization of CsPbBr ₃ Perovskite Nanoparticles and Nanocomposite Films

Journal Article · Mon Apr 20 00:00:00 EDT 2020 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201916492· OSTI ID:1615438

Kim, Hyunki ^[1]; Hight‐Huf, Nicholas ^[2]; Kang, Ji‐Hwan ^[1]; Bisnoff, Phoebe ^[1]; Sundararajan, Suvin ^[1]; Thompson, Theo ^[1]; Barnes, Michael ^[2]; Hayward, Ryan C. ^[1]; ^[1]

Polymer Science and Engineering Department University of Massachusetts Amherst Amherst MA 01003 USA
Department of Chemistry University of Massachusetts Amherst USA

Abstract

Functional polymers with sulfobetaine or phosphorylcholine zwitterions as pendent groups are demonstrated as both ligands and host matrices for CsPbBr ₃ perovskite nanoparticles (PNPs). These polymers produce nanocomposite films with excellent NP dispersion, optical transparency, and impressive resistance to NP degradation upon exposure to water. Multidentate interactions of the zwitterion‐containing copolymers with the PNPs induce dispersed or weakly aggregated nanocomposite morphologies, depending on the extent of zwitterionic functionality in the polymer. Incorporating additional functionality into the polymers, such as benzophenone pendent groups, yields lithographically patternable films, while time‐resolved photoluminescence measurements provide insight into the electronic impact of PNPs in zwitterionic polymer matrices.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0016208

OSTI ID:: 1615438

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 27 Vol. 132; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (31)

High Charge Carrier Mobilities and Lifetimes in Organolead Trihalide Perovskites Wehrenfennig, Christian; Eperon, Giles E.; Johnston, Michael B. Advanced Materials, Vol. 26, Issue 10 https://doi.org/10.1002/adma.201305172	journal	December 2013
All-Inorganic Colloidal Perovskite Quantum Dots: A New Class of Lasing Materials with Favorable Characteristics Wang, Yue; Li, Xiaoming; Song, Jizhong Advanced Materials, Vol. 27, Issue 44 https://doi.org/10.1002/adma.201503573	journal	October 2015
Light‐Driven Shape Morphing, Assembly, and Motion of Nanocomposite Gel Surfers Kim, Hyunki; Kang, Ji‐Hwan; Zhou, Ying Advanced Materials, Vol. 31, Issue 27 https://doi.org/10.1002/adma.201900932	journal	May 2019
CsPbBr 3 QD/AlO x Inorganic Nanocomposites with Exceptional Stability in Water, Light, and Heat Loiudice, Anna; Saris, Seryio; Oveisi, Emad Angewandte Chemie, Vol. 129, Issue 36 https://doi.org/10.1002/ange.201703703	journal	June 2017
CsPbBr ₃ QD/AlO _x Inorganic Nanocomposites with Exceptional Stability in Water, Light, and Heat Loiudice, Anna; Saris, Seryio; Oveisi, Emad Angewandte Chemie International Edition, Vol. 56, Issue 36 https://doi.org/10.1002/anie.201703703	journal	June 2017
Phosphonic Acid Stabilized Colloidal CsPbX ₃ (X=Br, I) Perovskite Nanocrystals and Their Surface Chemistry Koh, Weon-kyu; Park, Sungjun; Ham, Yongnam ChemistrySelect, Vol. 1, Issue 13 https://doi.org/10.1002/slct.201600809	journal	August 2016
Multifaceted Excited State of CH ₃ NH ₃ PbI ₃ . Charge Separation, Recombination, and Trapping Christians, Jeffrey A.; Manser, Joseph S.; Kamat, Prashant V. The Journal of Physical Chemistry Letters, Vol. 6, Issue 11 https://doi.org/10.1021/acs.jpclett.5b00594	journal	May 2015
Polymer-Enhanced Stability of Inorganic Perovskite Nanocrystals and Their Application in Color Conversion LEDs Meyns, Michaela; Perálvarez, Mariano; Heuer-Jungemann, Amelie ACS Applied Materials & Interfaces, Vol. 8, Issue 30 https://doi.org/10.1021/acsami.6b02529	journal	July 2016
Encapsulation of Perovskite Nanocrystals into Macroscale Polymer Matrices: Enhanced Stability and Polarization Raja, Shilpa N.; Bekenstein, Yehonadav; Koc, Matthew A. ACS Applied Materials & Interfaces, Vol. 8, Issue 51 https://doi.org/10.1021/acsami.6b09443	journal	December 2016
Synthesis and Stabilization of Colloidal Perovskite Nanocrystals by Multidentate Polymer Micelles Hou, Shaocong; Guo, Yuzheng; Tang, Yuguo ACS Applied Materials & Interfaces, Vol. 9, Issue 22 https://doi.org/10.1021/acsami.7b03445	journal	May 2017
Colloidal CsPbX ₃ (X = Cl, Br, I) Nanocrystals 2.0: Zwitterionic Capping Ligands for Improved Durability and Stability Krieg, Franziska; Ochsenbein, Stefan T.; Yakunin, Sergii ACS Energy Letters, Vol. 3, Issue 3 https://doi.org/10.1021/acsenergylett.8b00035	journal	February 2018
Highly Dynamic Ligand Binding and Light Absorption Coefficient of Cesium Lead Bromide Perovskite Nanocrystals De Roo, Jonathan; Ibáñez, Maria; Geiregat, Pieter ACS Nano, Vol. 10, Issue 2 https://doi.org/10.1021/acsnano.5b06295	journal	January 2016
Modulated Formation of MOF-5 Nanoparticles—A SANS Analysis Nayuk, R.; Zacher, D.; Schweins, R. The Journal of Physical Chemistry C, Vol. 116, Issue 10 https://doi.org/10.1021/jp3003728	journal	March 2012
High Photoluminescence Efficiency and Optically Pumped Lasing in Solution-Processed Mixed Halide Perovskite Semiconductors Deschler, Felix; Price, Michael; Pathak, Sandeep The Journal of Physical Chemistry Letters, Vol. 5, Issue 8 https://doi.org/10.1021/jz5005285	journal	March 2014
Microscopic Observation of Aging of Silica Particles in Unvulcanized Rubber Shinohara, Yuya; Kishimoto, Hiroyuki; Yagi, Naoto Macromolecules, Vol. 43, Issue 22 https://doi.org/10.1021/ma102095b	journal	November 2010
Functional Polymer Nanocomposites Enhanced by Nanorods Hore, Michael J. A.; Composto, Russell J. Macromolecules, Vol. 47, Issue 3 https://doi.org/10.1021/ma402179w	journal	December 2013
Nanocrystals of Cesium Lead Halide Perovskites (CsPbX ₃ , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I. Nano Letters, Vol. 15, Issue 6 https://doi.org/10.1021/nl5048779	journal	February 2015
Excitons versus free charges in organo-lead tri-halide perovskites D’Innocenzo, Valerio; Grancini, Giulia; Alcocer, Marcelo J. P. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4586	journal	April 2014
Solution-processed hybrid perovskite photodetectors with high detectivity Dou, Letian; Yang, Yang (Micheal); You, Jingbi Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6404	journal	November 2014
Band filling with free charge carriers in organometal halide perovskites Manser, Joseph S.; Kamat, Prashant V. Nature Photonics, Vol. 8, Issue 9 https://doi.org/10.1038/nphoton.2014.171	journal	August 2014
Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals Akkerman, Quinten A.; Rainò, Gabriele; Kovalenko, Maksym V. Nature Materials, Vol. 17, Issue 5 https://doi.org/10.1038/s41563-018-0018-4	journal	February 2018
Photovoltaic solar cell technologies: analysing the state of the art Nayak, Pabitra K.; Mahesh, Suhas; Snaith, Henry J. Nature Reviews Materials, Vol. 4, Issue 4 https://doi.org/10.1038/s41578-019-0097-0	journal	March 2019
Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent Lin, Kebin; Xing, Jun; Quan, Li Na Nature, Vol. 562, Issue 7726 https://doi.org/10.1038/s41586-018-0575-3	journal	October 2018
Stable and conductive lead halide perovskites facilitated by X-type ligands Ruan, Longfei; Shen, Wei; Wang, Aifei Nanoscale, Vol. 9, Issue 21 https://doi.org/10.1039/C7NR02125A	journal	January 2017
Functional polymers for growth and stabilization of CsPbBr ₃ perovskite nanoparticles Kim, Hyunki; So, Soonyong; Ribbe, Alexander Chemical Communications, Vol. 55, Issue 12 https://doi.org/10.1039/C8CC09343A	journal	January 2019
Mean-field models of structure and dispersion of polymer-nanoparticle mixtures Ganesan, Venkat; Ellison, Christopher J.; Pryamitsyn, Victor Soft Matter, Vol. 6, Issue 17 https://doi.org/10.1039/b926992d	journal	January 2010
The structure of chain end-grafted nanoparticle/homopolymer nanocomposites Green, Peter F. Soft Matter, Vol. 7, Issue 18 https://doi.org/10.1039/c1sm05076a	journal	January 2011
Not just fractal surfaces, but surface fractal aggregates: Derivation of the expression for the structure factor and its applications Besselink, R.; Stawski, T. M.; Van Driessche, A. E. S. The Journal of Chemical Physics, Vol. 145, Issue 21 https://doi.org/10.1063/1.4960953	journal	December 2016
Small-angle scattering from porous solids with fractal geometry Mildner, D. F. R.; Hall, P. L. Journal of Physics D: Applied Physics, Vol. 19, Issue 8 https://doi.org/10.1088/0022-3727/19/8/021	journal	August 1986
Recombination Kinetics in Organic-Inorganic Perovskites: Excitons, Free Charge, and Subgap States Stranks, Samuel D.; Burlakov, Victor M.; Leijtens, Tomas Physical Review Applied, Vol. 2, Issue 3 https://doi.org/10.1103/PhysRevApplied.2.034007	journal	September 2014
Properties and potential optoelectronic applications of lead halide perovskite nanocrystals Kovalenko, Maksym V.; Protesescu, Loredana; Bodnarchuk, Maryna I. Science, Vol. 358, Issue 6364 https://doi.org/10.1126/science.aam7093	journal	November 2017

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