Electronic and Optical Properties of 2D Transition Metal Carbides and Nitrides (MXenes)

Hantanasirisakul, Kanit; Gogotsi, Yury

doi:10.1002/adma.201804779

Electronic and Optical Properties of 2D Transition Metal Carbides and Nitrides (MXenes)

Journal Article · Mon Nov 19 00:00:00 EST 2018 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201804779· OSTI ID:1612996

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Drexel Univ., Philadelphia, PA (United States); Drexel University
Drexel Univ., Philadelphia, PA (United States)

2D transition metal carbides, carbonitrides, and nitrides, known as MXenes, are a rapidly growing family of 2D materials with close to 30 members experimentally synthesized, and dozens more studied theoretically. They exhibit outstanding electronic, optical, mechanical, and thermal properties with versatile transition metal and surface chemistries. They have shown promise in many applications, such as energy storage, electromagnetic interference shielding, transparent electrodes, sensors, catalysis, photothermal therapy, etc. The high electronic conductivity and wide range of optical absorption properties of MXenes are the key to their success in the aforementioned applications. However, relatively little is currently known about their fundamental electronic and optical properties, limiting their use to their full potential. In this review, MXenes' electronic and optical properties from both theoretical and experimental perspectives, as well as applications related to those properties, are discussed, providing a guide for researchers who are exploring those properties of MXenes.

View Accepted Manuscript (DOE)

Research Organization:: Drexel Univ., Philadelphia, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0018618

OSTI ID:: 1612996

Alternate ID(s):: OSTI ID: 1482743

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 52 Vol. 30; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Surface Modified Ti ₃ C ₂ MXene Nanosheets for Tumor Targeting Photothermal/Photodynamic/Chemo Synergistic Therapy Liu, Gongyuan; Zou, Jianhua; Tang, Qianyun ACS Applied Materials & Interfaces, Vol. 9, Issue 46 https://doi.org/10.1021/acsami.7b13421	journal	November 2017
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Role of the surface effect on the structural, electronic and mechanical properties of the carbide MXenes Zha, Xian-Hu; Luo, Kan; Li, Qiuwu EPL (Europhysics Letters), Vol. 111, Issue 2 https://doi.org/10.1209/0295-5075/111/26007	journal	July 2015
Effect of surface functionalization on the electronic transport properties of Ti ₃ C ₂ MXene Berdiyorov, G. R. EPL (Europhysics Letters), Vol. 111, Issue 6 https://doi.org/10.1209/0295-5075/111/67002	journal	September 2015
Exploration and prediction of topological electronic materials based on first-principles calculations Weng, Hongming; Dai, Xi; Fang, Zhong MRS Bulletin, Vol. 39, Issue 10 https://doi.org/10.1557/mrs.2014.216	journal	October 2014
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Two-Dimensional Molybdenum Carbide (MXene) with Divacancy Ordering for Brackish and Seawater Desalination via Cation and Anion Intercalation Srimuk, Pattarachai; Halim, Joseph; Lee, Juhan Universität des Saarlandes https://doi.org/10.22028/d291-28913	collection	January 2018
Stratified Graphene-Noble Metal Systems for Low-Loss Plasmonics Applications Rast, L.; Sullivan, T. J.; Tewary, V. K. arXiv https://doi.org/10.48550/arxiv.1301.5620	text	January 2013
Topological Insulator Materials Ando, Yoichi arXiv https://doi.org/10.48550/arxiv.1304.5693	text	January 2013
Nearly Free Electron States in MXenes Khazaei, Mohammad; Ranjbar, Ahmad; Ghorbani-Asl, Mahdi arXiv https://doi.org/10.48550/arxiv.1604.07516	text	January 2016
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Anisotropic MXene Aerogels with a Mechanically Tunable Ratio of Electromagnetic Wave Reflection to Absorption Han, Meikang; Yin, Xiaowei; Hantanasirisakul, Kanit Advanced Optical Materials, Vol. 7, Issue 10 https://doi.org/10.1002/adom.201900267	journal	March 2019
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2D metal carbides and nitrides (MXenes) for energy storage

Journal Article · Mon Jan 16 19:00:00 EST 2017 · Nature Reviews. Materials · OSTI ID:1399374

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2D transition metal carbides
2D transition metal nitrides
36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
MXenes
chemistry
electronic properties
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Electronic and Optical Properties of 2D Transition Metal Carbides and Nitrides (MXenes)

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