Detection of Rashba spin splitting in 2D organic-inorganic perovskite via precessional carrier spin relaxation

Todd, Seth B.; Riley, Drew B.; Binai-Motlagh, Ali; Clegg, Charlotte; Ramachandran, Ajan; March, Samuel A.; Hoffman, Justin M.; Hill, Ian G.; Stoumpos, Constantinos C.; Kanatzidis, Mercouri G.; Yu, Zhi-Gang; Hall, Kimberley C.

doi:10.1063/1.5099352

Detection of Rashba spin splitting in 2D organic-inorganic perovskite via precessional carrier spin relaxation

Journal Article · Fri Aug 16 00:00:00 EDT 2019 · APL Materials

DOI:https://doi.org/10.1063/1.5099352· OSTI ID:1611841

Todd, Seth B. ^[1]; Riley, Drew B. ^[2]; Binai-Motlagh, Ali ^[2]; Clegg, Charlotte ^[2]; Ramachandran, Ajan ^[2]; March, Samuel A. ^[2]; Hoffman, Justin M. ^[3]; Hill, Ian G. ^[2]; Stoumpos, Constantinos C. ^[3]; Kanatzidis, Mercouri G. ^[3]; ^[4]; ^[2]

Dalhousie Univ., Halifax, NS (Canada); DOE/OSTI
Dalhousie Univ., Halifax, NS (Canada)
Northwestern Univ., Evanston, IL (United States)
Washington State Univ., Pullman, WA (United States)

The strong spin-orbit interaction in the organic-inorganic perovskites tied to the incorporation of heavy elements (e.g., Pb and I) makes these materials interesting for applications in spintronics. In conjunction with a lack of inversion symmetry associated with distortions of the metal-halide octahedra, surfaces and interfaces, or the application of a bias, the Rashba effect (used in spin field-effect transistors and spin filters) has been predicted to be much larger in these materials than in traditional III-V semiconductors such as GaAs. Evidence of strong Rashba coupling has been observed in both 3D (bulk) and 2D perovskites, with the relative role of bulk and surface Rashba contributions in the former case under active debate. The varying size of the reported spin splittings points to the need for more experimental studies of Rashba effects in the organic-inorganic perovskite family of materials. Here, we apply time-resolved circular dichroism techniques to the study of carrier spin dynamics in a 2D perovskite thin film [(BA)2MAPb2I7; BA = CH3(CH2)3NH3, MA = CH3NH3]. Our findings confirm the presence of a Rashba spin splitting via the dominance of precessional spin relaxation induced by the Rashba effective magnetic field (also known as D’yakonov Perel spin relaxation). The size of the Rashba spin splitting in our system was extracted from simulations of the measured spin dynamics incorporating LO-phonon and electron-electron scattering, yielding a value of 10 meV at an electron energy of 50 meV above the band gap, representing a 20 times larger value than in GaAs quantum wells.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Santa Barbara, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: SC0012541

OSTI ID:: 1611841

Alternate ID(s):: OSTI ID: 1567930

Journal Information:: APL Materials, Journal Name: APL Materials Journal Issue: 8 Vol. 7; ISSN 2166-532X

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

References (90)

Photophysics of Organic-Inorganic Hybrid Lead Iodide Perovskite Single Crystals Fang, Hong-Hua; Raissa, Raissa; Abdu-Aguye, Mustapha Advanced Functional Materials, Vol. 25, Issue 16 https://doi.org/10.1002/adfm.201404421	journal	February 2015
Lead-Free Halide Perovskite Solar Cells with High Photocurrents Realized Through Vacancy Modulation Kumar, Mulmudi Hemant; Dharani, Sabba; Leong, Wei Lin Advanced Materials, Vol. 26, Issue 41 https://doi.org/10.1002/adma.201401991	journal	September 2014
Direct or Indirect Bandgap in Hybrid Lead Halide Perovskites? Sarritzu, Valerio; Sestu, Nicola; Marongiu, Daniela Advanced Optical Materials, Vol. 6, Issue 10 https://doi.org/10.1002/adom.201701254	journal	March 2018
A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego Angewandte Chemie, Vol. 126, Issue 42 https://doi.org/10.1002/ange.201406466	journal	September 2014
A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego Angewandte Chemie International Edition, Vol. 53, Issue 42 https://doi.org/10.1002/anie.201406466	journal	September 2014
Semiconductor Spintronics and Quantum Computation Awschalom, D. D.; Loss, D.; Samarth, N. NanoScience and Technology https://doi.org/10.1007/978-3-662-05003-3	book	January 2002
Exciton state in two-dimensional perovskite semiconductor (C10H21NH3)2PbI4 Ishihara, Teruya; Takahashi, Jun; Goto, Takenari Solid State Communications, Vol. 69, Issue 9 https://doi.org/10.1016/0038-1098(89)90935-6	journal	March 1989
Magnetoabsorption of the lowest exciton in perovskite-type compound (CH3NH3)PbI3 Hirasawa, M.; Ishihara, T.; Goto, T. Physica B: Condensed Matter, Vol. 201 https://doi.org/10.1016/0921-4526(94)91130-4	journal	July 1994
Comparative study on the excitons in lead-halide-based perovskite-type crystals CH₃NH₃PbBr₃ CH₃NH₃PbI₃ Tanaka, Kenichiro; Takahashi, Takayuki; Ban, Takuma Solid State Communications, Vol. 127, Issue 9-10, p. 619-623 https://doi.org/10.1016/s0038-1098(03)00566-0	journal	September 2003
g Factors and Spin-Lattice Relaxation of Conduction Electrons Yafet, Y. Solid State Physics https://doi.org/10.1016/s0081-1947(08)60259-3	book	January 1963
Scintillation properties of (C6H13NH3)2PbI4: Exciton luminescence of an organic/inorganic multiple quantum well structure compound induced by 2.0 MeV protons Shibuya, K.; Koshimizu, M.; Takeoka, Y. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 194, Issue 2 https://doi.org/10.1016/s0168-583x(02)00671-7	journal	August 2002
Thin-Film Preparation and Characterization of Cs ₃ Sb ₂ I ₉ : A Lead-Free Layered Perovskite Semiconductor Saparov, Bayrammurad; Hong, Feng; Sun, Jon-Paul Chemistry of Materials, Vol. 27, Issue 16 https://doi.org/10.1021/acs.chemmater.5b01989	journal	August 2015
Ruddlesden–Popper Hybrid Lead Iodide Perovskite 2D Homologous Semiconductors Stoumpos, Constantinos C.; Cao, Duyen H.; Clark, Daniel J. Chemistry of Materials, Vol. 28, Issue 8, p. 2852-2867 https://doi.org/10.1021/acs.chemmater.6b00847	journal	April 2016
Intriguing Optoelectronic Properties of Metal Halide Perovskites Manser, Joseph S.; Christians, Jeffrey A.; Kamat, Prashant V. Chemical Reviews, Vol. 116, Issue 21 https://doi.org/10.1021/acs.chemrev.6b00136	journal	June 2016
Surface Electronic Structure of Hybrid Organo Lead Bromide Perovskite Single Crystals Komesu, Takashi; Huang, Xin; Paudel, Tula R. The Journal of Physical Chemistry C, Vol. 120, Issue 38 https://doi.org/10.1021/acs.jpcc.6b08329	journal	September 2016
Rashba Effect and Carrier Mobility in Hybrid Organic–Inorganic Perovskites Yu, Zhi-Gang The Journal of Physical Chemistry Letters, Vol. 7, Issue 16 https://doi.org/10.1021/acs.jpclett.6b01404	journal	July 2016
Electric Field- and Strain-Induced Rashba Effect in Hybrid Halide Perovskites Leppert, Linn; Reyes-Lillo, Sebastian E.; Neaton, Jeffrey B. The Journal of Physical Chemistry Letters, Vol. 7, Issue 18 https://doi.org/10.1021/acs.jpclett.6b01794	journal	September 2016
First-Principles Study of Novel Two-Dimensional (C ₄ H ₉ NH ₃ ) ₂ PbX ₄ Perovskites for Solar Cell Absorbers Wang, Da; Wen, Bo; Zhu, Ya-Nan The Journal of Physical Chemistry Letters, Vol. 8, Issue 4 https://doi.org/10.1021/acs.jpclett.7b00003	journal	January 2017
Rashba Band Splitting in Organohalide Lead Perovskites: Bulk and Surface Effects Mosconi, Edoardo; Etienne, Thibaud; De Angelis, Filippo The Journal of Physical Chemistry Letters, Vol. 8, Issue 10 https://doi.org/10.1021/acs.jpclett.7b00328	journal	May 2017
Rashba and Dresselhaus Couplings in Halide Perovskites: Accomplishments and Opportunities for Spintronics and Spin–Orbitronics Kepenekian, Mikaël; Even, Jacky The Journal of Physical Chemistry Letters, Vol. 8, Issue 14 https://doi.org/10.1021/acs.jpclett.7b01015	journal	July 2017
Charge-Carrier Dynamics in 2D Hybrid Metal–Halide Perovskites Milot, Rebecca L.; Sutton, Rebecca J.; Eperon, Giles E. Nano Letters, Vol. 16, Issue 11 https://doi.org/10.1021/acs.nanolett.6b03114	journal	October 2016
Highly Efficient Visible Colloidal Lead-Halide Perovskite Nanocrystal Light-Emitting Diodes Yan, Fei; Xing, Jun; Xing, Guichuan Nano Letters, Vol. 18, Issue 5 https://doi.org/10.1021/acs.nanolett.8b00789	journal	April 2018
Rashba and Dresselhaus Effects in Hybrid Organic–Inorganic Perovskites: From Basics to Devices Kepenekian, Mikaël; Robles, Roberto; Katan, Claudine ACS Nano, Vol. 9, Issue 12 https://doi.org/10.1021/acsnano.5b04409	journal	September 2015
Real-Time Observation of Exciton–Phonon Coupling Dynamics in Self-Assembled Hybrid Perovskite Quantum Wells Ni, Limeng; Huynh, Uyen; Cheminal, Alexandre ACS Nano, Vol. 11, Issue 11 https://doi.org/10.1021/acsnano.7b03984	journal	October 2017
Four-Wave Mixing in Perovskite Photovoltaic Materials Reveals Long Dephasing Times and Weaker Many-Body Interactions than GaAs March, Samuel A.; Riley, Drew B.; Clegg, Charlotte ACS Photonics, Vol. 4, Issue 6 https://doi.org/10.1021/acsphotonics.7b00282	journal	June 2017
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G. Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038 https://doi.org/10.1021/ic401215x	journal	July 2013
2D Homologous Perovskites as Light-Absorbing Materials for Solar Cell Applications Cao, Duyen H.; Stoumpos, Constantinos C.; Farha, Omar K. Journal of the American Chemical Society, Vol. 137, Issue 24 https://doi.org/10.1021/jacs.5b03796	journal	June 2015
Importance of Spin–Orbit Coupling in Hybrid Organic/Inorganic Perovskites for Photovoltaic Applications Even, Jacky; Pedesseau, Laurent; Jancu, Jean-Marc The Journal of Physical Chemistry Letters, Vol. 4, Issue 17 https://doi.org/10.1021/jz401532q	journal	August 2013
Cation-Induced Band-Gap Tuning in Organohalide Perovskites: Interplay of Spin–Orbit Coupling and Octahedra Tilting Amat, Anna; Mosconi, Edoardo; Ronca, Enrico Nano Letters, Vol. 14, Issue 6 https://doi.org/10.1021/nl5012992	journal	May 2014
Highly Spin-Polarized Carrier Dynamics and Ultralarge Photoinduced Magnetization in CH ₃ NH ₃ PbI ₃ Perovskite Thin Films Giovanni, David; Ma, Hong; Chua, Julianto Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/nl5039314	journal	February 2015
Excitons versus free charges in organo-lead tri-halide perovskites D’Innocenzo, Valerio; Grancini, Giulia; Alcocer, Marcelo J. P. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4586	journal	April 2014
Solution-processed hybrid perovskite photodetectors with high detectivity Dou, Letian; Yang, Yang (Micheal); You, Jingbi Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6404	journal	November 2014
Tunable ferroelectric polarization and its interplay with spin–orbit coupling in tin iodide perovskites Stroppa, Alessandro; Di Sante, Domenico; Barone, Paolo Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6900	journal	December 2014
Lead iodide perovskite light-emitting field-effect transistor Chin, Xin Yu; Cortecchia, Daniele; Yin, Jun Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8383	journal	June 2015
Lead halide perovskite nanowire lasers with low lasing thresholds and high quality factors Zhu, Haiming; Fu, Yongping; Meng, Fei Nature Materials, Vol. 14, Issue 6 https://doi.org/10.1038/nmat4271	journal	April 2015
Bright light-emitting diodes based on organometal halide perovskite Tan, Zhi-Kuang; Moghaddam, Reza Saberi; Lai, May Ling Nature Nanotechnology, Vol. 9, Issue 9 https://doi.org/10.1038/nnano.2014.149	journal	August 2014
Direct measurement of the exciton binding energy and effective masses for charge carriers in organic–inorganic tri-halide perovskites Miyata, Atsuhiko; Mitioglu, Anatolie; Plochocka, Paulina Nature Physics, Vol. 11, Issue 7 https://doi.org/10.1038/nphys3357	journal	June 2015
Spin-polarized exciton quantum beating in hybrid organic–inorganic perovskites Odenthal, Patrick; Talmadge, William; Gundlach, Nathan Nature Physics, Vol. 13, Issue 9 https://doi.org/10.1038/nphys4145	journal	May 2017
Inversion symmetry and bulk Rashba effect in methylammonium lead iodide perovskite single crystals Frohna, Kyle; Deshpande, Tejas; Harter, John Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04212-w	journal	May 2018
Long-lived polarization memory in the electronic states of lead-halide perovskites from local structural dynamics Rivett, Jasmine P. H.; Tan, Liang Z.; Price, Michael B. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06009-3	journal	August 2018
Simultaneous observation of free and defect-bound excitons in CH3NH3PbI3 using four-wave mixing spectroscopy March, Samuel A.; Clegg, Charlotte; Riley, Drew B. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep39139	journal	December 2016
Advancements in perovskite solar cells: photophysics behind the photovoltaics Sum, Tze Chien; Mathews, Nripan Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/c4ee00673a	journal	January 2014
Intrinsic femtosecond charge generation dynamics in single crystal CH ₃ NH ₃ PbI ₃ Valverde-Chávez, David A.; Ponseca, Carlito S.; Stoumpos, Constantinos C. Energy & Environmental Science, Vol. 8, Issue 12 https://doi.org/10.1039/c5ee02503f	journal	January 2015
Tin perovskite/fullerene planar layer photovoltaics: improving the efficiency and stability of lead-free devices Marshall, Kenneth P.; Walton, Richard I.; Hatton, Ross A. Journal of Materials Chemistry A, Vol. 3, Issue 21 https://doi.org/10.1039/c5ta02950c	journal	January 2015
Does Rashba splitting in CH ₃ NH ₃ PbBr ₃ arise from 2 × 2 surface reconstruction? Che, Xiaoyang; Traore, Boubacar; Katan, Claudine Physical Chemistry Chemical Physics, Vol. 20, Issue 14 https://doi.org/10.1039/c8cp00745d	journal	January 2018
980 nm compact optical isolators using Cd1–x–yMnxHgyTe single crystals for high power pumping laser diodes Kimura, M.; Onodera, K.; Masumoto, T. Electronics Letters, Vol. 30, Issue 23 https://doi.org/10.1049/el:19941327	journal	November 1994
Electronic analog of the electro‐optic modulator Datta, Supriyo; Das, Biswajit Applied Physics Letters, Vol. 56, Issue 7 https://doi.org/10.1063/1.102730	journal	February 1990
All‐optical picosecond switching of a quantum well etalon using spin‐polarization relaxation Nishikawa, Yuji; Tackeuchi, Atsushi; Nakamura, Satoshi Applied Physics Letters, Vol. 66, Issue 7 https://doi.org/10.1063/1.113439	journal	February 1995
Electron spin relaxation in InGaAs/InP multiple-quantum wells Tackeuchi, Atsushi; Wada, Osamu; Nishikawa, Yuji Applied Physics Letters, Vol. 70, Issue 9 https://doi.org/10.1063/1.118506	journal	March 1997
Subpicosecond spin relaxation in GaAsSb multiple quantum wells Hall, K. C.; Leonard, S. W.; van Driel, H. M. Applied Physics Letters, Vol. 75, Issue 23 https://doi.org/10.1063/1.125422	journal	December 1999
Subpicosecond spin relaxation in GaAsSb multiple quantum wells Hall, K. C.; Leonard, S. W.; van Driel, H. M. Applied Physics Letters, Vol. 75, Issue 26 https://doi.org/10.1063/1.125586	journal	December 1999
Laser threshold reduction in a spintronic device Rudolph, J.; Hägele, D.; Gibbs, H. M. Applied Physics Letters, Vol. 82, Issue 25 https://doi.org/10.1063/1.1583145	journal	June 2003
Nonmagnetic semiconductor spin transistor Hall, K. C.; Lau, Wayne H.; Gündoğdu, K. Applied Physics Letters, Vol. 83, Issue 14 https://doi.org/10.1063/1.1609656	journal	October 2003
Performance of a spin-based insulated gate field effect transistor Hall, Kimberley C.; Flatté, Michael E. Applied Physics Letters, Vol. 88, Issue 16 https://doi.org/10.1063/1.2192152	journal	April 2006
Ultrafast optical control of coercivity in GaMnAs Hall, K. C.; Zahn, J. P.; Gamouras, A. Applied Physics Letters, Vol. 93, Issue 3 https://doi.org/10.1063/1.2963972	journal	July 2008
Carrier diffusion in thin-film CH ₃ NH ₃ PbI ₃ perovskite measured using four-wave mixing Webber, D.; Clegg, C.; Mason, A. W. Applied Physics Letters, Vol. 111, Issue 12 https://doi.org/10.1063/1.4989970	journal	September 2017
Switchable S = 1/2 and J = 1/2 Rashba bands in ferroelectric halide perovskites Kim, M.; Im, J.; Freeman, A. J. Proceedings of the National Academy of Sciences, Vol. 111, Issue 19 https://doi.org/10.1073/pnas.1405780111	journal	April 2014
Structural fluctuations cause spin-split states in tetragonal (CH ₃ NH ₃ )PbI ₃ as evidenced by the circular photogalvanic effect Niesner, Daniel; Hauck, Martin; Shrestha, Shreetu Proceedings of the National Academy of Sciences, Vol. 115, Issue 38 https://doi.org/10.1073/pnas.1805422115	journal	September 2018
Spin-Orbit Coupling Effects in Zinc Blende Structures Dresselhaus, G. Physical Review, Vol. 100, Issue 2 https://doi.org/10.1103/physrev.100.580	journal	October 1955
Theory of the Effect of Spin-Orbit Coupling on Magnetic Resonance in Some Semiconductors Elliott, R. J. Physical Review, Vol. 96, Issue 2 https://doi.org/10.1103/physrev.96.266	journal	October 1954
Spin splitting of conduction subbands in III-V heterostructures due to inversion asymmetry Pfeffer, P.; Zawadzki, W. Physical Review B, Vol. 59, Issue 8 https://doi.org/10.1103/physrevb.59.r5312	journal	February 1999
Electron-spin decoherence in bulk and quantum-well zinc-blende semiconductors Lau, Wayne H.; Olesberg, J. T.; Flatté, Michael E. Physical Review B, Vol. 64, Issue 16 https://doi.org/10.1103/physrevb.64.161301	journal	September 2001
Spin relaxation in (110) and (001) InAs/GaSb superlattices Hall, K. C.; Gündoğdu, K.; Altunkaya, E. Physical Review B, Vol. 68, Issue 11 https://doi.org/10.1103/physrevb.68.115311	journal	September 2003
Electronic model for self-assembled hybrid organic/perovskite semiconductors: Reverse band edge electronic states ordering and spin-orbit coupling Even, J.; Pedesseau, L.; Dupertuis, M. -A. Physical Review B, Vol. 86, Issue 20 https://doi.org/10.1103/physrevb.86.205301	journal	November 2012
Relativistic quasiparticle self-consistent electronic structure of hybrid halide perovskite photovoltaic absorbers Brivio, Federico; Butler, Keith T.; Walsh, Aron Physical Review B, Vol. 89, Issue 15 https://doi.org/10.1103/physrevb.89.155204	journal	April 2014
Two-dimensional Fröhlich interaction in transition-metal dichalcogenide monolayers: Theoretical modeling and first-principles calculations Sohier, Thibault; Calandra, Matteo; Mauri, Francesco Physical Review B, Vol. 94, Issue 8 https://doi.org/10.1103/physrevb.94.085415	journal	August 2016
Giant Rashba Splitting in CH 3 NH 3 PbBr 3 Organic-Inorganic Perovskite Niesner, Daniel; Wilhelm, Max; Levchuk, Ievgen Physical Review Letters, Vol. 117, Issue 12 https://doi.org/10.1103/physrevlett.117.126401	journal	September 2016
Stable biexcitons in two-dimensional metal-halide perovskites with strong dynamic lattice disorder Thouin, Félix; Neutzner, Stefanie; Cortecchia, Daniele Physical Review Materials, Vol. 2, Issue 3 https://doi.org/10.1103/physrevmaterials.2.034001	journal	March 2018
Synthesis, characterization and phase transitions in the inorganic–organic layered perovskite-type hybrids [(C _n H _{2 n + 1} NH ₃ ) ₂ PbI ₄ ], n = 4, 5 and 6 Billing, David G.; Lemmerer, Andreas Acta Crystallographica Section B Structural Science, Vol. 63, Issue 5 https://doi.org/10.1107/s0108768107031758	journal	September 2007
Photoelectronic Responses in Solution-Processed Perovskite CH$_{\bf 3}$ NH$_{\bf 3}$PbI $_{\bf 3}$ Solar Cells Studied by Photoluminescence and Photoabsorption Spectroscopy Yamada, Yasuhiro; Nakamura, Toru; Endo, Masaru IEEE Journal of Photovoltaics, Vol. 5, Issue 1 https://doi.org/10.1109/jphotov.2014.2364115	journal	January 2015
Tunable room-temperature spin-selective optical Stark effect in solution-processed layered halide perovskites Giovanni, David; Chong, Wee Kiang; Dewi, Herlina Arianita Science Advances, Vol. 2, Issue 6 https://doi.org/10.1126/sciadv.1600477	journal	June 2016
Giant Rashba splitting in 2D organic-inorganic halide perovskites measured by transient spectroscopies Zhai, Yaxin; Baniya, Sangita; Zhang, Chuang Science Advances, Vol. 3, Issue 7 https://doi.org/10.1126/sciadv.1700704	journal	July 2017
Enhanced photovoltaic performance and stability with a new type of hollow 3D perovskite {en}FASnI ₃ Ke, Weijun; Stoumpos, Constantinos C.; Zhu, Menghua Science Advances, Vol. 3, Issue 8 https://doi.org/10.1126/sciadv.1701293	journal	August 2017
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH₃NH₃PbI₃ Xing, G.; Mathews, N.; Sun, S. Science, Vol. 342, Issue 6156, p. 344-347 https://doi.org/10.1126/science.1243167	journal	October 2013
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber Stranks, S. D.; Eperon, G. E.; Grancini, G. Science, Vol. 342, Issue 6156, p. 341-344 https://doi.org/10.1126/science.1243982	journal	October 2013
Organic-Inorganic Hybrid Materials as Semiconducting Channels in Thin-Film Field-Effect Transistors Kagan, C. R.; Mitzi, D. B.; Dimitrakopoulos, C. D. Science, Vol. 286, Issue 5441, p. 945-947 https://doi.org/10.1126/science.286.5441.945	journal	October 1999
Carrier Mobility Dependence of Electron Spin Relaxation in GaAs Quantum Wells Terauchi, Ryota; Ohno, Yuzo; Adachi, Taro Japanese Journal of Applied Physics, Vol. 38, Issue Part 1, No. 4B https://doi.org/10.1143/jjap.38.2549	journal	April 1999
Charge-Carrier Dynamics in Organic-Inorganic Metal Halide Perovskites Herz, Laura M. Annual Review of Physical Chemistry, Vol. 67, Issue 1 https://doi.org/10.1146/annurev-physchem-040215-112222	journal	May 2016
Real-Time Observation of Exciton-Phonon Coupling Dynamics in Self-Assembled Hybrid Perovskite Quantum Wells Ni, Limeng; Huynh, U.; Cheminal, Alexandre Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.27641	text	January 2018
Long-lived polarization memory in the electronic states of lead-halide perovskites from local structural dynamics. Rivett, Jasmine PH; Tan, Liang Z.; Price, Michael Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.32068	text	January 2018
Direct measurement of the exciton binding energy and effective masses for charge carriers in organic–inorganic tri-halide perovskites Miyata, A.; Mitioglu, A.; Plochocka, P. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.38431	text	January 2015
Relativistic quasiparticle self-consistent electronic structure of hybrid halide perovskite photovoltaic absorbers Brivio, Federico; Butler, Keith T.; Walsh, Aron arXiv https://doi.org/10.48550/arxiv.1401.6993	text	January 2014
Direct Measurement of the Exciton Binding Energy and Effective Masses for Charge carriers in an Organic-Inorganic Tri-halide Perovskite Miyata, Atsuhiko; Mitioglu, Anatolie; Plochocka, Paulina arXiv https://doi.org/10.48550/arxiv.1504.07025	text	January 2015
Four-wave mixing in perovskite photovoltaic materials reveals long dephasing times and weaker many-body interactions than GaAs March, Samuel A.; Riley, Drew B.; Clegg, Charlotte arXiv https://doi.org/10.48550/arxiv.1602.05186	text	January 2016
Two-dimensional Fröhlich interaction in transition-metal dichalcogenide monolayers: Theoretical modeling and first-principles calculations Sohier, Thibault; Calandra, Matteo; Mauri, Francesco arXiv https://doi.org/10.48550/arxiv.1605.08207	text	January 2016
Carrier Diffusion in Thin-Film CH3NH3PbI3 Perovskite Measured using Four-Wave Mixing Webber, D.; Clegg, C.; Mason, A. W. arXiv https://doi.org/10.48550/arxiv.1706.04154	text	January 2017
Highly efficient visible colloidal lead-halide perovskite nanocrystal light-emitting diodes Yan, Fei; Xing, Jun; Xing, Guichuan arXiv https://doi.org/10.48550/arxiv.1801.10317	text	January 2018
Electron Spin Decoherence in Bulk and Quantum Well Zincblende Semiconductors Lau, Wayne H.; Olesberg, J. T.; Flatte', Michael E. arXiv https://doi.org/10.48550/arxiv.cond-mat/0004461	text	January 2000
Spin relaxation in (110) and (001) InAs/GaSb superlattices Hall, K. C.; Gundogdu, K.; Altunkaya, E. arXiv https://doi.org/10.48550/arxiv.cond-mat/0301080	text	January 2003
Non-magnetic semiconductor spin transistor Hall, K. C.; Lau, Wayne H.; Gundogdu, K. arXiv https://doi.org/10.48550/arxiv.cond-mat/0307687	text	January 2003

Cited By (2)

Ultrafast acoustic phonon scattering in CH ₃ NH ₃ PbI ₃ revealed by femtosecond four-wave mixing March, Samuel A.; Riley, Drew B.; Clegg, Charlotte The Journal of Chemical Physics, Vol. 151, Issue 14 https://doi.org/10.1063/1.5120385	journal	October 2019
Resonant free-carrier absorption in 2D hybrid organic-inorganic perovskites: The Rashba effect or small polarons? Yu, Zhi-Gang The Journal of Chemical Physics, Vol. 151, Issue 20 https://doi.org/10.1063/1.5127459	journal	November 2019

Similar Records

Origin of Rashba Spin-Orbit Coupling in 2D and 3D Lead Iodide Perovskites

Journal Article · Tue Mar 17 20:00:00 EDT 2020 · Scientific Reports · OSTI ID:1628976

Circular photogalvanic spectroscopy of Rashba splitting in 2D hybrid organic–inorganic perovskite multiple quantum wells

Journal Article · Wed Jan 15 19:00:00 EST 2020 · Nature Communications · OSTI ID:1619767

Related Subjects

36 MATERIALS SCIENCE
Materials Science
Physics
Science & Technology - Other Topics

Detection of Rashba spin splitting in 2D organic-inorganic perovskite via precessional carrier spin relaxation

Citation Formats

References (90)

Cited By (2)

Similar Records

Related Subjects