Nylon–MOF Composites through Postsynthetic Polymerization

Kalaj, Mark; Denny, Michael S.; Bentz, Kyle C.; Palomba, Joseph M.; Cohen, Seth M.

doi:10.1002/anie.201812655

Nylon–MOF Composites through Postsynthetic Polymerization

Journal Article · Mon Dec 03 00:00:00 EST 2018 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201812655· OSTI ID:1610000

Kalaj, Mark ^[1]; Denny, Michael S. ^[2]; Bentz, Kyle C. ^[2]; Palomba, Joseph M. ^[2]; ^[2]

Univ. of California, San Diego, CA (United States); DOE/OSTI
Univ. of California, San Diego, CA (United States)

Hybridization of metal–organic frameworks (MOFs) and polymers into composites yields materials that display the exceptional properties of MOFs with the robustness of polymers. However, the realization of MOF–polymer composites requires efficient dispersion and interactions of MOF particles with polymer matrices, which remains a significant challenge. Herein, we report a simple, scalable, bench-top approach to covalently tethered nylon–MOF polymer composite materials through an interfacial polymerization technique. The copolymerization of a modified UiO-66-NH2 MOF with a growing polyamide fiber (PA-66) during an interfacial polymerization gave hybrid materials with up to around 29 weight percent MOF. The covalent hybrid material demonstrated nearly an order of magnitude higher catalytic activity for the breakdown of a chemical warfare simulant (dimethyl-4-nitrophenyl phosphate, DMNP) compared to MOFs that are non-covalently, physically entrapped in nylon, thus highlighting the importance of MOF–polymer hybridization.

View Accepted Manuscript (DOE)

Research Organization:: University of California, San Diego, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1610000

Alternate ID(s):: OSTI ID: 1491431

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 8 Vol. 58; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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